Groundwater Utilization and Management in the State of Kuwait

Abstract

The main brackish groundwater resources in the State of Kuwait are the groundwater located in the Kuwait Group and the Dammam limestone aquifers. Most of the groundwater used in the State of Kuwait is for irrigation, some part of it is used for domestic purposes and for small scale industries. Since rainfall is seasonal and is less than the annual evaporation, the recharge from rainfall is negligible. Water levels in both the aquifers are highly affected by the pumping rate from each well. The groundwater is extracted heavily resulting in decline of water levels and the deterioration of groundwater quality though there is underflow from Saudi Arabia. Improvement of the groundwater management is essential for maintaining long-term productivity of the aquifers in the State of Kuwait.     

Microstructure and phase composition of cordierite-based co-clinker

The aim of this work is to study the effect of phase composition and microstructure of cordierite-based co-clinkers on the electrical properties and coefficient of thermal expansion of cordierite briquettes. To achieve this aim talc and kaolinite samples were collected from quarries in the Egyptian desert. The samples are characterized using XRD, XRF, polarized light, cathodoluminescence and SEM microscopy attached with EDAX, in addition to X-ray micro-computed tomography (3D- µXCT). The electrical properties and coefficient of thermal expansion of the cordierite briquettes are determined using HiTESTER instrument and automatic Netzsch DIL402 PC dilatometer, respectively.Five talc-based batches were shaped and fired in the temperature range 1000–1350 °C for 2 h. The microstructural and physical characteristics of the resulted cordierite-based co-clinkers depend mainly on the viscosity of the liquid phase developed during firing. The microchemistry of the cordierite briquettes confirms their enrichment of both cordierite and ferroan-cordierite crystallized directly from locally developed melts. The dielectric constant and loss factor values for cordierite briquettes allow their possible use as insulator components in electronic applications.     

Novel Dipyridinium Lipophile-Based Ionic Liquids Tethering Hydrazone Linkage: Design,Synthesis and Antitumorigenic Study

Novel dicationic pyridinium ionic liquids tethering amphiphilic long alkyl side chains and fluorinated counter anions have been successfully synthesized by means of the quaternization of the dipyridinium hydrazone through its alkylation with different alkyl halides. The resulting halogenated di-ionic liquids underwent a metathesis reaction in order to incorporate some fluorinated counter anions in their structures. The structures of all the resulting di-ionic liquids were characterized by several spectroscopic experiments. The antitumorigenic activities of the investigated compounds were further studied against three different human lung cancer cell lines. Compared to the standard chemotherapeutic agent, cisplatin, the synthesized di-ionic liquids exerted equal, even more active, moderate, or weak anticancer activities against the various lung cancer cell lines under investigation. The observed anticancer activity appears to be enhanced by increasing the length of the aliphatic side chains. Moreover, dicationic pyridinium bearing a nine carbon chain as counter cation and hexafluoro phosphate and/or tetrafluoro bororate as counter anion were selected for further evaluation and demonstrated effective and significant antimetastatic effects and suppressed the colonization ability of the lung cancer cells, suggesting a therapeutic potential for the synthesized compounds in lung cancer treatment.     

Hydrochemical investigation on the clastic and carbonate aquifers of Kuwait

The field pH and contents of basic cations, anions, total alkalinity and other aqueous species have been measured in 89 groundwater samples collected from clastic sediments and carbonate aquifers of Kuwait. The mean molar ratio of Mg²⁺/Ca²⁺ is 0.63 and 0.48 for the carbonate and clastic aquifers respectively, indicating that the groundwater of the carbonate aquifer is in equilibrium with calcite and dolomite, the calculated mean PCO₂ of the clastic and carbonate aquifers suggesting a deep closed environment system. The clastic aquifer is supersaturated with respect to calcite, aragonite, quartz and chalcedony, undersaturated to near-saturated with dolomite and undersaturated with respect to gypsum, anhydrite and halite, whereas the carbonate aquifer is supersaturated with respect to dolomite, calcite, aragonite and quartz but undersaturated with anhydrite, gypsum and halite. The salinity of both aquifers increases in the direction of flow. The water types are dominantly NaCl and Na₂SO₄ in the clastic aquifer and Na₂SO₄, CaSO₄ and NaCl in the carbonate aquifer. Electronic Publication     

