全文获取类型
收费全文 | 1895篇 |
免费 | 15篇 |
国内免费 | 5篇 |
专业分类
电工技术 | 74篇 |
综合类 | 2篇 |
化学工业 | 124篇 |
金属工艺 | 15篇 |
机械仪表 | 9篇 |
建筑科学 | 5篇 |
能源动力 | 8篇 |
轻工业 | 27篇 |
水利工程 | 2篇 |
石油天然气 | 1篇 |
无线电 | 51篇 |
一般工业技术 | 100篇 |
冶金工业 | 1444篇 |
原子能技术 | 37篇 |
自动化技术 | 16篇 |
出版年
2023年 | 4篇 |
2022年 | 5篇 |
2021年 | 9篇 |
2020年 | 4篇 |
2019年 | 11篇 |
2018年 | 17篇 |
2017年 | 9篇 |
2016年 | 11篇 |
2015年 | 4篇 |
2014年 | 10篇 |
2013年 | 22篇 |
2012年 | 12篇 |
2011年 | 12篇 |
2010年 | 16篇 |
2009年 | 29篇 |
2008年 | 20篇 |
2007年 | 22篇 |
2006年 | 15篇 |
2005年 | 10篇 |
2004年 | 6篇 |
2003年 | 9篇 |
2002年 | 12篇 |
2001年 | 19篇 |
2000年 | 17篇 |
1999年 | 49篇 |
1998年 | 477篇 |
1997年 | 249篇 |
1996年 | 176篇 |
1995年 | 85篇 |
1994年 | 81篇 |
1993年 | 109篇 |
1992年 | 20篇 |
1991年 | 21篇 |
1990年 | 16篇 |
1989年 | 21篇 |
1988年 | 21篇 |
1987年 | 33篇 |
1986年 | 27篇 |
1985年 | 24篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 11篇 |
1981年 | 9篇 |
1980年 | 20篇 |
1979年 | 3篇 |
1978年 | 8篇 |
1977年 | 31篇 |
1976年 | 84篇 |
1975年 | 6篇 |
1974年 | 6篇 |
排序方式: 共有1915条查询结果,搜索用时 15 毫秒
1.
Sawao Honda Shinobu Hashimoto Benoît Nait-Ali David S. Smith Yusuke Daiko Yuji Iwamoto 《Journal of the American Ceramic Society》2022,105(10):6335-6344
Porous alumina with a highly textured microstructure was fabricated by pulse electric current sintering (PECS) using alumina platelets. Highly oriented porous alumina with a porosity of 3%–50% was obtained by a pressure-controlled method of PECS. The properties of the highly textured porous alumina were measured in two directions. The nitrogen gas permeance and thermal conductivity at room temperature were higher in the direction along the platelet length due to the higher continuity of pores and the connectivity of alumina platelets, respectively. The anisotropy of the thermal conductivity at room temperature was investigated and explained by the effect of grain size of platelets as well as morphology and orientation of pores. The bending strength was higher with the loading direction along the platelet thickness. The thermal shock strength was clearly different in the two directions. The difference in the thermal shock strength was investigated by the measurement of properties and thermal stress analysis. 相似文献
2.
To determine whether there is any correlation between sudden decrease in barometric pressure and onset of labor, a non-experimental, retrospective study at a 948-bed tertiary care hospital was done. Pregnant patients of 36 weeks gestation or more who presented with spontaneous onset of labor during the 48 hours surrounding the 12 occurrences of significant drop in barometric pressure in 1992 were included in the study. Significantly more occurrences of onset of labor were identified in the 24 hours after a drop in barometric pressure than were identified in the 24 hours prior to the drop in barometric pressure (P < 0.05). Therefore, the overall number of labor onsets increased in the 24 hours following a significant drop in barometric pressure. 相似文献
3.
Improved visible-light responsive photocatalytic activity of N and Si co-doped titanias 总被引:1,自引:0,他引:1
Thermal reaction of titanium tetraisopropoxide and tetraethyl orthosilicate in 1,4-butanediol afforded nanocrystalline silica-modified
titanias having large surface area and superior thermal stability. In this study, the thus-obtained silica-modified titanias
were treated in an NH3 flow at high temperatures, and their physical and photocatalytic properties were investigated. Compared with NH3-treated TiO2 without silica modification, the NH3-treated silica-modified titanias showed a stronger absorption in the visible region (400–500 nm) and had a larger peak at
396 eV in the N 1s XPS spectrum. These results indicate that a larger amount of nitrogen was stably doped in the silica-modified
titania. The obtained products exhibited a high photocatalytic activity for degradation of Rhodamine B and decomposition of
acetaldehyde under visible light irradiation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
4.
