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Itiswellknownthatreductionofparticlesizeofcrystallinesystemcanresultinremarkablemodifica tionoftheirpropertieswhicharedifferentfromthoseofbulkbecauseofhighsurfacetovolumeratioandquan tumconfinementeffectofnanometermaterials .In1994 ,Bhargavaetal .reportedthatradiativetransi tionrateofMn2 ionsinZnSnanocrystalincreasedsixorderincomparisonwithbulkone[1] .Despitethisre sultwasstronglycriticizedlater ,studiesonnanosizedluminescentsemiconductorattractedgreatinter ests[2~ 4 ] .Sincecompoundsofra… 相似文献
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Nanoparticles and nanowires of LAPO4: Eu phosphors were synthesized by hydrothermal method. Their luminescent properties including electronic transition, surface effect, and temperature-dependent luminescent characteristics were systemically studied and compared to the bulk powders. It can be concluded that in comparison with the bulk powders, the fluorescence intensity decreases in nanoparticles and nanowires, while the lifetime increases, indicating that the radiative transition rate decreases. The nonradiative transition rate in nanowires decreases than that in nanoparticles due to its decreased surface to volume ratio. The temperature-dependent experiments indicate that the thermal quenching in nanopowders becomes weaker than that in the bulk powders. 相似文献
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Nanoparticles and nanowires of LaPO4: Eu phosphors were synthesized by hydrothermal method. Their luminescent properties including electronic transition, surface effect, and temperature-dependent luminescent characteristics were systemically studied and compared to the bulk powders. It can be concluded that in comparison with the bulk powders, the fluorescence intensity decreases in nanoparticles and nanowires, while the lifetime increases, indicating that the radiative transition rate decreases. The nonradiative transition rate in nanowires decreases than that in nanoparticles due to its decreased surface to volume ratio. The temperature-dependent experiments indicate that the thermal quenching in nanopowders becomes weaker than that in the bulk powders. 相似文献
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介绍了ECDP纤维的主要性能,ECDP/腈混纺针织绒的纺纱工艺,对生产过程中出现的困难,提出了解决办法。 相似文献
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