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排序方式: 共有879条查询结果,搜索用时 15 毫秒
1.
The behavior of two series of concrete slabs exposed to sulfate-bearing soils was investigated by a numerical model called
STADIUM. In addition to the diffusion of ions and moisture, the model also accounts for the effects of dissolution/precipitation
reactions on the transport mechanisms. The simulations yielded by the model were compared to the actual degradation of the
slabs after 8 years of exposure. The microstructural alterations of concrete resulting from the penetration of magnesium,
chloride and sulfate ions were studied by backscatter mode scanning electron microscope observations and energy-dispersive
X-ray analyses. The comparison of both series of data indicates that the model can reliably predict the various features of
the microstructural alterations of concrete.
Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’. 相似文献
Résumé Le comportement de deux séries de dalles sur sol en béton exposées à des sols chimiquement agressifs a été étudié à l'aide d'un code de calcul numérique appelé STADIUM. Ce modèle permet de décrire le transport couplé de l'eau et des ions dans des matériaux poreux non-saturés en prenant en considération l'influence des réactions chimiques. Les résultats des simultations de la dégradation du béton après huit ans d'exposition à des ions chlore, sulfate et magnésium. Les observations ont été réalisées par microscopie électronique à balayage. Des analyses par dispersion des rayons X ont également été effectuées. Les données démontrent clairement que le modèle perment de prédire avec précision le comportement du béton soumis à différents types d'agression chimique.
Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’. 相似文献
2.
J. Arghavani M. Derenne L. Marchand 《The International Journal of Advanced Manufacturing Technology》2003,21(10-11):713-732
The effect of surface characteristics on compressive stress and leakage rate in gasketed flanged joints is discussed qualitatively and quantitatively based on experimental verifications. The sensitivity of the sealing phenomenon to the sealing surface characteristics, gas pressure and stress level is presented. Sealing surfaces produced with grinding, turning and milling procedures of different roughness values were the subject of the tests with three types of gasket, namely, PTFE (polytetrafluoroethylene), graphite, and spiral wound. The experimental results indicated that the roughness value Ra (average arithmetic height) has no effect on the sealing performance of the gasket, except for the ground type sealing surfaces. The platen (flange) surface forms were found to be the determining factor on the leakage rate and flow regime for gasketed flanged joints. It is shown that the surface characteristics have no effect on the leakage rate and on the gasket performance for the PTFE gasket at high stress levels. However, at low stress levels the rougher ground and milled sealing surfaces having radial channels on the surface produce larger leakage rates. The effect of surface characteristics, stress level, and gas pressure was more evident on the graphite and spiral wound gasket types, at both low and high stress levels. It is also shown that the leakage rate follows an exponential law as a factor of surface stress and gas pressure, for all sealing surface characteristics and gasket types. While there is little difference in the leakage rate for the PTFE gasket when the gasket stress level is increased by a factor of two, from S3 to S5, a substantial leakage rate reduction by a ratio of 17.5 times was observed for the graphite and spiral wound gaskets for most sealing surfaces. On the other hand, when increasing the helium gas pressure from 200 to 800 p.s.i., the leakage rate increased by 5 times for the PTFE, and up to10 times for the graphite and the spiral wound gaskets. It was determined that while molecular flow regimes can be achieved for the PTFE gasket for all sealing surfaces, the two other gasket types provided laminar flow under the same operating conditions. 相似文献
3.
Oxidation of fullerene was performed with fuming nitric acid and a soluble orange compound was synthesized and identified as polyhydroxy-polynitro fullerene. The formation of fullerene derivatives containing oxygen and fluorine were attempted by different methods using F2, HF aqueous solution and fuming nitric acid. Resulting compounds were generally characterized by X-ray diffraction and IR and NMR spectroscopy. 相似文献
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6.
Gilles Thibault Gilles Paintaud Hsueh Cheng Sung Laurie Lajoie Edouard Louis the GETAID Celine Desvignes Herv Watier Valrie Gouilleux-Gruart David Ternant 《International journal of molecular sciences》2021,22(11)
The FcγRIIA/CD32A is mainly expressed on platelets, myeloid and several endothelial cells. Its affinity is considered insufficient for allowing significant binding of monomeric IgG, while its H131R polymorphism (histidine > arginine at position 131) influences affinity for multimeric IgG2. Platelet FcγRIIA has been reported to contribute to IgG-containing immune-complexe clearance. Given our finding that platelet FcγRIIA actually binds monomeric IgG, we investigated the role of platelets and FcγRIIA in IgG antibody elimination. We used pharmacokinetics analysis of infliximab (IgG1) in individuals with controlled Crohn’s disease. The influence of platelet count and FcγRIIA polymorphism was quantified by multivariate linear modelling. The infliximab half-life increased with R allele number (13.2, 14.4 and 15.6 days for HH, HR and RR patients, respectively). It decreased with increasing platelet count in R carriers: from ≈20 days (RR) and ≈17 days (HR) at 150 × 109/L, respectively, to ≈13 days (both HR and RR) at 350 × 109/L. Moreover, a flow cytometry assay showed that infliximab and monomeric IgG1 bound efficiently to platelet FcγRIIA H and R allotypes, whereas panitumumab and IgG2 bound poorly to the latter. We propose that infliximab (and presumably any IgG1 antibody) elimination is partly due to an unappreciated mechanism dependent on binding to platelet FcγRIIA, which is probably tuned by its affinity for IgG2. 相似文献
7.
