Microstructure and Sliding Wear Behaviour of Ni(Cr)-TiB_2 Coatings Deposited by HVOF Spraying of SHS Powders

THERMAL SPRAYING provides a large range ofcoatings,which increase the wear resistance ofsubstrates[1].One of the major coating families is thecermet,composed of hard ceramic particles with ametallic binder.The most commonly used cermetcoatings in industrial applications are based on eitherthe WC-Co or the Cr3C2-Ni(Cr)systems with WC-17wt%Co and Cr3C2-25wt%Ni(Cr)being typicalcompositions[2,3].Although WC-Co deposits are hardand wear resistant at ambient temperatures their rangeof ap…     

An analytical procedure for dynamic response determination of a viscoelastic beam with moderately large deflection using first-order shear deformation theory

In this article, the dynamic response of a viscoelastic beam with moderately large deflection subjected to transverse and axial loads is studied using the first-order shear deformation theory. The von-Karman strain displacement relations and Hooke's law are used for formulation. The solution of the equations, which are a system of nonlinear partial differential equations, are obtained analytically using the perturbation technique in conjunction with the eigenfunction expansion method. The results are compared with the finite elements method. Also, a sensitivity analysis is performed, and the effects of geometrical and material properties are investigated on the response.     

Robust design optimization of electro-thermal microactuator using probabilistic methods

Micromachining of microelectromechanical systems which is similar to other fabrication processes has inherent variation that leads to uncertain dimensional and material properties. Methods for optimization under uncertainty analysis can be used to reduce microdevice sensitivity to these uncertainties in order to create a more robust design, thereby increasing reliability and yield. In this paper, approaches for uncertainty and sensitivity analysis, and robust optimization of an electro-thermal microactuator are applied to take into account the influence of dimensional and material property uncertainties on microactuator tip deflection. These uncertainties include variation of thickness, length and width of cold and hot arms, gap, Young modulus and thermal expansion coefficient. A simple and efficient uncertainty analysis method is performed by creating second-order metamodel through Box-Behnken design and Monte Carlo simulation. Also, the influence of uncertainties has been examined using direct Monte Carlo Simulation method. The results show that the standard deviations of tip deflection generated by these uncertainty analysis methods are very close to each other. Simulation results of tip deflection have been validated by a comparison with experimental results in literature. The analysis is performed at multiple input voltages to estimate uncertainty bands around the deflection curve. Experimental data fall within 95 % confidence boundary obtained by simulation results. Also, the sensitivity analysis results demonstrate that microactuator performance has been affected more by thermal expansion coefficient and microactuator gap uncertainties. Finally, approaches for robust optimization to achieve the optimal designs for microactuator are used. The proposed robust microactuators are less sensitive to uncertainties. For this goal, two methods including Genetic Algorithm and Non-dominated Sorting Genetic Algorithm are employed to find the robust designs for microactuator.     

Fabrication and characterization of highly efficient three component CuBTC/graphene oxide/PSF membrane for gas separation application

Metal organic frameworks (MOFs) with marvelous properties have aroused enormous attention for different application especially gas adsorption and separation. In this regard, fabrication of MOF hybrids with carbon based materials is new strategy to upgrade MOF performance. In this study CuBTC (Copper benzene-1,3,5-tricarboxylic acid)/graphene oxide (GO) composite was synthesized and characterized by BET, SEM, TGA, XRD and FT-IR techniques. Then CuBTC and CuBTC/GO composite were incorporated into polysulfone (PSF) polymer to construct mixed matrix membranes (MMMs). The obtained membranes were characterized by SEM, TGA, XRD and tensile tests and their gas permeability was measured. The results were compared to those of CuBTC/PSF MMMs. It was revealed that CuBTC/GO composite as filler showed superior performance relative to CuBTC. For instance, 15 wt% loading of CuBTC/GO in PSF represented outstanding gas separation behavior while the same loading of CuBTC in PSF deteriorated performance of MMM. Well particle dispersion and favorable polymer-filler interaction were responsible for such observed difference. A high H₂/CH₄ and H₂/N₂ selectivity of 80.03 and 70.46 were recorded for CuBTC/GO in PSF (15 wt%) compared to 44.56 and 40.92 for CuBTC in PSF (15 wt%).     

