PH值对化学沉积制备CdS薄膜性质的影响

实验研究了pH值对化学沉积制备CdS薄膜性质的影响。表明：在柠檬酸钠作为络合剂的体系中随着溶液中氨水浓度的提高CdS薄膜会发生相变，从立方相变为六方相，即当氨水浓度为0．31M时，得到立方相的CdS薄膜；而当氨水的浓度大于0．51M时，得到六方相的CdS薄膜。氨水浓度的提高也使得CdS薄膜的形貌有了很大的改善，且制备得到的CdS薄膜从富CA变为富S，但是薄膜仍是n型。氨水浓度对CdS薄膜的光学性质也有很大的影响，随着氨水浓度的提高所得到的CdS薄膜的禁带宽度增大。     

高压热处理对氧沉淀低温形核的影响

研究了外加高压(1GPa)下对450℃热处理硅片中氧沉淀行为的影响.透射电镜观察表明相对于大气压下热处理的样品,高压处理的样品会产生密度更高、尺寸更小的氧沉淀,表明高压有利于小直径氧沉淀的生成.电学性能测试表明,高压下处理的样品其热施主生成浓度和生成速率远远高于常压下处理的样品,这表明热施主与低温热处理过程中生成的高浓度氧沉淀核心有密切的关系.     

基于星敏感器的姿态优化估计算法

对于采用星敏感器的航天器姿态确定问题,提出了一种快速的姿态优化估计方法;首先,根据Rodrigues参数和观测向量之间的线性关系,引入四元数,构造了不同的非奇异的优化准则;其次,借助四元数,求解了基于该准则的姿态优化算法;误差协方差分析和数值仿真结果表明,该算法与著名的QUaternion ESTmation(QUEST)算法相比,在相同的操作系统环境下,具有相同的姿态估计精度,但计算速度更快,对两种算法选取间隔为2000次的仿真步长,统计数据长度为100个采样点,最后对结果加权求平均值,统计结果显示仅为QUEST的三分之一;这种姿态优化估计方法具有一定的工程应用价值。     

铸造多晶硅中氧的热处理行为研究

研究了铸造多晶硅中不同温度单步退火下氧沉淀的形成规律。实验发现，单步热处理工艺下铸造多晶硅中氧沉淀的形成规律和单晶硅的基本相似，但是在铸造多晶硅中形成氧沉淀的量明显高于直拉单晶硅中氧沉淀的量；在含高密度位错的单晶硅中形成氧沉淀的量远高于无位错单晶硅中氧沉淀的生成量，而有晶界的多晶硅中形成氧沉淀生成量仅稍微高于无晶界单晶硅中氧沉淀生成量。以上结果表明，铸造多晶硅中位错对氧沉淀的形成有明显的促进作用，而晶界则对氧沉淀的促进作用不是很显著。最后，基于实验结果讨论了铸造多晶硅中初始氧浓度，位错和晶界对氧沉淀影响的机理。     

Influence of electroplating conditions on magnetic properties of Fe-36wt.% Ni alloy film

A Fe-Ni soft magnetic film was prepared in sulphate solution by electroplating. The influences of the molar ratio of n [Fe2+ ]/ n [Ni2+ ], current density, bath temperature, pH and L-ascorbic acid concentration on magnetic properties of Fe-Ni alloy film were investigated. The results show that the saturated flux density(BS) of the film increases initially and decreases after it reaches the specific value with the increase of n [Fe2+ ]/ n [Ni2+ ] molar ratio, current density, bath temperature and pH. However, the relationship between L-ascorbic acid concentration and B S keeps linear. It is observed that the coercive force( Hc) is enhanced with the increase of n [Fe2+ ]/ n [Ni2+ ] molar ratio, current density and pH. By comparison, when the bath temperature increases, Hc always decreases. With the increase of L-ascorbic acid concentration, the coercive force increases initially and then decreases.     

Study on the Propagation Law of Shock Wave Pressure in Tunnels with Different Materials

The propagation of shock wave pressure in the tunnel is greatly affected by the tunnel structure, shape, material and other factors, and there are great differences in the propagation law of shock wave pressure in different kinds of tunnels. In order to study the propagation law of shock wave pressure in tunnels with different mate-rials, taking the long straight tunnel with the square section as an example, the AUTODYN software is used to simulate the explosion of TNT in the concrete, steel and granite tunnel, and study on the variation law of shock wave pressure in tunnels with different materials. By using dimensional analysis and combined with the results of numerical simulation, a mathematical model of the propagation law of shock wave pressure in the tunnel is established, and the effectiveness of the mathematical model is verified by making the explosion test of the warhead in the reinforce concrete tunnel. The results show that the same mass of TNT explodes in the tunnel with different materials, and the shock wave overpressure peak at the same measuring point is approximate in the near field. However, there is a significant difference in the middle-far fields from the explosion center, the shock wave overpressure peak in the steel tunnel is 20.76% and 34.82% higher than that of the concrete and the granite tunnel respectively, and the shock wave overpressure peak in the concrete tunnel is 24.91% higher than that in the granite tunnel. Through the experimental verification, getting the result that the maximum relative deviation between the measured value and the calculated value of the shock wave overpressure peak is 11.85%. Therefore, it is proved that the mathematical model can be used to predict the shock wave overpressure peak in the tunnel with different materials, and it can provide some reference for the power evaluation of warhead explosion in the tunnel.     

硅基单结太阳能电池的制备技术、缺陷及其性能的研究

首先综述了硅基单结太阳能电池的分类、制备方法及进展,介绍了化学气相沉积法、液相外延法(LPPE)、金属诱导结晶法(MIC)、磁控溅射法以及分子束外延法等各种硅基太阳能电池的制备方法,阐述了各种制备工艺的优缺点。其次,总结了单晶硅、多晶硅以及非晶硅太阳能电池在组织结构、缺陷方面的研究现状。最后,对硅基太阳能电池的机械、电学、光学以及光电性能等方面的研究进展做了论述。     

热处理温度及掺硼对富硅氧化硅发光的影响

利用等离子体增强化学气相沉积制备了未掺杂与掺硼富硅氧化硅薄膜。在高纯N2气氛中经过600℃、800℃和1100℃热处理,发现随着热处理温度的升高,富硅氧化硅薄膜的光致发光发生了明显红移。这表明薄膜的光致发光来源逐渐由薄膜中的发光中心演变为硅纳米晶。在经过1100℃热处理的未掺杂与掺硼样品中,掺硼样品光致发光强度有明显减弱,这是由俄歇复合效应引起的。此外,在ESR测试谱中,掺硼样品的g因子为2.0020,这表明掺硼可以在薄膜基体和硅纳米晶之间的界面引入发光中心。     

全连续式冷轧工艺特征分析

全连续式冷轧工艺的发展对冷轧带钢的生产带来了重大的变革。然而能形成全连续轧制的条件也是有一定限度的,本文即是结合我国引进的宝钢2030mm轧机从入口段带钢运行条件导出带长与速度的关系式,从主电机功率的利用率分析了全连轧与常规轧制的差异。