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Coordinationpolymersareofgrowinginterestin viewoftheirpotentialapplicationincatalysis,mo lecularrecognition,sensors,storagedevicesandso on[1~3].Asamultifunctionalligand,benzenedicar boxylicacid(H2BDC)hasbeenextensivelyusedin thesynthesisofcoordinationp… 相似文献
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SiO2凝胶玻璃中Eu^+,Tb^3+与1,10—邻菲罗啉配合物的原位化学?… 总被引:3,自引:0,他引:3
应用原位化学复合方法,将Eu^3+、Tb^3+与,1,10-邻菲罗啉配合光学均匀复合到SiO2凝胶玻璃中,解决了国稀土含氮配合物易水解而难以用溶胶-凝胶工艺将其均匀掺入无机基质的问题。研究了原位配合物的荧光和热学性能。结果表明,由于配合物的形成使稀土离子特征荧光强度显著增加,而无机基质的保护作用则使原位配合物热稳性提高200℃以上。化学合成纯配合物Eu(Phen)2Cl3·2H2O的高分辨荧光谱表 相似文献
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Er3+掺杂的 MFT玻璃材料2H11/2、4S3/2→4I15/2荧光性质 总被引:2,自引:0,他引:2
计算了Er 相似文献
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用分子束外延生长了不同组分x的Zn1-xMnxSe外延膜和Zn1-xMnxSe/ZnSe超晶格.由于Zn1-xMnxSe的能隙Eg随组分变化在低组分区形成弓形,且弓形的范围随温度变化的反常特性,首次在光致发光谱(PL)中观测到当温度升高时,Zn1-xMnxSe/Znse超晶格中由ZnSe为阱、Zn1-xSe为垒转换成Zn1-xSe为阱,ZnSe为垒.瞬态光致发光结果表明,Zn1-xMnxSe/ZnSe超晶格中Mn++离子的激发态弛豫时间远大于Zn1=xMnxSe外延模中Mn++离子的弛豫时间,这可能是由于 相似文献
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Increases of emission intensities for Eu^3 at the S6 site relative to that at the C2 site were observed as UV excitation wavelength decreases from 300 nm to 200 nm in both bulk and nanocrystalline cubic Y2O3:Eu^3 . Decomposition of excitation spectra shows that the charge transfer band of Eu^3 at the S6 site lies in the high-energy side of that at the C2 site, resulting in that the energy transfer from the host prefers to the S6 site. Detailed emission and excitation spectral characteristics were analyzed and discussed. In addition, spectral red-shift were found in both charge transfer bands in nanocrystalline Y2O3: Eu^3 compared to the bulk material. The number ratio of S6 sites to C2 sites is also smaller in nanocrystalline Y2O3:Eu^3 than that in the bulk one. 相似文献
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Itiswellknownthatreductionofparticlesizeofcrystallinesystemcanresultinremarkablemodifica tionoftheirpropertieswhicharedifferentfromthoseofbulkbecauseofhighsurfacetovolumeratioandquan tumconfinementeffectofnanometermaterials .In1994 ,Bhargavaetal .reportedthatradiativetransi tionrateofMn2 ionsinZnSnanocrystalincreasedsixorderincomparisonwithbulkone[1] .Despitethisre sultwasstronglycriticizedlater ,studiesonnanosizedluminescentsemiconductorattractedgreatinter ests[2~ 4 ] .Sincecompoundsofra… 相似文献