A study of ionization electrons drifting large distances in liquid and solid argon

A two liter gridded ionization chamber was built and operated repeatedly to study electron transport in liquid and solid argon over distances up to 10 cm in drift fields of 0.01–2 kV/cm. A detailed analysis of the ionization pulse shape was performed, yielding information on both the degree of purity of the liquid and the electron drift velocity. Argon with an impurity concentration less than 0.2 ppb oxygen equivalent was obtained with a simple purification system. The measured attenuation length extrapolates to 7.5 m for liquid argon and to 1 m for solid argon at a drift field of 1 kV/cm.     

Thiazolium‐Based Catalysts for the Etherification of Benzylic Alcohols under Solvent‐Free Conditions

Thiazolium and imidazolium hybrid materials were prepared by radical reactions between a mercaptopropyl‐modified SBA‐15 mesoporous silica and bis‐vinylthiazolium or bis‐vinylimidazolium dibromide salts. These hybrid materials were characterized by several techniques and were employed in the etherification reaction of 1‐phenylethanol. Solvent‐free conditions at 160 °C under different gas phases (oxygen, air, nitrogen and argon) were used. The thiazolium‐based material displayed excellent performances. Further studies were carried out using unsupported thiazolium salts, with or without a methyl group at the C‐2 position of the thiazolium moiety. These studies allowed us to propose a reaction mechanism. The supported thiazolium‐based material was successfully used in the etherification reaction of two other benzylic alcohols and also in seven consecutive cycles. This work represents the first use of thiazolium‐based compounds as catalysts for the etherification reaction of alcohols.

     

Different Stages of Quiescence,Senescence, and Cell Stress Identified by Molecular Algorithm Based on the Expression of Ki67, RPS6, and Beta-Galactosidase Activity

During their life span, cells have two possible states: a non-cycling, quiescent state (G0) and a cycling, activated state. Cells may enter a reversible G0 state of quiescence or, alternatively, they may undergo an irreversible G0 state. The latter may be a physiological differentiation or, following a stress event, a senescent status. Discrimination among the several G0 states represents a significant investigation, since quiescence, differentiation, and senescence are progressive phenomena with intermediate transitional stages. We used the expression of Ki67, RPS6, and beta-galactosidase to identify healthy cells that progressively enter and leave quiescence through G0-entry, G0 and G0-alert states. We then evaluated how cells may enter senescence following a genotoxic stressful event. We identified an initial stress stage with the expression of beta-galactosidase and Ki67 proliferation marker. Cells may recover from stress events or become senescent passing through early and late senescence states. Discrimination between quiescence and senescence was based on the expression of RPS6, a marker of active protein synthesis that is present in senescent cells but absent in quiescent cells. Even taking into account that fixed G0 states do not exist, our molecular algorithm may represent a method for identifying turning points of G0 transitional states that continuously change.     

Building as Interface: or,What Architects Can Learn from Interaction Designers

Walter Aprile and Stefano Mirti have been engaged as designers, researchers and teachers at Interaction-Ivrea, a technological research institute in northern Italy, since it was established by Telecom Italia and Olivetti in 2001. Here, the two reflect on the series of experiments they have undertaken at the intersection of interactive technology and architecture, analysing their own working systems and the means by which they have chosen to pursue interdisciplinary dialogue. Copyright © 2005 John Wiley & Sons, Ltd.     

Experimental study of retrofit solutions for damaged concrete bridge slabs

Accurate information on the actual performance of the structural system after retrofit is an essential part of a cost-effective bridge management program. This paper summarizes the results of a thorough experimental program concerning the reinforced concrete deck of a real 40 year-old viaduct. The structure exhibited severe damage at the extrados mainly due to environmental agents, chemical attack and action of asphalt milling machines. Samples of the deck were cut and carried to the laboratory in order to assess the possibility of retrofit. The design of retrofit was aimed at increasing the load carrying capacity through replacement of the deteriorated concrete with a new concrete overlay and strengthening in flexure for both negative (hogging) and positive (sagging) bending moments. Experimental testing on small specimens and nondestructive techniques were carried out to identify the material properties and to evaluate the level of damage. The bonding between external reinforcement and the original or new (standard or polymer-modified) concrete was assessed through single-shear push–pull tests on 33 prismatic specimens of 100 × 200 × 500 mm³ strengthened with CFRP strips. The efficiency of the retrofit techniques was checked at the structural level through four-point bending tests on eight slabs of 500 × 200 × 2000 mm³. This research can contribute to guidelines for concrete patch repair of FRP-retrofitted concrete bridge decks, to ensure better long-term performance under service loads and environmental effects.     

CFRP-Based Strengthening Technique to Increase the Flexural and Energy Dissipation Capacities of RC Columns

A strengthening technique, combining carbon fiber-reinforced polymer (CFRP) laminates and strips of wet layup CFRP sheet, is used to increase both the flexural and the energy dissipation capacities of reinforced concrete (RC) columns of square cross section of low to moderate concrete strength class, subjected to constant axial compressive load and increasing lateral cyclic loading. The laminates were applied according to the near surface mounted technique to increase the flexural resistance of the columns, while the strips of CFRP sheet were installed according to the externally bonded reinforcement technique to enhance the concrete confinement, particularly in the plastic hinge zone where they also offer resistance to the buckling and debonding of the laminates and longitudinal steel bars. The performance of this strengthening technique is assessed in undamaged RC columns and in columns that were subjected to intense damage. The influence of the concrete strength and percentage of longitudinal steel bars on the strengthening effectiveness is assessed. In the groups of RC columns of 8 MPa concrete compressive strength, this technique provided an increase of about 67% and 46% in terms of column’s load carrying capacity, when applied to undamaged and damaged columns, respectively. In terms of energy dissipation capacity, the increase ranged from 40%–87% in the undamaged columns, while a significant increase of about 39% was only observed in one of the damaged columns. In the column of moderate concrete compressive strength (29 MPa), the technique was even much more effective, since, when compared to the maximum load and energy dissipation capacity of the corresponding strengthened column of 8 MPa of average compressive strength, it provided an increase of 39% and 109%, respectively, showing its appropriateness for RC columns of buildings requiring upgrading against seismic events.