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1.
Wenwei He Wuping Liao Weiwei Wang Deqian Li Chunji Niu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(9):1314-1320
BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated. RESULTS: The rate constant (Kao) becomes constant when the stirring speed was controlled between 250 rpm and 400 rpm. The activation energy (Ea) was calculated to be 21·41 kJ mol?1 or 88·17 kJ mol?1 (dependent on temperature) from the slope of log Kao against 1000/T. The linear relationship between the specific area and the extraction rate is the characteristic of an interfacial reaction control. The minimum bulk concentration of the extractant necessary to saturate the interface (Cmin) is lower than 4·19 × 10?4 mol L?1. CONCLUSION: The effect of stirring speed, temperature, and species concentration on the extraction rate demonstrates that the extraction regime depends on the extraction conditions. The chemical reaction control governs the extraction regime at temperatures below 303 K and a mixed control regime occurs when the temperature is between 303 K and 318 K. The probable locale for the chemical reaction is at the liquid–liquid interface and the rate equation is deduced to be: ? d[Nd3+](a)/dt = kf[Nd3+](a)[H4A](o)0·727[H+](a)?0·978. The rate‐controlling step was suggested by the analysis of the experimental results. Copyright © 2008 Society of Chemical Industry 相似文献
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Thirty six patients of pulmonary or nasopharyngeal carcinoma were treated with Xilixin granule (XLXG) combined with radiotherapy and compared their efficacy with that of 31 patients treated by Zhenqi Fuzheng granule combined with radiotherapy for control. Results showed that the symptoms of Yin Deficiency syndrome in treated group were obviously improved, the leucocyte decreased by 5.6%, while in control group it reached 25.8%, the 3 year survival rate was significantly higher in treated group (75.0%) than that in control group (51.6%). Animal experiment revealed that XLXG had the effects of tumor inhibition, it could increase white blood cells, platelets and hemoglobin of patients, especially in using large dosage. These results suggested that XLXG have some protective effect against radiotherapeutic damage in patients with malignant tumor. 相似文献
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The results of detailed measurements and calculations of the properties of Sydney University/Nitto Kohki evacuated collector tubes have been used to develop a formula for the instantaneous heat extraction efficiency η of a collector panel incorporating the evacuated tubes. The instantaneous efficiency depends on ambient temperature, mean fluid temperature in the collector, solar flux and the design of the manifold used to extract heat from the glass absorber tubes. Manifold design determines the mean temperature difference between absorber tube surface and mean fluid temperature for given operating conditions, and strongly affects the efficiency η of a collector panel. Neither changes in the number of evacuated tubes per unit area of collector, nor variations in solar flux, significantly alter the efficiency decrement Δ η0 associated with a particular manifold design. Calculated efficiencies agree well with experimental results for collector panels incorporating manifolds of various designs. The formula for efficiency η allows detailed analysis of the relative importance of various energy loss mechanisms in a collector. 相似文献
5.
邹志强 《稀有金属与硬质合金》1994,(1)
根据第十三届国际普兰西会议获得的信息,对国际上难熔金属、硬质合金、硬质材料和涂层技术等方面近几年来的研究和发展动态进行了综合评述。最后,提出了几点自己的看法。 相似文献
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伊犁盆地生成发展概述 总被引:7,自引:0,他引:7
本文对伊犁盆地的生成和发展做了初步探讨,认为它是在前震旦纪结晶基底之上经历了较长时间的抬升之后形成和发展起来的双层结构盆地,即石炭纪体内裂谷盆地,石炭纪后山间陆相盆地。 相似文献
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There are more than 660 thermal springs in West Yunnan Province, 30 of which are high-temperature hydrothermal systems with reservoir temperatures above 150°C.All thermal springs in West Yunnan are under the control of the tectonics, most of them being distributed at anticlinoria of metamorphic rocks and granites. This paper discusses the relationship between thermal areas and tectonics, the correlation between thermal springs in West Yunnan and North Thailand, and the geothermal prospects in West Yunnan. 相似文献
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The development and test of a PLC control program takes time, increases equipment down-time, and might damage hardware due to program errors. All of these problems can be eliminated if there is a computer simulation system for testing control programs off line. This paper presented a new method, called Direct Sequential Method, for simulating PLCs. This method resolves a ladder logic sequentially by applying a series of logic deductions. This simulation system has been implemented in C and tested successfully. 相似文献
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