Comparative study of monoclonal antibody scan in diagnosing orthopaedic infection

When clinical data are insufficient to diagnose infection of bone or joints, nuclear scanning becomes crucial in making an accurate diagnosis. The efficacy of (99m)technetium antigranulocyte monoclonal antibody Fab' fragment (LeukoScan) is prospectively compared with (111)indium white blood cell and (99m)technetium methylene diphosphonate bone scans in 74 patients with suspected musculoskeletal infections. They were grouped according to site of suspected infection: 33 long bones, 23 prosthetic joints, and 18 diabetic feet. Sixty-two of these 74 patients had surgical verification with histopathology or culture. The remaining 12 patients had clinical followup as proof of absence of infection. The overall sensitivity of LeukoScan, (111)indium white blood cell, and (99m)technetium methylene diphosphonate bone scans was 93%, 85% and 92%, respectively. Specificity was 89%, 75% and 52%, and accuracy was 90%, 79% and 74%, respectively. The conclusion from this study is that LeukoScan is more accurate in detecting osteomyelitis, with better sensitivity and specificity in prosthetic joints. Compared with (111)indium white blood cell scans, LeukoScan++ gives superior images, and results are obtained in 1 to 6 hours without biohazard risk from handling blood products.     

A gantry-based tri-modality system for bioluminescence tomography

A gantry-based tri-modality system that combines bioluminescence (BLT), diffuse optical (DOT), and x-ray computed tomography (XCT) into the same setting is presented here. The purpose of this system is to perform bioluminescence tomography using a multi-modality imaging approach. As parts of this hybrid system, XCT and DOT provide anatomical information and background optical property maps. This structural and functional a priori information is used to guide and restrain bioluminescence reconstruction algorithm and ultimately improve the BLT results. The performance of the combined system is evaluated using multi-modality phantoms. In particular, a cylindrical heterogeneous multi-modality phantom that contains regions with higher optical absorption and x-ray attenuation is constructed. We showed that a 1.5 mm diameter bioluminescence inclusion can be localized accurately with the functional a priori information while its source strength can be recovered more accurately using both structural and the functional a priori information.     

Online monitoring of diallyldimethylammonium chloride polymerization

Diallyldimethylammonium chloride, which is an acidic salt with numerous applications, was polymerized in water at three different monomer concentrations and at three different pHs which the monomer is in charged form. Reactions were investigated by the automatic continuous online monitoring of polymerization technique. Conversion, molecular weight, and reduced viscosity were monitored. The reaction is found to be second‐order with respect to monomer. Rate constants and molecular weights tend to increase with pH and concentration. POLYM. ENG. SCI., 54:1350–1356, 2014. © 2013 Society of Plastics Engineers     

Modelling the impact of land-cover change on potential soil loss in the Taita Hills,Kenya, between 1987 and 2003 using remote-sensing and geospatial data

In sub-Saharan Africa, natural vegetation is being transformed into agricultural lands at a fast rate, endangering ecosystem services and increasing soil-loss potential, which may trigger land degradation. For the Taita Hills study area in Kenya, multi-temporal land-cover models of 1987, 1999 and 2003, derived from Satellite Pour l'Observation de la Terre (SPOT) imagery using a multi-scale segmentation/object relationship modelling (MSS/ORM) methodology and a rainfall layer, a digital elevation model (DEM) and a digital soil map were applied to model potential soil loss. Population growth in the area has led to a shortage of agricultural land and movement of people to the lowlands, evidenced by a 39% (9.3 km²) increase in croplands from 30% to 41% of the study area during the research time frame. Expansion took place mostly in surrounding foothills and lowlands, at the expense of natural shrubland and grassland, but also occurred in the hills. Universal soil-loss equation (USLE) model results showed a 60% (4 km²) increase in the area of very high potential soil loss, from 7% of the study area in 1987 to 12% in 2003, due mainly to very high soil-loss potential in croplands. Whilst the area of croplands as a whole increased, the relative proportion of very high soil-loss potential in croplands remained 20%, both in 1987 and in 2003, indicating that newly cleared agricultural lands with vulnerable soils are the most at-risk areas.     

