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1.
In this study, the effect of pendant pyrene on the optical and electronic properties of poly(2,5‐dithienylpyrrole)s was studied. For this purpose a new pyrene coupled 2,5‐dithienylpyrrole derivative (SNS‐pyrene) was synthesized through click reaction. SNS‐pyrene was electrochemically polymerized and its electrochemical and optical properties were investigated by electrochemical and optical techniques. The polymer had a band gap of 3.36 eV and displayed light green to blue color variation upon oxidation in less than 2.48 s. Additionally, electrochemical copolymerization of SNS‐pyrene with 3,4‐ethylenedioxythiophene was achieved whilst a detailed investigation was performed on the effect of electrochemical polymerization conditions on the optoelectronic properties of the copolymers. Studies revealed that the copolymers exhibit multichromic reversible redox behavior with lower band gaps and shorter switching times than their parent polymer, P(SNS‐pyrene) © 2014 Society of Chemical Industry. 相似文献
2.
A method for the time suboptimal control of an industrial manipulator from an initial position and orientation to a final
position and orientation as it moves along a specified path is proposed. Nonlinear system equations that describe the manipulator
motion are linearized at each time step along the path. A method which gives the control inputs (joint angular velocities)
for time suboptimal control of the manipulator is developed. In the formulation, joint angular velocity and acceleration limitations
are also taken into consideration. A six degree of freedom elbow type manipulator is used in numerical examples to verify
the method developed. 相似文献
3.
Ugur Ozdemir Yucel Orkut Aktas Aslihan Vuruskan Yasin Dereli Ahmed Farabi Tarhan Karaca Demirbag Ahmet Erdem Ganime Duygu Kalaycioglu Ibrahim Ozkol Gokhan Inalhan 《Journal of Intelligent and Robotic Systems》2014,74(1-2):371-393
For the last four decades Unmanned Air Vehicles (UAVs) have been extensively used for military operations that include tracking, surveillance, active engagement with weapons and airborne data acquisition. UAVs are also in demand commercially due to their advantages in comparison to manned vehicles. These advantages include lower manufacturing and operating costs, flexibility in configuration depending on customer request and not risking the pilot on demanding missions. Even though civilian UAVs currently constitute 3 % of the UAV market, it is estimated that their numbers will reach up to 10 % of the UAV market within the next 5 years. Most of the civilian UAV applications require UAVs that are capable of doing a wide range of different and complementary operations within a composite mission. These operations include taking off and landing from limited runway space, while traversing the operation region in considerable cruise speed for mobile tracking applications. This is in addition to being able traverse in low cruise speeds or being able to hover for stationary measurement and tracking. All of these complementary and but different operational capabilities point to a hybrid unmanned vehicle concept, namely the Vertical Take-Off and Landing (VTOL) UAVs. In addition, the desired UAV system needs to be cost-efficient while providing easy payload conversion for different civilian applications. In this paper, we review the preliminary design process of such a capable civilian UAV system, namely the TURAC VTOL UAV. TURAC UAV is aimed to have both vertical take-off and landing and Conventional Take-off and Landing (CTOL) capability. TURAC interchangeable payload pod and detachable wing (with potential different size variants) provides capability to perform different mission types, including long endurance and high cruise speed operations. In addition, the TURAC concept is to have two different variants. The TURAC A variant is an eco-friendly and low-noise fully electrical platform which includes 2 tilt electric motors in the front, and a fixed electric motor and ducted fan in the rear, where as the TURAC B variant is envisioned to use high energy density fuel cells for extended hovering time. In this paper, we provide the TURAC UAV’s iterative design and trade-off studies which also include detailed aerodynamic and structural configuration analysis. For the aerodynamic analysis, an in-house software including graphical user interface has been developed to calculate the aerodynamic forces and moments by using the Vortex Lattice Method (VLM). Computational Fluid Dynamics (CFD) studies are performed to determine the aerodynamic effects for various configurations For structural analysis, a Finite Element Model (FEM) of the TURAC has been prepared and its modal analysis is carried out. Maximum displacements and maximal principal stresses are calculated and used for streamlining a weight efficient fuselage design. Prototypes have been built to show success of the design at both hover and forward flight regime. In this paper, we also provide the flight management and autopilot architecture of the TURAC. The testing of the controller performance has been initiated with the prototype of TURAC. Current work focuses on the building of the full fight test prototype of the TURAC UAV and aerodynamic modeling of the transition flight. 相似文献
4.
One hundred and fifty samples of raw calf/lamb meat samples (mince and chunks) and chicken parts (giblets, carcass) were analysed for the presence of Staphylococcus aureus. Eighty S. aureus strains were isolated and identified. Resistance of the strains to methicillin and other antibiotics was determined by the Kirby-Bauer disc diffusion test. The overall methicillin resistance rate for S. aureus was 67.5%. Of S. aureus strains, 87.5% were resistant to bacitracin. A high prevalence of penicillin G resistance was detected for S. aureus (53.8%). Few of the strains were resistant to erythromycin (7.5%). All strains were susceptible to vancomycin, sulbactam–ampicillin, ciprofloxacin and cefaperazone–sulbactam. This study confirmed the presence of S. aureus, especially antibiotic-resistant strains, in the foods examined, indicating poor sanitary conditions during processing which may create a health risk for consumers. 相似文献
5.
