Geckoprinting: assembly of microelectronic devices on unconventional surfaces by transfer printing with isolated gecko setal arrays

Developing electronics in unconventional forms provides opportunities to expand the use of electronics in diverse applications including bio-integrated or implanted electronics. One of the key challenges lies in integrating semiconductor microdevices onto unconventional substrates without glue, high pressure or temperature that may cause damage to microdevices, substrates or interfaces. This paper describes a solution based on natural gecko setal arrays that switch adhesion mechanically on and off, enabling pick and place manipulation of thin microscale semiconductor materials onto diverse surfaces including plants and insects whose surfaces are usually rough and irregular. A demonstration of functional ‘geckoprinted’ microelectronic devices provides a proof of concept of our results in practical applications.     

Variations in IC50 Values with Purity of Mushroom Tyrosinase

The effects of various inhibitors on crude, commercial and partially purified commercial mushroom tyrosinase were examined by comparing IC₅₀ values. Kojic acid, salicylhydroxamic acid, tropolone, methimazole, and ammonium tetrathiomolybdate had relatively similar IC₅₀ values for the crude, commercial and partially purified enzyme. 4-Hexylresorcinol seemed to have a somewhat higher IC₅₀ value using crude extracts, compared to commercial or purified tyrosinase. Some inhibitors (NaCl, esculetin, biphenol, phloridzin) showed variations in IC₅₀ values between the enzyme samples. In contrast, hydroquinone, lysozyme, Zn²⁺, and anisaldehyde showed little or no inhibition in concentration ranges reported to be effective inhibitors. Organic solvents (DMSO and ethanol) had IC₅₀ values that were similar for some of the tyrosinase samples. Depending of the source of tyrosinase and choice of inhibitor, variations in IC₅₀ values were observed.     

Gecko adhesion: evolutionary nanotechnology

If geckos had not evolved, it is possible that humans would never have invented adhesive nanostructures. Geckos use millions of adhesive setae on their toes to climb vertical surfaces at speeds of over 1ms-1. Climbing presents a significant challenge for an adhesive in requiring both strong attachment and easy rapid removal. Conventional pressure-sensitive adhesives (PSAs) are either strong and difficult to remove (e.g. duct tape) or weak and easy to remove (e.g. sticky notes). The gecko adhesive differs dramatically from conventional adhesives. Conventional PSAs are soft viscoelastic polymers that degrade, foul, self-adhere and attach accidentally to inappropriate surfaces. In contrast, gecko toes bear angled arrays of branched, hair-like setae formed from stiff, hydrophobic keratin that act as a bed of angled springs with similar effective elastic modulus to that of PSAs. Setae are self-cleaning and maintain function for months during repeated use in dirty conditions. Setae are an anisotropic 'frictional adhesive' in that adhesion requires maintenance of a proximally directed shear load, enabling either a tough bond or spontaneous detachment. Gecko-like synthetic adhesives may become the glue of the future-and perhaps the screw of the future as well.     

Computer-Mediated Word-of-Mouth Communication on RateMyProfessors.com: Expectancy Effects on Student Cognitive and Behavioral Learning

The purpose of this study was to experimentally test the influence of expectancies formed through computer-mediated word-of-mouth communication (WOM) on student learning. Increasingly, students rely on computer-mediated WOM through sites such as RateMyProfessors.com to aid in the process of information-gathering and course selection. It was hypothesized that students who received positive computer-mediated WOM about a course would demonstrate greater levels of cognitive and behavioral learning than would students who received no information or negative computer-mediated WOM. Results demonstrated the predicted effects for cognitive and behavioral learning. It was further hypothesized that observed expectancy effects would be mediated by affect toward learning. Results supported a partial mediational role for affect in the context of positive expectancies, but not negative expectancies. Results were discussed in terms of the role of computer-mediated WOM in generating expectations, the expectations-affect-behavior hypothesis, and the influence of student expectations on learning outcomes.     

Sex difference in polybrominated diphenyl ether concentrations of walleyes

Polybrominated diphenyl ether (PBDE) concentrations were determined for mature male and mature female walleyes (Sander vitreus) sampled from the Saginaw Bay population during 2007. PBDE concentrations in prey fish caught in the Saginaw River, the primary tributary to Saginaw Bay, and in Saginaw Bay during 2005 and 2007 also were determined. Mature male and mature female walleyes averaged 70.3 ng/g and 24.8 ng/g, respectively, in ΣPBDE, which was equal to the sum of concentrations of six PBDE congeners (BDE-28, BDE-47, BDE-99, BDE-100, BDE-153, and BDE-154). This sex difference was likely due to males spending more time in the Saginaw River system than females. Prey fish captured in the Saginaw River were roughly ten times higher in ΣPBDE than those caught in Saginaw Bay. BDE-47 was the predominant congener in both walleyes and prey fish, and this congener contributed about 50%, on average, to ΣPBDE. Congener profiles differed significantly between the two sexes of walleyes. In contrast, congener profiles of the prey fish did not differ significantly between the river-caught fish and the bay-caught fish. One plausible explanation for these congener profile results was that net trophic transfer efficiencies of PBDEs to walleyes from their prey were similar for all congeners except BDE-28, and that diet composition differed between the two sexes of walleyes.     

