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Preparation and High-Temperature Water-Gas Shift Catalytic Features of La1-xCexFeO3 Perovskite 总被引:1,自引:0,他引:1
Based on water-gas shift reaction mechanism and perovskite compounds characteristics, La1-xCexFeO3(.K) perovskite were designed and prepared as shift catalysts. DTA and XRD results reveal that La1-xCexFeO3 can be formed at 730-760℃ by mechanic-mix thermal decomposition method. Activity and heat-resisting tests show that La1-xCexFeO3 (.K) possess high thermal stability if x is less than or equals to 0.5. But when x is greater than 0.5, La1-xCexFeO3 (.K) will be converted into ceria and magnetite partially or completely under shift reaction conditions. In the case of x=0.5, the conversion of CO is about 68% at 530℃. Potassium can greatly improve the low temperature activity, but slightly reduces the high temperature activity, and has little impact on the thermal stability. La0.5Ce0.5FeO3(.K) is a promising chromium-free high temperature shift catalyst. 相似文献
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在40~200℃、0-16MPa范围内,运用Taylor分散技术实验测定了苯、吡啶和对硝基苯胺在乙醇中的无限稀释扩散系数。对于上述三种溶质,低温下扩散系数几乎不随压力变化;当温度超过100℃时,扩散系数随压力的增加明显下降,温度越高下降趋势越明显。使用修正的Wilke-Chang方程和Yang-Ma-Chen方程预测了高压乙醇体系的无限稀释扩散系数。与实验测量值的对比结果表明,温度低于100℃时修正的Wilke-Chang方程、Yang—Ma-Chen方程均能很好地预测高压乙醇体系的无限稀释扩散系数,平均偏差分别为7.3%和6.4%;但在高温条件下,除温度因素外.压力对缔合因子也有很大影响,从而使模型计算值远高于实验测定结果。吡啶和对硝基苯胺在乙醇中的无限稀释扩散系数未发现有文献报导。 相似文献
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规整填料表面点传质的可视化研究 总被引:1,自引:0,他引:1
采用显色化学反应的流体可视化方法研究规整填料表面上的点传质效果。并且用高精度彩色扫描仪进行后处理,把颜色值转化为数字值。通过风洞的标定特性来建立数字值和点传质量之间的关系,进而得到填料表面的点传质系数。由填料表面点传质系数的三维分布图,可清晰地看到在每两片填料交叉形成的任一传质单元当中,存在3个传质高峰。 相似文献
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INTRODUCTIONDispersionisveryimportanttothedesignoftricklebedreactorforbothchemicalandbiochemicalprocesses Thedegreeofdispersionofteninfluencesreactor performanceandscale up Thetraditionalmethodformodelingdispersionprocessesintricklebedreactorsisbasedon… 相似文献
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