Carbon deposition from acetone during oxidation of iron—the effects of chromium and nickel

Carbon deposition on iron, and its alloys with nickel and chromium, has been produced by catalytic decomposition of acetone in carbon dioxide at 700°C. Nickel has been identified as the major promoter of carbon deposition under these conditions, although iron is also active. When the conditions favoured the occurrence of carbon deposition, the morphology of the magnetite formed was changed from a crystalline structure to a type resembling “breakaway” oxide. Filamentary carbon was formed in all cases, the diameter of the filaments being dependent on whether chromium was present or absent in the substrate material. Initiation of filamentary growth on these materials is discussed.     

Nanobeam electron diffraction and high resolution imaging analysis of InN films grown on sapphire

A JEOL JEM-3000F field emission, analytical, high-resolution transmission electron microscope (HRTEM) was used to study InN films grown on sapphire substrates. It was found that, while the InN films maintained the hexagonal (wurtzite) structure, InN nanodomains with a cubic (zincblende) structure were also formed in the films. Nanobeam electron diffraction techniques were applied for identification of the cubic phase. The identification of the cubic InN was confirmed by HRTEM structural imaging. The cubic InN nanodomains are 3-10 nm in diameter, and are orientated in two different orientations with their [110](cubic) and [110](cubic) axes parallel to each other and their (111)(cubic) planes parallel to the (0001)(hex) plane of the hexagonal InN.     

Fast imaging of hard x rays with a laboratory microscope

An improved x-ray microscope with a fully electronic CCD detector system has been constructed that allows improved laboratory-based microstructural investigations of materials with hard x rays. It uses the Kirkpatrick-Baez multilayer mirror design to form an image that has a demonstrated resolution of 4 mum at 8 keV (Cu K(alpha) radiation). This microscope performs well with standard sealed-tube laboratory x-ray sources, producing digital images with 20-s exposure times for a 5-mum Au grid (a thickness of two absorption lengths).     

Accuracy of self-reported data for estimating crash severity

Estimated traveling speed and speed limit have typically been used in population-based surveillance data to estimate crash severity. The accuracy of these measures in predicting crash severity is unknown. The Partners for Child Passenger Safety (PCPS) surveillance system offers a unique opportunity to compare these measures, as well as a novel measure of crash severity, “self-report” delta-V, to the accepted measure of delta-V estimated during detailed crash-investigations in 118 crashes. This “self-report” delta-V was computed from the estimated traveling speeds and direction of impact obtained from telephone interviews with drivers. These “self-reported” delta-V estimates are modestly associated with crash-investigation delta-V estimates, with the degree of association a function of the direction of impact: when the respondent was struck from the rear, the degree of association is strong; frontal, side, and single-vehicle crashes yield weaker associations. This “self-reported” delta-V measure, however, is a substantial improvement over use of estimated traveling speed or speed limit only.     

Competitive binding of Pu and Am with bone mineral and novel chelating agents

Effective direct removal of actinides such as Pu and Am from bone in vivo has not been accomplished to date, even with the strong chelating agents CaNa3DTPA or ZnNa3DTPA. This study, using an established in vitro system, compared removal of Pu and Am bound to bone mineral by ZnNa3DTPA and 10 chelating agents designed specifically to sequester actinides, including Pu and Am. Ligands tested were tetra, hexa, and octadentate, with linear or branched backbones containing sulfocatechol [CAM(S)], hydroxycatechol [CAM(C)], hydroxipyridinone (1,2-HOPO, Me-3,2-HOPO), or hydroxamate functional groups. The wide range of Pu and Am removal exhibited by the test ligands generally agreed with their metal coordination and chemical properties. The most effective agents for Pu (100 microM concentration, 24-48 h contact) are all octadentate as follows: 3,4,3-LICAM(S) (54% unbound); 3,4,3-LICAM(C) (6.2%); 3,4,3-LI(1,2-HOPO) (3.8%); H(2,2)-(Me-3,2-HOPO) (2.2%) and DFO-(1,2-HOPO) (1.8%). The other ligands removed less than 1% of the bound Pu; and ZnNa3DTPA removed only 0.086%. The most effective ligands for Am removal (100 microM, 24-48 h contact) are as follows: octadentate H(2,2)-(Me-3,2-HOPO) (21% unbound); 3,4,3-LI(1,2-HOPO) (14.5%) and 3,4,3-LICAM(C) (5.9%); hexadentate TREN-(Me-3,2-HOPO) and TREN-(1,2-HOPO) (9.6%); and tetradentate 5-LIO(Me-3,2-HOPO) (5.2%). Am removal by ZnNa3DTPA was about 1.4%. Among the ligands presently considered for possible human use, only 3,4,3-LI(1,2-HOPO) removed potentially useful amounts of both Pu and Am from bone mineral.     

Fast Filtering and Smoothing for Multivariate State Space Models

This paper investigates a new approach to diffuse filtering and smoothing for multivariate state space models. The standard approach treats the observations as vectors, while our approach treats each element of the observational vector individually. This strategy leads to computationally efficient methods for multivariate filtering and smoothing. Also, the treatment of the diffuse initial state vector in multivariate models is much simpler than in existing methods. The paper presents details of relevant algorithms for filtering, prediction and smoothing. Proofs are provided. Three examples of multivariate models in statistics and economics are presented for which the new approach is particularly relevant.     

Investigation of solid particle number measurement: Existence and nature of sub-23 nm particles under PMP methodology

A Particle Measurement Program (PMP) compliant system, an AVL advanced particle counter (APC) and an alternative volatile particle removal system, a catalytic stripper (CS) were evaluated and compared for measuring solid particle number (PN) emissions. The evaluations and comparisons were conducted using sulfuric acid and hydrocarbon particles as model volatile particles in laboratory tests, and diluted exhaust from a diesel particle filter (DPF)-equipped heavy-duty diesel vehicle operated on a heavy-duty chassis dynamometer under steady speed conditions at two different engine loads. For the laboratory test, both the APC and CS removed more than 99% of the volatile particles in terms of PN when using aerosols composed of pure sulfuric acid or hydrocarbons. When using laboratory test aerosols consisting of mixtures of sulfuric acid and hydrocarbons more than 99% of the particles were removed by the APC but the surviving particles were no longer entirely volatile, 12–14% were solid. For the chassis dynamometer test, PN emissions between 3 and 10 nm downstream the APC were ∼2 and 7 times higher than the PN emissions of particles above 10 nm at the 74% and 26% engine load, respectively. At the 26% engine load, PN level of the 3–10 nm particles downstream the APC were significantly higher than that in the dilution tunnel, demonstrating that the APC was making 3–10 nm particles. The PN emission of 3–10 nm particles downstream the APC was related to the heating temperature of the APC evaporation tube, suggesting these particles are artifacts formed by renucleation of semivolatiles. Considerably fewer particles between 3 to 10 nm were seen downstream of the CS for both engine loads due mainly to removal of semivolatile material by the catalytic substrates, although some of this difference could be attributed to diffusion and thermophoretic losses. The findings of this study imply that improvement of the current PMP protocol would be necessary if the PMP were to be used in other applications where the PN emissions of particles below 23 nm are important.