Structural and chemical analysis of C : H,O /Si : H,O multilayers deposited by reactive RF sputtering

Hydro-oxygenated carbon (C : H,O) and silicon (Si : H,O) layers are deposited by RF sputtering of graphite and silicon targets in a mixture of argon, hydrogen and oxygen gases. C : H,O/Si : H,O/C : H,O/Si : H,O... multilayers are obtained by sequential deposition of C : H,O and Si : H,O layers. Infrared (IR) spectroscopy, Grazing Incidence X-ray Diffraction (GIXD) and X-ray Photoelectron Spectroscopy (XPS) techniques have been used to analyse the formed multilayers. The IR spectra made on as deposited structures show the presence of Si---C, Si---O, C---O, Si---H, C---H and C=C bonds. This result indicates an interfacial reactivity between Si : H,O and C : H,O layers. The latter result is confirmed by the XPS measurements. After an annealing at 850°c for two hours under argon atmosphere (10^-3 mbar), the concentration of the Si---C bonds is increased by a factor two while the Si---H and C---H bonds disappear complet The GIXD measurements show that the multilayers are amorphous when annealed below 750°C, and they are crystallized with the formation of the α-SiC phase if the heat treatment is made at 850°C. The mean size of the microcrystallites is 50 Å about.     

Iron pyrite films prepared by sulfur vapor transport

Iron films deposited via thermal evaporation, with a thickness between 100 and 250 nm, were converted into FeS₂ by open sulfur transport using nitrogen as a gas vector. The films thus obtained constituted a single pyrite phase and were optically highly absorbing. The sulfurization process was optimized. As a result, sample temperature and conversion time were found to be the major determining parameters. The films were characterized using several methods. The crystallinity and phase identification were determined by X-ray diffractometry. Scanning electron microscopy showed a homogeneous surface of both iron and pyrite layers. Optical transmission measurements confirmed the highly absorbing character of FeS₂ and allowed the determination of direct (1.35 eV) and indirect (0.82 eV) transitions.     

Adaptive speckle imaging interferometry (ASII): New technology for advanced drying analysis of coatings

In this work a new optical technology, ASII, is presented, for the study of film formation from all kinds of dispersed systems, such as latexes, emulsions or solvent-borne suspensions. Various film-forming products have been investigated, including water-borne coatings, on various types of substrates. A wide range of information can be extracted such as objective drying times (dust-free, dry-hard times, etc) or mechanism taking place, thereby offering new possibilities to analyse film formation from complex colloidal systems.     

Coherent addition of adjacent lasers by forked eigenstate operation

Forked laser eigenstates are shown to provide a powerful tool both to phase lock spatially separated laser oscillators and to add their powers coherently into a TEM(00) output beam. Coherent addition of the powers extracted from two fiber-coupled diode-pumped Nd:YAG channels is theoretically and experimentally demonstrated. Pure TEM(00) oscillation is obtained with a 20% optical-to-optical conversion efficiency. The coherence of the two-propagation-axis laser is proved, and single-frequency operation is demonstrated. The scalability of the scheme is discussed.     

Continuous planar phospholipid bilayer supported on porous silicon thin film reflector

Reconstituting artificial membranes for in vitro studies of cell barrier mechanisms and properties is of major interest in biology. Here, artificial membranes supported on porous silicon photonic crystal reflectors are prepared and investigated. The materials are of interest for label-free probing of supported membrane events such as protein binding, molecular recognition, and transport. The porous silicon substrates are prepared as multilayered films consisting of a periodically varying porosity, with pore dimensions of a few nanometers in size. Planar phospholipid bilayers are deposited on the topmost surface of the oxidized hydrophilic mesoporous silicon films. Atomic force microscopy provides evidence of continuous bilayer deposition at the surface, and optical measurements indicate that the lipids do not significantly infiltrate the porous region. The presence of the supported bilayer does not obstruct the optical spectrum from the porous silicon layer, suggesting that the composite structures can act as effective optical biosensors.     