Natural radioactivity contents in tobacco and radiation dose induced from smoking

One of the causative factors for cancer-inducing mechanisms in humans is radioactive elements present in tobacco leaves used in the manufacture of cigarettes. Smoking of tobacco and its products increases the internal intake and radiation dose due to naturally occurring radionuclides that are considered to be one of the most significant causes of lung cancer. In this work, different commercial types of cigarettes, cigar and moassel were collected from market. Naturally occurring radionuclides (226)Ra and (214)Bi ((238)U series), (228)Ac and (228)Ra ((232)Th series), (40)K and man-made (137)Cs were measured in tobacco using gamma-ray spectrometer. Results show that the average concentrations of (238)U, (232)Th and (40)K were 4.564, 3.940 and 1289.53 Bq kg(-1), respectively. This reflects their origin from the soil by root uptake and fertilisers used in the cultivation of tobacco plants. Concentration of (137)Cs was 0.348 Bq kg(-1) due to root uptake or deposition onto the leaf foliage. For smokers, the annual effective dose due to inhalation of (238)U varied from 49.35 to 139.40 μSv(-1) (average 104.27 μSv y(-1)), while of (232)Th from 23.86 to 111.06 μSv y(-1) (average 65.52 μSv y(-1)). The annual effective dose resulting from (137)Cs was varied from 10.96 to 24.01 nSv y(-1) (average 19.41 nSv y(-1)).     

Hydrogeochemical study of the clastic aquifer in the Umm Gudair field,Kuwait

The Kuwait Group aquifer is a major source of brackish groundwater in the State of Kuwait. The aquifer ranges in thickness from 150–400 m. In the Umm Gudair well field, the water has total dissolved solids ranging from 3,130 to 4,790 mg/l. According to the Sulin classification, all the Kuwait Group aquifer samples are characterized as Cl–Mg or Cl–Ca genetic water types. The chemical data indicate that the aquifer is generally in equilibrium with respect to calcite, dolomite and gypsum but undersaturated with respect to halite and polygorskite. The study has indicated that de-dolomitization is the major geochemical process controlling the chemistry of this aquifer, increasing the major complexes of sulphate and carbonate due to the dissolution of gypsum. The ratio of Cl/Na indicates that the Na⁺ ions have been taken from the Kuwait Group aquifer by reverse ion exchange.      

Aldehyde Dehydrogenases Expression in Corneal Epithelial Cells with Limbal Stem Cell Deficiency

Purpose: The purpose of the present study is to investigate the expression of aldehyde dehydrogenases (ALDHs) in rabbit corneas with limbal stem cell deficiency (LSCD) and corneas treated with cultured autologous oral mucosa epithelial cell sheet CAOMECS designed to reconstruct the ocular surface with LSCD. Methods: New Zealand white rabbit autologous oral mucosal epithelial cells were isolated from a buccal biopsy and cultured to be grafted back onto corneas of rabbit model of LSCD. Immunofluorescent staining and Western blot analysis were used to compare the expression of ALDH1A1 and ALDH1A3 in healthy, LSCD-diseased, CAOMECS treated corneas. Human oral mucosal and corneal epithelial cells (OMECS and CECs) were cultured and treated with retinoic acid (RA) to further investigate the expression of ALDHs. Results: In healthy corneas, ALDH1A1 and ALDH1A3 were markedly expressed in basal cells of corneal epithelium. In LSCD diseased corneas, ALDH1A1 and ALDH1A3 were markedly expressed in the conjunctivalized apical epithelial cells, the goblet cells, and the stroma. CAOMECS grafted corneas showed a decreased expression of ALDHs as compared to LSCD diseased corneas. Western blot analysis confirmed the up regulation of ALDH1A1 and ALDH1A3 expression in LSCD-diseased corneal epithelial cells. CAOMECS expressed low levels of ALDH1A1 and ALDH1A3, as compared to diseased CECs (D-CEC). When ALDH1A3 was up regulated by retinoic acid treatment in OMECS, Pax-6 expression was down regulated, suggesting a decrease in regenerative capacity when ALDH enzymes are up regulated. Conclusions: These findings report for the first time the up regulation of ALDH1A1 and ALDH1A3 in rabbit corneas with LSCD and document that CAOMECS grafting used to reconstruct corneal epithelium may reduce the expression levels of ALDH enzymes.     

