Workpiece surface modification using electrical discharge machining

Electrical discharge machining (EDM) is a widely used process in the mould / die and aerospace industries. Following a brief summary of the process, the paper reviews published work on the deliberate surface alloying of various workpiece materials using EDM. Details are given of operations involving powder metallurgy (PM) tool electrodes and the use of powders suspended in the dielectric fluid, typically aluminium, nickel, titanium, etc. Following this, experimental results are presented on the surface alloying of AISI H13 hot work tool steel during a die sink operation using partially sintered WC / Co electrodes operating in a hydrocarbon oil dielectric. An L8 fractional factorial Taguchi experiment was used to identify the effect of key operating factors on output measures (electrode wear, workpiece surface hardness, etc.). With respect to microhardness, the percentage contribution ratios (PCR) for peak current, electrode polarity and pulse on time were ˜24, 20 and 19%, respectively. Typically, changes in surface metallurgy were measured up to a depth of ˜30 μm (with a higher than normal voltage of ˜270 V) and an increase in the surface hardness of the recast layer from ˜620 HK_0.025 up to ˜1350 HK_0.025.     

Comparison of amperometric methods for detection of exocytosis from single pancreatic beta-cells of different species

Two methods for amperometric detection of exocytosis at single pancreatic beta-cells were compared. In the first, direct detection of insulin was accomplished using an insulin-sensitive chemically modified electrode. In the second, 5-hydroxytryptamine (5-HT) that had been allowed to accumulate within the beta-cell secretory vesicles was detected with a bare carbon electrode. The goal of the comparison was to determine whether 5-HT secretion was a valid marker of insulin secretion in single beta-cells. To aid in this comparison, some experiments involved simultaneous measurement of insulin and 5-HT at cells previously allowed to accumulate 5-HT. Upon application of common insulin secretagogues, current spikes resulting from detection of 5-HT, insulin, or both compounds were obtained indicative of secretion via exocytosis. The mean area of current spikes obtained from simultaneous measurements equaled the sum of the mean area of insulin and 5-HT measured independently. Additionally, analyses of the number of spikes obtained for detection of insulin, 5-HT, or both compounds were similar for several common secretagogues. These data support the hypothesis that accumulated 5-HT is released from insulin containing secretory vesicles, exclusively. In addition, measurement of insulin and 5-HT from beta-cells of different species was compared to determine whether a species dependence exists for the two methods compared here. Detection of 5-HT results in a similar number of spikes that are equivalent to insulin in frequency and amplitude in human, porcine, and canine beta-cells; however, in mouse and INS-1 beta-cells, 5-HT is more readily detected than insulin.     

Electrochemical superabrasive machining of a nickel-based aeroengine alloy using mounted grinding points

Brief design and manufacture considerations are detailed for a hybrid electrochemical grinding unit adapted from a vertical machining centre using a 40,000 rpm spindle and 500 A DC generator. Subsequently, experimental work is presented on the influence of tool bond systems, superabrasive grit type and electrical parameters when simultaneous ECM/grinding Udimet 720 using 10-15 mm diameter plain points. Single layer electroplated CBN tools produced G-ratios and maximum normal cutting forces of ∼451 and ∼45 N, respectively, compared to ∼128 and 557 N for equivalent diamond wheels. Data on workpiece roughness and overcut are also presented as are initial results for a fir tree shaped tool.     

Modelling of temperature and forces when orthogonally machining hardened steel

This paper initially considers heat generation in single-point metal cutting and the direct/indirect techniques employed to measure cutting temperatures. The development of analytical models of the cutting process is briefly reviewed, including more recent work involving finite element (FE) methods. Details are given of the different FE packages and formulation methods used by different researchers. Following on from this, an FE model is presented using FORGE 2® to simulate cutting forces and temperature distributions when orthogonal turning a hardened hot work die steel, AISI H13 (52HRC), with polycrystalline cubic boron nitride (PCBN) tooling. Experimental data from infrared chip surface temperature measurements and cutting force output are used to validate the model. Good correlation was obtained between experimental and modelled results for temperature; however, the FE analysis underestimated feed force results due to a lack of adequate workpiece property data and simplistic tool/chip friction assumptions.     

