Flame-Sprayed Glaze Coatings: Effects of Operating Parameters and Feedstock Characteristics Onto Coating Structures

Many substrates do not sustain the conventional glazing process (i.e., vitreous glazing) due to the relatively high temperature required by this treatment (i.e., up to 1400 °C in some cases) to fuse glazes after their application on the surface to be covered. Flame spraying could appear as a solution to circumvent this limitation and to avoid thermal decomposition of substrates. This contribution describes some structural attributes of glaze coatings manufactured by flame spraying. It also discusses the influence of the feedstock powder morphology and some of its physical properties on coating characteristics. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

Discrepancy search for the flexible job shop scheduling problem

The flexible job shop scheduling problem (FJSP) is a generalization of the classical job shop problem in which each operation must be processed on a given machine chosen among a finite subset of candidate machines. The aim is to find an allocation for each operation and to define the sequence of operations on each machine, so that the resulting schedule has a minimal completion time. We propose a variant of the climbing discrepancy search approach for solving this problem. We also present various neighborhood structures related to assignment and sequencing problems. We report the results of extensive computational experiments carried out on well-known benchmarks for flexible job shop scheduling. The results demonstrate that the proposed approach outperforms the best-known algorithms for the FJSP on some types of benchmarks and remains comparable with them on other ones.     

Image analysis of dermal collagen changes during skin aging

A missense mutation in the human alpha synuclein gene was recently identified in some cases of familial Parkinson's disease (FPD). We have developed an antibody that recognizes the C-terminal 12 amino acids of the human alpha synuclein protein and have demonstrated that alpha synuclein is an abundant component of the Lewy bodies found within the degenerating neurons of patients with Parkinson's disease (PD). The presence of alpha synuclein in Lewy bodies of sporadic PD patients suggests a central role for alpha synuclein in the pathogenesis of PD.     

Comparative study of the Cd. Cu and Pb determination by AAS and by ICP-AES in river water : Application to a mediterranean river (Congost river, Catalonia, Spain)

The accuracy, precision, detection limit and rapidity in the determination of Cd, Cu and Pb in river water by AAS determination, previous extraction with APDC-MIBK system, is compared with direct determination method ICP-AES. Both methods show a similar detection limit and an analogous accuracy by the addition standard method. With a calibration curve only ICP-AES presents good accuracy, this technique is advantageous in long term precision and requires minimum sample preparation. The sample stability at different temperature conservation is studied. Finally both methods are applied to the determination of Cd, Cu and Pb in Congost river water.     

The cost of the surgical treatment of cataracts at the African Institute of Tropical Ophthalmology (Bamako, Mali)

In developing countries, cataracts are a serious public health problem. There are a large number of patients, an estimated 3 millions in Africa alone, awaiting operations. However, the number of surgical interventions is small for a variety of reasons, including the cost. To try to reduce the cost of surgery, we analysed the various elements involved at the African Institute of Tropical Ophthalmology (AITO) in Bamako (Mali). The route followed by the patient, from contact with the health service through to post-operative health care was analysed in terms of individual jobs, supplies and equipment required. The unit cost of each of these elements was assessed using an adapted calculation method. The results show that the cost of the removal of the lens at the AITO is 15,200 FCFA (or $56). Installing an intra-ocular lens significantly improves the outcome for a similar cost (16,500 FCFA or $60). The relative costs of various elements were as follows: food, 32%, the suture, 12%; and equipment only 13%. Thus, to reduce the overall cost of surgery for cataracts, ambulatory surgery should be organised, with efforts to reduce the costs of suture. High quality equipment should be used, because its life-span is such that it can be amortised over a long period.     

Analysis of adenoviruses and polyomaviruses quantified by qPCR as indicators of water quality in source and drinking-water treatment plants

Three drinking-water treatment plants were analyzed for the presence of human adenoviruses (HAdV) and JC polyomavirus (JCPyV), previously suggested as viral contamination indicators, in order to define their water quality in relation to the presence of viral pathogens and the efficiency of the treatments applied.The 90% of the river water samples had positive results of HAdV (10¹-10⁴ genome copies (GC)/L); and 48%, of JCPyV (10⁰-10³ GC/L). Lower concentrations of HAdV and JCPyV were found in different treatment steps of the plants in absence of bacterial standards. Virus removal efficiencies were higher than 5 logs in plants 1 and 3 and could be quantified as >2 logs in plant 2. However, three post-chlorinated samples from plants 2 and 3 (11%) were found to be positive for HAdV by qPCR, but did not show infectivity in the cell cultures assayed. Simple methods based on the adsorption-elution of viruses from glass wool give low-cost and efficient virus recovery from source water and large-volume water samples. Quantification of JCPyV and HAdV using qPCR is useful for evaluating virus removal efficiency in water treatment plants, identification of Hazard Analysis and Critical Control Points (HACCP) and as a molecular index of the virological quality of water. Though infectivity is not guaranteed when using qPCR techniques in water treated with disinfection processes, the quality of source water, where viruses have proved to have infective capabilities, and the removal efficiency of viral particles may be efficiently quantified.     

Hemolglobin encapsulation in chitosan/calcium alginate beads

A mild chitosan/calcium alginate encapsulation process, as applied to encapsulation of hemoglobin, was investigated. The first procedure consisted of adding dropwise a hemoglobin-containing sodium alginate mixture in a chitosan solution, then hardening the interior of capsules thus formed, in the presence of CaCl₂. In the second method, the droplets were directly pulled off in a chitosan–CaCl₂ mixture. Both procedures led to beads containing a high concentration in entrapped hemoglobin as more than 90% of the initial concentration (150 g/L) were retained inside the beads provided that the chitosan concentration was great enough. The molecular weight of chitosan (M?_u 245,000 or 390,000) and the pH of its solution (2, 4, or 5.4) had only a slight effect, the best retention being obtained with beads prepared at pH 5.4. The hemoglobin release during the bead storage in water was found to depend on the conditions of their formation and especially on the chitosan molecular weight. The best retention during storage in water was obtained with beads prepared with the high M?_u chitosan solution at pH 2. Considering the total loss in hemoglobin during the bead formation and after 1 month of storage in water, the best results were obtained by preparing the beads in an 8 g/L solution of a 390,000 chitosan at pH 4 (less than 7% of loss with regard to the 150 mg/L initial concentration). © 1994 John Wiley & Sons, Inc.