The Effect of Ti on Mechanical Properties of Extruded In-Situ Al-15 pct Mg2Si Composite

This work was carried out to investigate the effect of different Ti concentrations as a modifying agent on the microstructure and tensile properties of an in-situ Al-15 pctMg₂Si composite. Cast, modified, and homogenized small ingots were extruded at 753 K (480 °C) at the extrusion ratio of 18:1 and ram speed of 1 mm/s. Various techniques including metallography, tensile testing, and scanning electron microscopy were used to characterize the mechanical behavior, microstructural observations, and fracture mechanisms of this composite. The results showed that 0.5 pctTi addition and homogenizing treatment were highly effective in modifying Mg₂Si particles. The results also exhibited that the addition of Ti up to 0.5 pct increases both ultimate tensile strength (UTS) and tensile elongation values. The highest UTS and elongation values were found to be 245 MPa and 9.5 pct for homogenized and extruded Al-15 pctMg₂Si-0.5 pctTi composite, respectively. Fracture surface examinations revealed a transition from brittle fracture mode in the as-cast composite to ductile fracture in homogenized and extruded specimens. This can be attributed to the changes in size and morphology of Mg₂Si intermetallic and porosity content.     

Mesoporous silica coated gold nanorods: a multifunctional theranostic platform for radiotherapy and X-ray imaging

Journal of Porous Materials - The development of theranostic nanostructures is one of the most advanced branches of pharmaceutical and medical sciences in the world today. Due to the unique...     

Low Temperature Hall Effect Investigation of Conducting Polymer-Carbon Nanotubes Composite Network

Polypyrrole (PPy) and polypyrrole-carboxylic functionalized multi wall carbon nanotube composites (PPy/f-MWCNT) were synthesized by in situ chemical oxidative polymerization of pyrrole on the carbon nanotubes (CNTs). The structure of the resulting complex nanotubes was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The effects of f-MWCNT concentration on the electrical properties of the resulting composites were studied at temperatures between 100 K and 300 K. The Hall mobility and Hall coefficient of PPy and PPy/f-MWCNT composite samples with different concentrations of f-MWCNT were measured using the van der Pauw technique. The mobility decreased slightly with increasing temperature, while the conductivity was dominated by the gradually increasing carrier density.     

Feldspar/titanium dioxide/chitosan as a biophotocatalyst hybrid for the removal of organic dyes from aquatic phases

Feldspar/titanium dioxide/chitosan hybrid, a photoactive biocompatible adsorbent for anionic dyes, was synthesized, characterized, and successfully tested. The adsorbent characterization, pH role, adsorbent dose effect, equilibrium data, kinetic plats, and thermodynamic parameters are reported. The point of zero charge for the hybrid was measured to be 8.3, and the most favorable pH range for the adsorption process was found to be below this pH value. The adsorption equilibrium study demonstrated that the Freundlich model was best fitted to the experimental data. Without UV light exposure, the prepared adsorbent adsorbed 72 mg of Acid Black 1 (AB1)/g of sorbent (86% removal) from a 100‐mL solution with an initial dye concentration of 50 mg/L, whereas UV irradiation resulted in an increase in the elimination of AB1 dye (97% removal). The kinetic data was depicted well by the pseudo‐second‐order model. The thermodynamic parameters indicated that the reaction between the hybrid and the dye was exothermic and also spontaneous at lower temperatures. In the batch desorption process, several aqueous solutions adjusted to different pH values were tested, and the best desorption performance (90% desorption) was achieved at pH 11. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40247.     

Removal of Diazinon from aqueous solution by electrocoagulation process using aluminum electrodes

Electrocoagulation (EC) is an electrochemical method to treat polluted wastewaters and aqueous solutions. In this paper, the removal of Diazinon was studied by EC on aluminum electrode. The effect of several parameters such as initial concentration of Diazinon, current density, solution conductivity, effect of pH, and electrolysis time were investigated on EC performance. The obtained results showed that the removal efficiency of EC depends on the current density, initial concentration of Diazinon and electrolysis time. The optimum pH is 3 and also the solution conductivity has no significant effect on removal efficiency.     

Designing a nuclear battery based on the Mo-99 radioactive source soluble in water and aqua regia in order to use in early tests

Today, millions of electrocommunication, electric, medical, and industrial devices use battery. Batteries with long life and high energy density seem to be essential in medical, military, oil and mining, aerospace areas as well as conditions in which access is difficult and in situations where replacement or recharging of battery is costly.In this regard, the use of radiation energy resulting from radioactive materials and its conversion to electric energy can be effective in making batteries. In the present study,various Mo-99 radioisotope values with a half-life of 65.98 h were used as a soluble radioactive source in two materials of water and aqua regia. Then, by comparing the results of the Monte Carlo simulations program MCNPX for these two solutions, it was found that when the water is used instead of aqua regia(for idealization), the values of the superficial current of electrons, the volumetric flux of electrons, and the deposited energy in the volume containing the radioactive solution increased by 10.80, 4.10,and 13.80%, respectively. Also, the short-circuit current and energy conversion efficiency of this battery with a concentration of 0.01 molar, Mo-99 dissolved in the aqua regia are 0.79μA and 16.47%, respectively.