排序方式: 共有56条查询结果,搜索用时 15 毫秒
1.
Microstructures and evolution mechanism of highly undercooled Ni-Pb hypermonotectic alloy 总被引:1,自引:0,他引:1
The microstructures and evolution mechanism of the undercooled Ni-20%Pb(molar fraction) alloy were investigated systematically by high undercooling solidification technique. The experiment results indicate that the morphology of α-Ni phase and the distribution of Pb element in undercooled Ni-20% Pb alloys change with the in-crease of undercooling. The main evolution mechanisms of α-Ni are dendrite remelting and recrystallization. Pb phase in the microstructure of Ni-20% Pb hypermonotectic alloy originates from L2 phase separated from the parent melt during the cooling process through immiscible gap and L2 phase formed at the temperature of monotectic trans-formation. The solubility of Ph element in α-Ni phase under high undercooling condition is up to 5.83% which is ob-viously higher than that under equilibrium solidification condition. The real reason that causes the solubility difference is distinct solute trapping. 相似文献
2.
研究了Si Zr B模壳涂层对准晶Al72Ni12Co16合金过冷度与凝固组织的影响规律。通过使用Si Zr B涂层模壳,在Al72Ni12Co16合金中获得了不同大小的过冷度,其最大值达到195K。根据经典形核理论,计算了熔体与涂层内壁间的润湿角。研究结果表明:Si Zr B涂层对过冷准晶Al72Ni12Co16合金熔体具有较强的抑制形核作用,因而可使大体积合金熔体获得深过冷。 相似文献
3.
4.
Y和Ce的同时加入使镁合金获得了优异的阻燃效果,实现了镁合金在大气条件下的无保护熔炼。AES和XRD表面分析结果表明,Mg-Y-Ce阻燃镁合金在高温下暴露于大气中时,合金表面会生成一层以Y2O3为主的氧化膜。干燥空气中,Mg-3Y-4.5Ce合金在773, 873和973 K下氧化时,其氧化动力学曲线遵循立方规律。基于高温氧化热力学,详细分析了Mg-Y-Ce合金在高温下的选择性氧化机制,并从电化学角度探讨了Y2O3膜的半导体特性及其对镁合金基体进一步氧化的阻碍机制 相似文献
5.
6.
The pentacene-based organic field effect transistor (OFET) with a thin transition metal oxide (WO3) layer between pentacene and metal (AI) source/drain electrodes was fabricated. Compared with conventional OFET with only metal AI source/drain electrodes, the introduction of the WO3 buffer layer leads to the device performance enhancement. The effective field-effect mobility and threshold voltage are improved to 1.90 em2/(V.s) and 13 V, respectively. The performance improvements are attributed to the decrease of the interface energy barrier and the contact resistance. The results indicate that it is an effective approach to improve the OFET performance by using a WO3 buffer layer. 相似文献
7.
采用累积叠轧法(ARB)对Mg/Al多层板材进行高周期ARB变形,利用光学显微镜(OM)、扫描电子显微镜(SEM)和能谱仪(EDS)研究了Mg/Al多层板材在ARB变形过程中的微观组织,并在拉伸试验机上测试板材的室温抗拉强度并通过扫描电子显微镜(SEM)观察拉伸试验后的断口形貌。结果表明,随着叠轧周期数的增加,Mg/Al多层复合材料层界面处生成并长大的金属间化合物明显细化,该化合物会逐渐呈连续多层状分布,同时也提高了层界面的结合程度。不过,Mg/Al多层复合材料的抗拉强度在叠轧过程中却呈现出不规则的变化趋势。 相似文献
8.
为了寻求Mg-Y-Ca阻燃镁合金的强化方法,详细研究了Y和Ca对Mg-4%Zn合金微观组织和力学性能的影响。结果发现,只要加入0.3%的Ca就可使晶粒大为细化,而随着Ca含量的增加,Mg-4%Zn-Ca合金的抗拉强度呈先快速增加后缓慢降低的趋势;随着Y含量的增加,凝固组织逐渐粒化,晶粒尺寸变小,相应地,其抗拉强度呈上升趋势。在综合考虑阻燃能力和力学性能的基础上,按照致密氧化膜的形成条件,选定Mg-4%Zn-3.5%Y-0.8%Ca为新型阻燃镁合金的初步成分。该合金能够在无保护条件下进行熔炼及浇注,且具有较好的力学性能,很有潜力发展成为综合性能优良的新型阻燃镁合金。 相似文献
9.
Good ignition-proof principle and mechanical properties were realized in Mg-Y-Ca-Zr alloy system.By adding Y and Ca elements,the ignition point of Mg-3.5Y-0.8Ca alloy was improved to over 1173 K,and the alloy could be melted in air without any protections.The ef-fect of Zr addition on the microstructures and mechanical properties of Mg-3.5Y-0.8Ca alloys were investigated,and Mg-3.5%Y-0.8%Ca-0.4%Zr alloy had good comprehensive properties with tensile strength of 190 MPa and elongation of 11%.Auger electron spectros-copy(AES) and X-ray diffraction(XRD) analysis revealed that the oxide film formed on the surface of Mg-3.5Y-0.8Ca alloy was mainly composed of Y2O3.Thermogravimetric measurements in dry air indicated that the oxidation dynamics curves measured at 773,873 and 973 K followed the cubic law.Moreover,the semiconductor characteristic of Y2O3 film and its effect on ignition-proof properties of Magnesium al-loys were discussed from the viewpoint of electrochemistry. 相似文献
10.