Yucel Birol 《国际钢铁研究》2009,80(8):588-592
Semisolid processing, already a well established manufacturing route for the production of intricate, thin‐walled aluminium and magnesium parts with mechanical properties as good as forged grades, faces a major challenge in the case of steels. The tool materials must withstand complex load profiles and relatively higher forming temperatures for thousands of forming cycles for industrial application to be attractive. Since the forming pressures are much lower than those encountered in conventional forging, the principle die failure mechanism in steel thixoforging is expected to be thermal fatigue. Hence, suitable materials able to withstand the steel thixoforming environment for an economically acceptable life, can be best identified with a thermal fatigue test. Such a test is described in the present work. A novel CrNiCo and a nickel‐base superalloy, reported to exhibit superior thermal fatigue resistance in demanding tooling applications, was tested under thermal fatigue conditions encountered in the thixoforming of steels. 相似文献
6.
The potential of cooling slope casting process to produce EN AW 6082 forging stock for the manufacture of EN AW 6082 suspension components was investigated. EN AW 6082 billets cast over a cooling plate offer a fine uniform structure that can be forged even without a separate homogenization treatment. This is made it possible by the limited superheat of the melt at the start of casting and the fractional solidification that occurs already on the cooling plate. Suspension parts forged from cast and homogenized billets with or without Cr all showed a uniform structure, and the hardness reached HV 110 after the standard artificial ageing treatment. 相似文献
7.
铝合金半固态浆料中球形颗粒的演变 总被引:1,自引:0,他引:1
Yucel BIROL 《中国有色金属学会会刊》2013,23(1):1-6
用AlSi7Mg0.6半固态浆料进行实验,研究球形颗粒的演变机理.在略高于液相线温度下水淬的样品中结晶相主要为枝晶,而采用旋转圆筒的方式来搅拌熔体使其冷却到半固态温度范围内时样品的结晶相完全球化.在铸造前进行较长时间的内冷却和搅拌,可以得到较高的固相分数.不同大小的枝晶碎片的存在表明,在搅拌过程中,初始的固相分数形成后不再受冷却的影响. 相似文献
8.
High-temperature abrasive wear testing of potential tool materials for thixoforming of steels 总被引:1,自引:0,他引:1
Yucel Birol 《Tribology International》2010,43(11):2222-286
High temperature abrasive wear performance of Inconel 617, Stellite 6 alloys and X32CrMoV33 hot work tool steel was investigated. The wear resistance of the latter is degraded at 750 °C due to its inferior oxidation resistance. Extensive oxidation co-occuring with abrasive wear at 750 °C leads to substantial material loss due to the lack of a protective oxide scale, sufficiently ductile to sustain the abrasion without extensive spalling. The wear resistance of the Inconel 617 and Stellite 6 alloys, on the other hand, improves at 750 °C owing to protective oxides that sustain the abrasion without spalling. 相似文献
9.
Multivariate extensions of well-known linear mixed-effects models have been increasingly utilized in inference by multiple imputation in the analysis of multilevel incomplete data. The normality assumption for the underlying error terms and random effects plays a crucial role in simulating the posterior predictive distribution from which the multiple imputations are drawn. The plausibility of this normality assumption on the subject-specific random effects is assessed. Specifically, the performance of multiple imputation created under a multivariate linear mixed-effects model is investigated on a diverse set of incomplete data sets simulated under varying distributional characteristics. Under moderate amounts of missing data, the simulation study confirms that the underlying model leads to a well-calibrated procedure with negligible biases and actual coverage rates close to nominal rates in estimates of the regression coefficients. Estimation quality of the random-effect variance and association measures, however, are negatively affected from both the misspecification of the random-effect distribution and number of incompletely-observed variables. Some of the adverse impacts include lower coverage rates and increased biases. 相似文献
10.
Amiodarone decreases plasma and tissue triiodothyronine (T3) and increases plasma cholesterol levels resembling changes seen during hypothyroidism. To elucidate the mechanism of amiodarone-induced hypercholesterolemia we investigated gene expression of three key proteins in cholesterol metabolism (cholesterol 7 alpha-hydroxylase, LDL receptor, HMG-CoA reductase) in livers of rats. Animals were treated with amiodarone or propylthiouracil (to induce mild hypothyroidism). The LDL receptor mRNA was downregulated (approximately 50%) in both amiodarone-treated and hypothyroid animals, while the other mRNA remained unchanged after 14-day treatment. The results suggest that amiodarone-induced hypercholesterolemia is associated with decreased LDL receptor mRNA levels. 相似文献