Environmentally friendly synthesis and photopolymerization of acrylated methyl ricinoleate for biomedical applications

In this study, we aimed to develop an efficient synthesis and photopolymerization of acrylated methyl ricinoleate (AMR) for biomedical applications. During the first step of the synthesis, methyl ricinoleate (MR) and boric acid were esterified via azeotropic distillation in toluene. Afterward, MR–boric acid ester was acrylated with acrylic acid at 165 °C via a boric acid ester acidolysis reaction. The bulk photopolymerization of AMR was performed in the presence of the photoinitiator 2,2-dimethoxy-2-phenyl acetophenone (DMPA) under 365 nm UV irradiation. Even with the use of 0.4% DMPA, a 35% monomer conversion was achieved within 30 min. Moreover, AMR, the plant-oil-based monomer, was also copolymerized with N-isopropyl acrylamide to obtain thermoresponsive hydrogels on the glass surface for biomedical applications. The synthesized materials were characterized by Fourier transform infrared (FTIR) spectroscopy, ¹H-NMR spectroscopy, and thermal characterization via thermogravimetric analysis (TGA) and differential scanning calorimetry techniques. The surfaces were characterized by FTIR and Energy Dispersive X-ray (EDS) spectroscopy. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47969.     

Effect of immunosuppression and splenectomy in transplantation sarcomas in mice

After spontaneous regression of transplanted tumours, marked reduction in number of tumours was found when challenged with isogenic tumour cells. The ALS abrogates this effect. Tumour removal by surgical excision of limb and subsequent time scheduled challenge by tumour cells maximally suppress on the 10th day and continues up to the 42nd day the tumorogenic effect. Splenectomy has no effect if done before a day or 3 days after challenge but marked decrease in tumour development was seen when challenged on the 8th day after splenectomy. Amputation and splenectomy together potentiates tumour formation. Only in tumour extrication, does resistance develop up to the 42nd day from surgery. Challenging at a different site in mice with tumours, resulted in prolongation of the intervals of tumour formation. Challenge after surgical removal of tumour after a time lapse, results in marked reduction in number and size of tumours. Surgical tumour extrication after splenectomy and subsequent challenge on 11th day inhibited tumour formation. Whereas splenectomized tumour bearing mice when challenged at a heterosite did not develop resistance.     

Novel allpass filter configuration employing single OTRA

A new circuit configuration uses a single operational transresistance amplifier (OTRA) and four passive elements to realize both first- and second-order allpass filters. Owing to internal grounding of the OTRA input terminals, effects of input parasitics are significantly reduced. Applications of the circuit include the realization of the phase equalizer, the quadrature oscillator, and the high-Q bandpass filter for analog signal processing. The performance of the allpass filter is illustrated by circuit-level simulation of a quadrature oscillator with CMOS realization of the OTRA.     

GIS母线中金属异物运动的探讨

介绍GIS母线内部存在金属异物时的影响，对金属异物在不同情况下的运动规律进行了探讨和研究。     

Numerical treatment of a quasilinear initial value problem with boundary layer

The paper deals with the singularly perturbed quasilinear initial value problem exhibiting initial layer. First the nature of solution of differential problem before presenting method for its numerical solution is discussed. The numerical solution of the problem is performed with the use of a finite-fitted difference scheme on an appropriate piecewise uniform mesh (Shishkin-type mesh). An error analysis shows that the method is first-order convergent except for a logarithmic factor, in the discrete maximum norm, independently of the perturbation parameter. Finally, numerical results supporting the theory are presented.     

高压自能式灭弧室和操动机构的技术进步(二)

高压SF_6断路器经多次改进在欧洲和日本已发展成第三代产品,第一代为热膨胀式断路器加助吹,将液压机构改为弹簧操动机构和变开距混合式灭弧室。第二代产品为改善开断容性电流特性发展“双容积”灭弧室和新型动态压缩灭弧室,以及双向运行触头系统等,更进一步减少分合闸操作功应用旋弧灭弧原理迫使电弧快速旋转冷却使电流零点时熄灭。第三代产品主要介绍加强操动机构的可靠性和稳定性,传输时无功消耗少,减少机构零件数量等。