Group-Scheduling for Multi-Service Optical Burst Switching (OBS) Networks

We propose a new burst scheduling mechanism for Optical Burst-Switched (OBS) networks. The new approach is made possible by gathering data bursts into groups and performing the scheduling decision for each group collectively. In OBS group-scheduling, bursts will not be considered for scheduling until a pre-defined time period elapses, during which the group of burst header packets would be gathered. By transforming a set of data bursts into a set of corresponding time intervals, the problem of scheduling these bursts is transformed into a combinatorial optimization problem. Graph algorithms are applied to obtain the maximum number of non-overlapping bursts. The proposed OBS group-scheduling scheme is shown to improve the performance of OBS networks over existing scheduling schemes in terms of burst loss probability and channel utilization. With an extension through a sequential optimization, using a Branch-and-Bound technique, the proposed scheme can support multiple classes of service. It is shown that the new scheduling approach has several desired characteristics including fairness and service differentiability among classes in terms of burst loss probability and channel utilization.     

Applying error correction codes to achieve security and dependability

We apply Linear Error Correction (LEC) code to a novel encoding scheme to assure two fundamental requirements for transmission channels and storage units: security and dependability. Our design has the capacity to adapt itself to different applications and their various characteristics such as availability, error rate, and vulnerabilities. Based on simple logic operations, our scheme affords fast encryption, scalability (dual or more column erasures), and flexibility (LEC encoder employed as a front end to any conventional compression scheme). Performance results are very promising: Experiments on dual erasures outperform conventional compression algorithms including Arithmetic Coding, Huffman, and LZ77.     

Naphtha derived from polyolefins

Conversion of polyolefins (HDPE, LDPE and PP) into feedstock naphtha was investigated by hydroliquefaction process. Hydroliquefaction experiments were carried out under cold hydrogen pressure of 5 MPa at the temperatures between 375 and 450 °C in absence and presence of catalyst. Two types commercial catalysts were used, a hydrocracking catalyst (DHC-8) and a hydrogenation catalyst (HYDROBON). The effect of temperature and catalyst type on product yields and composition of gas and liquid products was investigated. The temperature was the main effect in hydroliquefaction. DHC-8 showed good cracking activity, but it gave the liquid product containing high olefin content same as thermal run. Although HYDROBON catalyst produced the sufficient amount of liquid (and naphtha fraction) at the higher temperature, it gave the liquid product with very low olefin content. The naphtha fractions obtained from polyolefins under the optimal hydrocracking conditions were analyzed by PIONA instrument to determine the hydrocarbon groups. PIONA analysis showed that the naphtha obtained from hydroliquefaction over HYDROBON catalyst could be used as a petrochemical feedstock. However, the naphtha obtained in presence of DHC-8 catalyst, which is to be used a feedstock, was needed further hydrogenation treatment.     

Rheological and fusion behaviors of PVC micro‐ and nano‐composites evaluated from torque rheometer data

The effects of calcium carbonate (CaCO₃) particle size on the fusion and rheological behaviors of rigid poly(vinyl chloride) (PVC) composites prepared in a Haake torque rheometer were investigated by means of torque data recorded during processing. Increasing the number of particles in the same blend volume by decreasing the particle size resulted in increasing frictional forces. This increase led in turn to increased fusion torque and decreased fusion time and temperature. The power‐law‐index values of the composites increased with decreasing particle size except for 25‐nm CaCO₃. The viscosities of all composites were found to decrease with shear rate; therefore, high pseudoplasticity was observed. At a particular rotor speed, viscosity of the composites decreased with decreasing particle size except for 25‐nm CaCO₃. The overall results showed that the particle size of CaCO₃ altered the fusion characteristics and rheological behavior of PVC. J. VINYL ADDIT. TECHNOL., 2010. © 2010 Society of Plastics Engineers     

Petrochemicals from ethanol over a W-Si-based nanocomposite bidisperse solid acid catalyst

Very high ethylene selectivity values approaching 100% and very high ethanol conversion values approaching 85% were obtained in dehydration of ethanol over a new W-silicate-based nanocomposite catalyst having both meso and macropores and containing a W/Si atomic ratio of 0.85. Silicotungsticacid was successfully incorporated into the catalyst structure following a one-pot hydrothermal synthesis procedure. This catalyst is highly stable and does not loose activity in polar solvents and it has a sufficiently high surface area for catalytic applications. Calcination temperature of the catalyst was found to have a very significant effect on the catalyst structure and also on its catalytic performance in ethanol dehydration. Maximum selectivity of the second major reaction product diethylether was obtained as 0.7 at 200 °C, with the catalyst which was calcined at 400 °C. Very high ethylene and diethylether yield values obtained in this study at different reaction conditions are highly promising for the production of petrochemicals from ethanol.