In order to clarify the roles of three cysteines in ketosteroid isomerase (KSI) from Pseudomonas putida biotype B, each of the cysteine residues has been changed to a serine residue (C69S, C81S, and C97S) by site-directed mutagenesis. All cysteine mutations caused only a slight decrease in the k(cat) value, with no significant change of Km for the substrate. Even modification of the sulfhydryl group with 5,5'-dithiobis(2-nitrobenzoic acid) has almost no effect on enzyme activity. These results demonstrate that none of the cysteines in the KSI from P. putida is critical for catalytic activity, contrary to the previous identification of a cysteine in an active-site-directed photoinactivation study of KSI. Based on the three-dimensional structures of KSIs with and without dienolate intermediate analog equilenin, as determined by X-ray crystallography at high resolution, Asp-103 was found to be located within the range of the hydrogen bond to the equilenin. To assess the role of Asp-103 in catalysis, Asp-103 has been replaced with either asparagine (D103N) or alanine (D103A) by site-directed mutagenesis. For D103A mutant KSI there was a significant decrease in the k(cat) value: the k(cat) of the mutant was 85-fold lower than that of the wild-type enzyme; however, for the D103N mutant, which retained some hydrogen bonding capability, there was a minor decrease in the k(cat) value. These findings support the idea that aspartic acid 103 in the active site is an essential catalytic residue involved in catalysis by hydrogen bonding to the dienolate intermediate. 相似文献
5.
6.
7.
This study demonstrates that the use of high field 1H NMR spectroscopy permits individual detection of phosphatidylcholine and sphingomyelin molecules at the surface of native low density lipoprotein (LDL) particles. Distinct behaviour was observed for the choline head group -N(CH3)3 resonances of these different phospholipids revealing preferential immobilisation for phosphatidylcholine. This suggests the existence of reversible and irreversible phosphatidylcholine-apolipoprotein B interactions and is consistent with microdomain formation at the surface monolayer of LDL. The novel resonance assignment and results show that 1H NMR can provide efficient and practical means for future studies on the structure and dynamics at the LDL surface. 相似文献
8.
HS Wong 《Canadian Metallurgical Quarterly》1997,38(11):459-464
9.
EG Mdurvwa JI Alak GE Pimentel-Smith HS Gakou S Kolavala H Abdelrahman PG Reddy 《Canadian Metallurgical Quarterly》1997,43(7):1039-1044
The LP-BM5 murine leukemia virus causes acquired immunodeficiency syndrome in C57BL/6J mice (MAIDS), similar to that of AIDS in humans. The objective of this study was to determine the effect of LP-BM5 viral infection on cellular activation and membrane integrity of splenocytes. Oxidative burst in splenocytes in response to exposure to PMA (20 microg/ml) was significantly higher (p<.02) in infected than in control mice at two weeks post-infection using luminol-enhanced chemiluminescence. By 13 weeks post-infection superoxide anion production in infected mice was significantly lower when compared to controls coinciding with decreased proliferative response to mitogens. The extent of cell membrane damage as indicated by lactic dehydrogenase (LDH) activity in serum was significantly higher in infected than in control mice (p<.001). The results from this study suggests that LP-BM5 virus causes an initial stimulation of cellular activity followed by a decreased cell activation characterized by decreased proliferation of splenocytes and decreased oxygen radical production. Decreased cell membrane integrity indicated by increased LDH activity may partly be responsible for these changes. 相似文献
10.
J Hellman EM Zanzot PM Loiselle SF Amato KM Black Y Ge JT Kurnick HS Warren 《Canadian Metallurgical Quarterly》1997,176(5):1260-1268
The binding of IgG in antiserum to Escherichia coli J5 to the surface of Enterobacteriaceae and to cell wall fragments released from serum-exposed bacteria was studied in a search for potentially protective epitopes other than lipopolysaccharide (LPS). IgG titers to multiple heterologous gram-negative smooth bacteria increased following incubation of the bacteria in serum and decreased following absorption with serum-exposed heterologous bacteria. IgG eluted from absorbing bacteria bound to at least three conserved bacterial outer membrane proteins (OMPs), but not LPS, as assessed by immunoblotting. The same OMPs were present in LPS-containing macromolecular cell wall fragments released by incubation of heterologous gram-negative bacteria in human serum. Part of the protection offered by J5 antiserum could be from binding of IgG to conserved OMPs at the bacterial surface or to OMPs in cell-wall fragments released from dying bacteria. 相似文献