Aquifer characteristics and water quality of Miocene–Pleistocene sediments, Kuwait

Al-Atraf is one of the water well fields of Kuwait supplying Kuwait City with the brackish groundwater obtained from the Kuwait Group aquifer of Miocene–Pleistocene age. The study determined the hydrogeological and hydrochemical characteristics of the groundwater in order to identify the major chemical processes that influence the groundwater quality of the study area. The results of the aquifer test analyses indicate that the Kuwait Group is a confined to semi-confined aquifer, with a transmissivity ranging between 62 and 321 m²/day. The flow net analysis implied that the groundwater moves from southwest to northeast. The estimated transmissivity values agree well with those calculated from the aquifer test. The results of the chemical analyses data of the Al-Atraf field show that the groundwater is mainly brackish, of NaCl and Na₂SO₄ water types. The groundwater is undersaturated with respect to halite, gypsum and anhydrite and supersaturated with respect to quartz, dolomite and calcite in the direction of groundwater flow. The average Pco₂ of the groundwater is higher than the Pco₂ of the earths atmosphere indicating that the groundwater is supplied with CO₂ during the infiltration processes and dissolves the carbonate minerals under closed-system conditions.     

Hydrogeological and Hydrochemical Study of the Al-Shagaya Field-F, Kuwait

The study area, Al-Shagaya Field-F, is located at the south western part of Kuwait and includes twenty-seven production water wells, tapping the Kuwait Group aquifer. The main objectives of this study were to identify the aquifer type, determine its properties, outline the geological factors and the hydrochemical processes that control the quality of the groundwater of the study area, and to assess the water quality of the Kuwait Group aquifer. Analyses of aquifer test data revealed that the Kuwait Group aquifer acts as a semi-confined to confined aquifer, with a range of transmissivity values between 103 and 1,198 m²/day. The initial water level ranges from 70 to 146 m (M.S.L). The estimated quantity of groundwater entering the study area is about 12,950 m³/day. The chemical analyses show that the groundwater of the study area is a brackish water type, with total dissolved solids ranging from 3,586 to 5,334 mg/l. The aquifer salinity increases in the direction of regional flow towards the NE. The average pH value is 7.7 and the average electrical conductivity is 5,349 s/cm. Groundwater is highly concentrated with Na⁺, Ca²⁺, Cl^- and SO₄^2- and is depleted in HCO₃^- and Mg²⁺ ions. It is characterized by secondary salinity, where the alkaline earths exceed the alkalies and strong acids exceed weak acids. Three groundwater chemical types are recognized: NaCl, Na₂SO₄ and CaCl₂. The NaCl water type is the most abundant in the study area. The main genetic types of water are: MgCl₂ and Na₂SO₄. It is found that the groundwater is oversaturated with respect to aragonite and calcite and undersaturated with respect to anhydrite, gypsum, halite and dolomite. A comparison of the hydrochemical coefficients of Na⁺/Cl^-, SO₄^2-/Cl^- and Ca²⁺/Mg²⁺ in the study area with those of seawater and river water shows that the groundwater of the study area is a mixture of marine and continental water.