美国艾默生公司压缩机应用技术讲座——第三十二讲全年能效比：一种更好的制冷系统性能的量度

本文的目的是对现有的制冷空调系统的效率测量方法进行审视，并提出一种更为精确的衡量制冷系统的实际运行情况的新方法。     

Occupational safety: application of the job demand-control-support model

The utility of the job demand-control-support (JDCS) model for explaining psychological and physical well-being has been documented in a variety of settings. The current study's purpose was to assess the effectiveness of the JDCS model for predicting occupational safety well-being criteria (i.e., workplace injuries) based on two studies that employed samples of union blue-collar workers from two different regions of the United States. The JDCS model's buffer hypotheses were evaluated using hierarchical linear modeling. Both studies showed significant interactions between situational constraints and safety control to predict workplace injuries such that safety control buffered the negative effects of situational constraints. No significant three-way interaction between situational constraints, safety control, and safety climate on workplace injuries was found for either study. The implications of the present findings for both the JDCS model and occupational safety research are discussed.     

页岩气井水力压裂技术及环境问题探讨

水力压裂法开采天然气时,用高压将混有化学物质和沙子的水注入到地下页岩层,在高压下用水压裂岩石,同时用沙或其他物质支撑裂口,使页岩破碎释放出气体。国内外页岩气井水压裂增产技术,主要包括清水压裂、同步压裂、重复压裂和水平井压裂技术;深度研究页岩气井水力压裂带来的环境污染问题,主要包括甲烷污染和其他化学物质污染;分析目前在页岩气水力压裂开发中解决环境污染问题的具体补救措施,主要包括压裂返排废水的控制、对空气污染的控制和非常规气清洁开发的黄金准则。     

Injection molding with an additive manufactured tool

This study examines the viability of using additively manufactured injection molding tools for short run proof‐of‐concept plastic parts by assessing the quantity and quality of molded parts. Prototyping injection molded parts traditionally can be very expensive, but with improved additive manufacturing materials and techniques such costs could be reduced. To prove this, plastic tools were made by using PolyJet and Fused Deposition Modeling out of Digital ABS, FullCure 720, and ULTEM 1010 materials in this study. The test tools were then compared to the standard P20 metal tool by molding acetal, polycarbonate (PC), and polypropylene (PP) in each tool type. The molded parts were analyzed for processing effects on part shrink, physical, and mechanical properties. Testing concluded that parts molded with additively manufactured tools performed comparably to parts made on a P20 tool. However, the quantity of satisfactory parts molded in acetal and PC were consistent with the literature at 10–100 parts. Conversely, molding in PP suggested that processing with additive manufactured tools could exceed 250 parts. POLYM. ENG. SCI., 59:1911–1918, 2019. © 2019 Society of Plastics Engineers     

Rate-dependent frictional adhesion in natural and synthetic gecko setae

Geckos owe their remarkable stickiness to millions of dry, hard setae on their toes. In this study, we discovered that gecko setae stick more strongly the faster they slide, and do not wear out after 30 000 cycles. This is surprising because friction between dry, hard, macroscopic materials typically decreases at the onset of sliding, and as velocity increases, friction continues to decrease because of a reduction in the number of interfacial contacts, due in part to wear. Gecko setae did not exhibit the decrease in adhesion or friction characteristic of a transition from static to kinetic contact mechanics. Instead, friction and adhesion forces increased at the onset of sliding and continued to increase with shear speed from 500 nm s⁻¹ to 158 mm s⁻¹. To explain how apparently fluid-like, wear-free dynamic friction and adhesion occur macroscopically in a dry, hard solid, we proposed a model based on a population of nanoscopic stick–slip events. In the model, contact elements are either in static contact or in the process of slipping to a new static contact. If stick–slip events are uncorrelated, the model further predicted that contact forces should increase to a critical velocity (V*) and then decrease at velocities greater than V*. We hypothesized that, like natural gecko setae, but unlike any conventional adhesive, gecko-like synthetic adhesives (GSAs) could adhere while sliding. To test the generality of our results and the validity of our model, we fabricated a GSA using a hard silicone polymer. While sliding, the GSA exhibited steady-state adhesion and velocity dependence similar to that of gecko setae. Observations at the interface indicated that macroscopically smooth sliding of the GSA emerged from randomly occurring stick–slip events in the population of flexible fibrils, confirming our model predictions.