The evolution of communication vehicles: linear progress andcyclical progress

Examines several aspects of communication methods (`vehicles') and the various types of progress that have been made over the years. Much of the progress we have made in communicating is rooted strongly in our past. Much of the future of our communication vehicles will be rooted in our present and our understanding of our present. In this paper, we focus our discussion on six aspects of communication: (1) communication vehicles for teaching and learning; (2) forums for communication-wide interchange of ideas; (3) vehicles for search-and-retrieval of information; (4) the richness of the communication media set; (5) venues of communication-where we communicate and the tools we use; and (6) the idea of linearity in communication     

Two potential energetic compounds: Ammonium superoxide and ammonium ozonide

Abstract

Two proposed ionic compounds, NH₄O₂ and NH₄O₃, are discussed in terms of several properties related to energetic performance. These include oxygen content, moles of gas produced and heat released upon decomposition, and specific impulse. The heat release was calculated in each instance using the predicted lattice energy, which was obtained from the computed electrostatic potential on the surface of the negative ion. NH₄O₂ is found to be superior to HMX in each property considered, while NH₄O₃ is better than HMX in some and comparable in the others.     

Cardiorespiratory and thermoregulatory response of working in fire-fighter protective clothing in a temperate environment

The cardiorespiratory and thermal responses of two intensities of treadmill exercise were compared for brief periods (12 min) in fire ensemble (FE) but without self contained breathing apparatus, and sports ensemble (SE), in a temperature environment. A further experiment explored the responses of subjects exercising in FE over a prolonged period (60 min). Eighteen male fire-fighters wearing either FE or SE walked on a level treadmill for 6 min at 5 km x h(-1) increasing to 7 km x h(-1) for 6 min. Following a recovery interval of 1 h, the exercise protocol was repeated in the second ensemble; the order of ensemble was balanced. Heart rate (HR), rectal temperature (Tre), VO2 max and rating of perceived exertion (RPE) were monitored continuously under both ensembles. At 7 km x h(-1), VO2 was significantly higher (p<0.05) in FE (36.1 and 39.9 ml x kg(-1) x min(-1)) than in SE and represented 74% VO2 max. There were no changes Tre. In experiment 2, following a rest interval of at least 36 h, eight subjects in FE walked on the treadmill at 6 km x h (gradient 10%) for 60 min also in temperate conditions, where HR, Tre and RPE were recorded at 10-min intervals. During the 60-min exercise in FE, HR reached 161 beats x min(-1) and Tre increased to 38.3 degrees C. Despite considerable subject discomfort, Tre remained below dangerous levels (38.4 degrees C). When RPE were compared with a physiological strain index (PSI) calculated from Tre and HR data over 60 min, there was no significant difference (p<0.05) with a correlation coefficient (r) of 0.98. The results suggest that RPE and PSI are closely related when exercise is sufficiently prolonged or intense to elevate Tre and HR in fire-fighters wearing FE in temperate conditions. If further investigation confirms this relationship for hot humid conditions in which fire-fighters operate, then with training, it may provide individuals with a valid measure of dangerous levels of perceived heat strain.     

Free radical initiation mechanisms in copolymerisation studied by the nitroxide trapping technique

The initiation mechanism for the radical copolymerisation of vinyl acetate, a typical electron donor monomer, and acrylonitrile, a typical electron acceptor monomer, initiated by t-butoxy radicals, has been investigated by the nitroxide radical trapping technique: 1,1,3,3-tetramethyl-1,3-dihydroisoindol-2-yloxyl (T) was the radical trapping agent. Two adducts (diastereomers) containing both vinyl acetate and acryionitrile monomers were isolated. From a kinetic analysis of these and other products over a wide range of conditions, a mechanism involving separate monomer addition, which may be regarded as normal kinetic control of monomer addition, is shown to be most consistent with the observed results.