Poly(butylene terephthalate)–clay nanocomposites prepared by melt intercalation: morphology and thermomechanical properties

Nanocomposites based on poly(butylene terephthalate) (PBT) and an organoclay (Cloisite 30B) were prepared by melt blending using a twin‐screw extruder. Two kinds of PBTs, ie PBT‐A and PBT‐B, with different inherent viscosities (η_inh), were used for this study (η_inh of PBT‐A and PBT‐B were 0.74 and 1.48, respectively). Dispersion of the clay layers in the PBT nanocomposites was characterized by using X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile and dynamic mechanical properties and non‐isothermal crystallization temperatures of the nanocomposites were also examined. Nanocomposites based on the higher‐viscosity PBT (PBT‐B) showed a higher degree of exfoliation of the clay and a higher reinforcing effect when compared to the composites based on the lower‐viscosity PBT (PBT‐A). The clay nanolayers dispersed in PBT matrices lead to increases in the non‐isothermal crystallization temperatures of the PBTs, with such increases being more significant for the PBT‐B nanocomposites than for the PBT‐A nanoocomposites. Copyright © 2004 Society of Chemical Industry     

Linearity improvement of cascode low-noise amplifiers using double DS method with a tuned inductor

We propose a highly linear low-noise amplifier (LNA) using the double derivative superposition method with a tuned inductor. This topology has an auxiliary common gate stage of the cascode amplifier to cancel each third-order intermodulation distortion (IMD3) component and can provide a high third-order input intercept point (IIP3) for the 5.25 GHz frequency band. From the simulation results using the TSMC 0.18 μm RF CMOS process, the IIP3 in the proposed cascode LNAs can be improved by 9 dB, compared with the conventional derivative superposition method. The proposed LNA achieves an IIP3 of + 15 dBm with a gain of 10.5 dB, a noise figure of 2.4 dB, and a power consumption of 6 mA at 1.5 V.     

Sliding mode cutting force regulator for turning processes

Continuous sliding mode control is applied to turning processes for cutting force regulation. The motivation of the use of the slide mode control scheme is to solve the nonlinearity problem caused by the feedrate override command element in the commercial CNC machine tool. When the adaptive control algorithm is applied to the commercial CNC machine tool, it is one of the practical methods that the programmed feedrate is overridden after the control algorithm is carried out. However, most CNC lathe manufacturers offer limited number of data bits for feedrate override, thus resulting in nonlinear behavior of the machine tools. Such nonlinearity brings ‘quantized' or discrete effect so that the optimal feedrate is rounded off before being fed into the CNC system. To compensate for this problem, continuous sliding mode control is applied. Simulation and experimental results are presented in comparison with those obtained from applying adaptive control which is a widely used approach in cutting force regulation. Adaptive control loses its effectiveness in the presence of nonlinearity since it generally requires linear parametrization of the control law or the system dynamics. Experiments are conducted under various machining conditions, subject to changes in spindle speed, material of work-piece, and type of machining process. The suggested slide mode controller shows smoother cutting force fluctuation, which cannot be achieved by the conventional adaptive controller. The experimental set-up reflects the emphasis on the practicality of the sliding mode controller. In order to avoid the use of a dynamometer in the course of measuring the cutting force, the indirect cutting force measuring system is used by means of feed drive servo-motor current sensing.     

Velocity and mass diffusivity effects on the linear and nonlinear phenomena of the Burke-Schumann flame with acoustic excitation

Journal of Mechanical Science and Technology - The dynamics of the Burke-Schumann flame in terms of the Péclet number variation were investigated. The effect of the Péclet number on the...     

Lemon juice improved color acceptance of aronia (Aronia melanocarpa) pound cake by copigmentation

Food Science and Biotechnology - Anthocyanins can be changed into dark purplish color during pound cake preparation due to high temperature and alkaline baking soda, which lowers color acceptance...     

Surface Hydrophobicity Modulates the Key Characteristics of Cancer Spheroids through the Interaction with the Adsorbed Proteins

Three-dimensional in vitro cancer models have emerged as a promising tool for various cancer-related applications. However, the limited availability of the in vitro model capable of adequately recapitulating the active interactions between the cancer cells and the surrounding tumor microenvironment (TME) hampers their use for therapeutic applications. Here, it is demonstrated that the proteins adsorbed on the culture substrate significantly influence the characteristics of the cancer cells, thereby suggesting that the modulation of cell–protein interaction can be a powerful tool to construct an advanced cancer model. A series of polymers are prepared for the precise control of the surface hydrophobicity of the culture plate. Cancer cells cultured on the polymers exhibit distinct morphological transitions ranging from monolayer to spheroids with entirely different characteristics depending on the surface hydrophobicity. The poly (cyclohexyl methacrylate) surface of the highest hydrophobicity tested in this study strongly attracts albumin from the media for enhanced adsorption and induces conformational changes in albumin upon binding, leading to the formation of spheroid with the most enriched tumorigenic properties. It is believed that this finding can provide new insights when selecting the experimental strategy to appropriately mimic the complex interplay between the cancer cells and the TME.     

The effect of annealing ambient on the characteristics of an indium-gallium-zinc oxide thin film transistor

In this study, the effects of different annealing conditions (air, O2, N2, vacuum) on the chemical and electrical characteristics of amorphous indium-gallium-zinc oxide (a-IGZO) thin film transistors (TFT) were investigated. The contact resistance and interface properties between the IGZO film and the gate dielectric improved after an annealing treatment. However, the chemical bonds in the IGZO bulk changed under various annealing atmospheres, which, in turn, altered the characteristics of the TFTs. The TFTs annealed in vacuum and N2 ambients exhibited undesired switching properties due to the high carrier concentration (>10(17) cm(-3)) of the IGZO active layer. In contrast, the IGZO TFTs annealed in air and oxygen ambients displayed clear transfer characteristics due to an adequately adjusted carrier concentration in the operating range of the TFT. Such an optimal carrier concentration arose through the stabilization of unstable chemical bonds in the IGZO film. With regard to device performance, the TFTs annealed in O2 and air exhibited saturation mobility values of 8.29 and 7.54 cm2/Vs, on-off ratios of 7.34 x 10(8) and 3.95 x 10(8), and subthreshold swing (SS) values of 0.23 and 0.19 V/decade, respectively. Therefore, proper annealing ambients contributed to internal modifications in the IGZO structure and led to an enhancement in the oxidation state of the metal. As a result, defects such as oxygen vacancies were eliminated. Oxygen annealing is thus effective for controlling the carrier concentration of the active layer, decreasing electron traps, and enhancing TFT performance.