Building blocks for a two-frequency laser lidar-radar: a preliminary study

A new principle of lidar-radar is theoretically and experimentally investigated. The proposed architecture is based on the use of an rf modulation of the emitted light beam and a direct detection of the backscattered intensity. Use of a radar-processing chain allows one to obtain range and Doppler measurements with the advantages of lidar spatial resolution. We calculate the maximum range of this device, taking into account different possible improvements. In particular, we show that use of a pulsed two-frequency laser and a spatially multimode optical preamplification of the backscattered light leads to calculated ranges larger than 20 km, including the possibility of both range and Doppler measurements. The building blocks of this lidar-radar are tested experimentally: The radar processing of an rf-modulated backscattered cw laser beam is demonstrated at 532 nm, illustrating the Doppler and identification capabilities of the system. In addition, signal-to-noise ratio improvement by optical pre-amplification is demonstrated at 1.06 microm. Finally, a two-frequency passively Q-switched Nd:YAG laser is developed. This laser then permits two-frequency pulses with tunable pulse duration (from 18 to 240 ns) and beat frequency (from 0 to 2.65 GHz) to be obtained.     

Comparison of Modeling Approaches for the Capacitance–Voltage and Current–Voltage Characteristics of Advanced Gate Stacks

In this paper, we compare the capacitance-voltage and current-voltage characteristics of gate stacks calculated with different simulation models developed by seven different research groups, including open and closed boundaries approaches to solve the Schroumldinger equation inside the stack. The comparison has been carried out on template device structures, including pure SiO₂ dielectrics and high-kappa stacks, forcing the use of the same physical parameters in all models. Although the models are based on different modeling assumptions, the discrepancies among results in terms of capacitance and leakage current are small. These discrepancies have been carefully investigated by analyzing the individual modeling parameters and the internal quantities (e.g., tunneling probabilities and subband energies) contributing to current and capacitance     

Modification of porous carbon tubes with enzymes: application for biofuel cells

Enzyme biocatalyst assemblies on electrode surfaces can be used to construct efficient membrane-less biofuel cells. The present study reports on the construction of biocatalytic oxygen electrodes based on the modification of porous carbon tubes with laccase and 2,2′-azinobis-(3-ethylbenzothiazoline−6-sulfonate) (ABTS²⁻) as mediator, co-immobilized within electrochemically polymerized films. Porous carbon tubes are used as original conducting support for enzyme incorporation and for the transport of dissolved dioxygen solution via diffusive flow through the porosity. The activity of the laccase immobilized on the porous carbon support is determined. Performance of the biocathodes towards the reduction of dioxygen to water is demonstrated by chronoamperometry at +0.4 V vs. Ag/AgCl in citrate/phosphate buffer pH 3. Moreover, the current–voltage behaviour of the biocathodes show high current densities at pH 3 (a current peak equal to 280 μA cm⁻² for the biocathode based on both entrapped laccase and mediator) and a low oxygen reduction overvoltage compared to platinum electrode.     

The transfer of TEM00 and TEM01 beams through a hard-aperture

Abstract

We determine the far-field divergence angle θ ₀₀ (θ ₀₁) resulting from the diffraction of a TEM₀₀ (TEM₀₁) beam incident on a circular aperture. It is demonstrated that, with a suitable choice of the aperture radius, the ratio θ ₀₁/θ ₀₀ is enhanced to about 2, while its value is 1.64 without the aperturing effect. It is shown that this effect allows high discrimination between TEM₀₀ and TEM₀₁ modes either in the case of a spatial filter or in the case of an apertured resonator.     

Characterization of yttria-stabilized zirconia thin films deposited by electron beam evaporation on silicon substrates

Structure, phase composition and electrical conductivity of thin yttria-stabilized zirconia (YSZ) films deposited by electron beam evaporation on a silicon (1 0 0) substrate at different temperatures i.e. room temperature (r.t.), 700 and 830°C, as well as the quality of the YSZ–Si interface have been investigated. The phase composition was verified by Raman spectroscopy and by infrared (i.r.) transmission measurements. The structure of films changed in agreement with their electrical conductivity depending on the deposition temperature. Both structure and thereby electrical conductivity were influenced by the high concentration of Y2O3 stabilizer used and by the post-deposition thermal treatment of films. The deposition temperature was also important in determining the quality of the YSZ–Si interface and hence the accessible sweep of the surface potential. The capacitance–voltage characteristics of the metal–insulator–semiconductor (MIS) structures incorporating YSZ films measured at r.t. showed hysteresis and positive shifts of the flat-band voltages. © 1998 Chapman & Hall