Optimism, coping, psychological distress, and high-risk sexual behavior among men at risk for acquired immunodeficiency syndrome (AIDS).

In a cohort of gay men responding to the threat of AIDS, dispositional optimism was associated with less distress, less avoidant coping, positive attitudes as a coping strategy, and fewer AIDS-related concerns. Men who knew they were seropositive for HIV were significantly more optimistic about not developing AIDS than men who knew they were seronegative for HIV. This AIDS-specific optimism was related to higher perceived control over AIDS and to active coping among seropositive men only and to health behaviors in both serostatus groups. There was no relation of optimism to risk-related sexual behavior. It is concluded that optimism is psychologically adaptive without necessarily compromising health behavior. It is also concluded that it is useful to distinguish between event-based optimistic expectations and dispositional optimism. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

A stitch in time: Self-regulation and proactive coping.

In a conceptual and temporal framework, derived from research on social cognition, social interaction, and stress and coping, the authors analyze the processes through which people anticipate or detect potential stressors and act in advance to prevent them or to mute their impact (proactive coping). The framework specifies five stages in proactive coping: (1) resource accumulation, (2) recognition of potential stressors. (3) initial appraisal, (4) preliminary coping efforts, and (5) elicitation and use of feedback concerning initial efforts. The authors detail the role of individual differences, skills, and resources at each stage. They highlight the unique predictions afforded by a focus on proactive coping and the importance of understanding how people avoid and offset potential stressors. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effects of social comparison direction, threat, and self-esteem on affect, self-evaluation, and expected success.

Two studies explored the conditions under which social comparisons are used to manage negative affect and naturalistic threats. Study 1 examined induced mood and dispositional self-esteem as determinants of affective responses to upward and downward comparisons. Consistent with a mood repair prediction, only low-self-esteem Ss in whom a negative mood had been induced reported improved mood after exposure to downward comparison information. Study 2 examined the impact of naturalistic threats on responses to comparison information. Relative to a no-comparison baseline, low-self-esteem Ss who had experienced a recent academic setback reported more favorable self-evaluations and greater expectations of future success in college after exposure to downward comparison information. These results remained significant after controlling statistically for general distress. Implications for downward comparison theory are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Preparation and characterization of cross-linked phospholipid bilayer capillary coatings for protein separations

Analysis of protein and peptide mixtures via capillary electrophoresis is hindered by nonspecific adsorption of analytes to the capillary walls, resulting in poor separations and quantitative reproducibility. Phospholipid bilayer (PLB) coatings are very promising for improving protein and peptide separations due to the native resistance to nonspecific protein adsorption offered by PLBs; however, these coatings display limited chemical and temporal stability. Here, we show the preparation and characterization of a highly cross-linked, polymerized phospholipid capillary coating prepared using bis-SorbPC. Poly(bis-SorbPC) PLB coatings are prepared in situ within fully enclosed fused silica capillaries via self-assembly and radical polymerization. Polymerization of the PLB coating stabilizes the membrane against desorption from the surface and migration in an electric field, improves the temporal and chemical stability, and allows for the separation of both cationic and anionic proteins, while preserving the native resistance to nonspecific protein adsorption of natural PLBs.     

Cutting temperatures when ball nose end milling γ-TiAl intermetallic alloys

Experimental results are presented for Ti–45Al–2Mn–2Nb + 0.8 vol% TiB₂XD and Ti–45Al–8Nb–0.2C alloys. Three approaches were employed involving a constantan-workpiece thermocouple arrangement, implanted K-type thermocouples and IR thermography. New and worn (~300 μm flank wear) coated carbide tools were used under dry conditions when down milling at 50–345 m/min, with workpieces mounted horizontally and at 45°. Despite slight variation in ancillary finishing parameters there was generally good agreement between data sets for the different evaluation techniques employed and for both alloys. Higher temperatures were measured with the workpiece at 45°, with constantan-workpiece thermocouple temperatures of 375 °C and 413 °C for new and worn tools respectively at 345 m/min.