Caroline Fauquant Valrie Briard Nadine Leconte Marie‐Caroline Michalski 《European Journal of Lipid Science and Technology》2005,107(2):80-86
The aim of this study was to characterize the fatty acid composition of the core and membrane of differently sized milk fat globules separated by microfiltration, which can now be used to manufacture dairy products. Native milk fat globules of various mean diameters, ranging from d43 = 2.3 µm to 8.0 µm, were obtained using microfiltration of raw whole milk. After milk fat globule washing, the milk fat globule membrane (MFGM) and the triglyceride core (TC) were separated by manual churning. After total lipid extraction from each fraction, their fatty acid composition was characterized using methyl ester analysis by gas chromatography. Regardless of season, no significant differences were observed in the fatty acid composition of the MFGM phospholipids. Conversely, significant differences were found in the fatty acid composition of TC; particularly, small fat globule TC contained more medium‐chain fatty acids and less stearic acid than large fat globule TC. These results show that the previously observed differences in total fatty acid composition among differently sized milk fat globules are due to their triglyceride composition and MFGM amount rather than to the composition of the MFGM. 相似文献
8.
Fabienne Fay Isabelle Linossier Valérie Langlois Karine Vallee‐Rehel Michal Y. Krasko Abraham J. Domb 《应用聚合物科学杂志》2007,106(6):3768-3777
This article describes the synthesis and in vitro analysis of poly(ester anhydride) antimicrobial protection coatings. Poly(ester anhydride)s composed of ricinoleic acid, sebacic acid, terephthalic acid, and isophthalic acid were used in this study. The polymers were compatible with various fillers commonly used in paint preparation. The in vitro experiments showed that the polymers are able to release diuron, an antimicrobial agent, for months. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
9.
A. Tressaud V. Gupta L. Piraux L. Lozano E. Marquestaut S. Flandrois A. Marchand O.P. Bahl 《Carbon》1994,32(8)
The intercalation of fluorine in various types of carbon fibers (PAN-based or pitch-based, asreceived or high-temperature treated) has been investigated at room temperature in the presence of gaseous HF. Stage-1 compounds with C2.5F to C4F compositions are obtained for 10 bar F2 pressures, whereas lower pressures (1 bar F2) lead to stage-2 compounds. Although in higher stages (≥2) the electrical conductivity is generally larger than in the pristine fiber, in stage-1 compounds a drastic increase of resistivity is observed, ρ being more than one order of magnitude larger than that of the starting material. Finally, fluorine-intercalated GICs have been found appropriate to investigate the effects of disorder and reduced dimensionality. 相似文献
10.
Mohamed Jaziri Nizar Mnif Valérie Massardier-Nageotte Hervé Perier-Camby 《Polymer Engineering and Science》2007,47(7):1009-1015
The objective of this work is to study the properties of blends that could result from the recycling of end-of-life vehicles (ELV). While ethylene propylene rubber (EPR) and ethylene propylene diene monomer (EPDM) have been used extensively as elastomeric additives in poly(propylene) (PP), they can be substituted by ethylene-1-octene copolymer (EOC). As a consequence, the matter resulting from the sorting of ELV might be more complex and made of PP, EPR, and EOC. The effect of incorporating EOC [that is a polyethylene elastomer (PEE)] and maleic anhydride grafted polypropylene (PP-g-MAH) on the rheological, thermal, and morphological properties of PP/EPR blends has been investigated. Blends of various compositions (with and without compatibilizer) were prepared using a corotating twin-screw extruder. The results were compared to the ones presented by a commercial (PP/EPR) blend. The EPR phase is dispersed in the form of spherical particles in (PP/EPR). The EOC phase is dispersed in the form of aggregated particles. Dynamic viscoelastic and differential scanning calorimetry properties of (PP/EPR)/EOC blends shows the incompatibility of the components even in presence of PP-g-MAH copolymer. POLYM. ENG. SCI., 47:1009–1015, 2007. © 2007 Society of Plastics Engineers 相似文献