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1.
2.
Properties and applications of β‐glycosidase from Bacteroides thetaiotaomicron that specifically hydrolyses isoflavone glycosides 下载免费PDF全文
Da‐Hye Byun Hye‐Jeong Choi Hye‐Won Lee Hye‐Yeon Jeon Woo‐Jae Choung Jae‐Hoon Shim 《International Journal of Food Science & Technology》2015,50(6):1405-1412
To modify the glycan part of glycosides, the gene encoding β‐glycosidase was cloned from Bacteroides thetaiotaomicron VPI‐5482. The cloned gene, bt_1780, was expressed in Escherichia coli MC1061 and the expressed enzyme was purified using Ni‐NTA affinity chromatography. The purified enzyme, BTBG, showed optimal activity at 50 °C and pH 5.5. Interestingly, this enzyme did not have any hydrolysing activity on ordinary β‐linkage–containing substrates such as xylobiose, lactose and cello‐oligosaccharide, but specifically hydrolysed isoflavone glycosides such as daidzin, genistin and glycitin. Compared to a commercial beta glucosidase, BTBG selectively hydrolysed isoflavone glycosides in soybean extract mixture solution. These results suggest that BTBG may be a specialized enzyme for the hydrolysis of glycosides and that the substrate specificity of BTBG is applicable for the bioconversion of isoflavone glycosides in the food industry. 相似文献
3.
4.
Ki Hyun Kim Yong Hoon Kang Byoungho Lee 《Photonics Technology Letters, IEEE》1997,9(12):1610-1612
A photorefractive volume hologram was recorded and probed using light diffracted from a tapered optical fiber as a reference beam. A single-mode fiber (SMF) was chemically etched and tapered to give a complicated beam pattern, and it is shown that the tapered optical fiber can be utilized to increase the storage density of the volume hologram. Spatial selectivity of the volume hologram with this method was increased by two times compared to the normal SMF referencing, which is due to the fact that the complicated beam pattern has little correlation with its shifted version 相似文献
5.
The reduction of calcium sulfate to produce calcium sulfide is a part of the cyclic process for converting sulfur dioxide
to elemental sulfur that is described in Part I. The kinetics of the hydrogen reduction of nickel-catalyzed calcium-sulfate
pellets were investigated using a thermogravimetric analysis (TGA) technique at reaction temperatures between 1023 and 1088
K and hydrogen partial pressures between 12.9 and 86.1 kPa. The reactivity of nickel-catalyzed calcium-sulfate pellets was
demonstrated by the conversion of 70 pct fresh nickel-catalyzed calcium sulfate to calcium sulfide in 20 minutes at 1073 K
under a hydrogen partial pressure of 86.1 kPa. Furthermore, the reactivity remained relatively intact after ten cycles of
reactions and regenerations. This observed characteristic of the pellets is important because the solids must be reusable
for repeated cycles to avoid generating secondary pollutants. The nucleation and growth rate expression was found to be useful
in describing the kinetics of the reaction, which had an activation energy of about 167 kJ/mol (∼40 kcal/mol) in all reaction
cycles except for the first regenerated samples that were lower at 146 kJ/mol (35 kcal/mol). The reaction order with respect
to hydrogen partial pressure was 0.22 in all cycles with the exception of the first regenerated sample for which it was 0.37. 相似文献
6.
Xiang‐Dan Li Zhen‐Xin Zhong Sang‐Hoon Han Seung Hee Lee Myong‐Hoon Lee 《Polymer International》2005,54(2):406-411
From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry 相似文献
7.
John E. Sohn 《The Journal of Adhesion》1985,19(1):15-27
Enhanced matrix-filler adhesion is realized after filler treatment with a surface treatment process. The hydrosol/coupling agent treatment was applied to a wide range of inorganic and organic fillers, and adhesion to a variety of matrix resins was improved. Scanning Electron Microscopy (SEM) was used to determine the locus of failure in the filled systems. The locus of failure shows the relative degree of adhesion between the filler and the polymer matrix. Significant improvement in adhesion in humid environments is also observed. 相似文献
8.
The AA7075 alloys reinforced with SiC and without SiC particles were fabricated by a pressureless infiltration method, and
then, their tensile properties and microstructures were analyzed. The spontaneous infiltration of molten metal at 800 °C for
1 hour under a nitrogen atmosphere made it possible to fabricate 7075 Al matrix composite reinforced with SiC, as well as
a control 7075 Al without SiC. A significant strengthening even in the control alloy occurred due to the formation of in-situ AlN particle even without an addition of SiC particles. Composite reinforced with SiC particles exhibited higher strength
values than the control alloy in all aging conditions (underaged (UA), peak-aged (PA), and overaged (OA)), as well as a solution
treated condition. Spontaneous infiltration was further prompted owing to the combined effect of both Mg and Zn. This may
lead to an enhancement of wetting between the molten alloy and the reinforcement. Consequently, strength improvement in a
composite may be attributed to good bond strength via enhancement of wetting. The grain size of the control alloy is greatly decreased to about 2.5 μm compared to 10 μm for the
commercial alloy. In addition, the grain size in the composite is further decreased to about 2 μm. These grain refinements
contributed to strengthening of the control alloy and the composite. 相似文献
9.
One-dimensional mathematical modeling was used to describe the self-propagating high-temperature synthesis (SHS) process for preparing TiAl3 and Ni3Al intermetallics. The kinetic parameters (activation energies and pre-exponential factors) for the two compounds were obtained by matching experimental measurement and the numerical solution. The results thus obtained were compared with rate parameters obtained using different methods. The activation energy was 483 and 283 kJ mol?1 for the formation of TiAl3 and Ni3Al, respectively. The temperature profiles calculated using the mathematical model were compared with experimental measurements for both aluminides which indicated reasonable agreement. Fine particle size and moderate preheating increase the SHS rates. 相似文献
10.
Kinetics of zinc oxide formation from zinc sulfide by reaction with lime in the presence of water vapor 总被引:1,自引:0,他引:1
A novel reaction scheme for transforming certain metal sulfides to the corresponding oxides has been developed. In this process,
steam oxidizes the sulfide into the oxide, and the hydrogen sulfide produced reacts with lime to form calcium sulfide and
regenerate steam. There is no net consumption or generation of gaseous species. Thus, the overall reaction can be carried
out in a closed system as far as the gas phase is concerned. This eliminates the possibility of emitting hydrogen sulfide
out of the reactor. Only certain metal sulfides are thermodynamically amenable to this treatment. In this paper, the reaction
of ZnS to ZnO by this scheme is described, together with a detailed formulation of the rate equation for the overall reaction
based on the kinetics of the component gas-solid reactions. Although the present work was done with CaO, other suitable oxides
may be used in its place. A further potential application of this process is to the selective oxidation of certain sulfide(s)
from complex sulfide ores as a treatment prior to the separation of minerals. 相似文献