Mobility of trace elements from selected Australian fly ashes and its potential impact on aquatic ecosystems

Batch leaching tests have been performed on fly ashes collected from four Australian power stations fuelled by chemically different coals. Two acidic and two alkaline fly ashes were subjected to long-term (144 h) leaching tests, and the behaviour of As, B, Mo and Se was investigated to obtain data on their potential for mobilisation during fly ash-water interactions. All four elements are mobile under different conditions and over different leaching times. The concentrations of these elements released in leaching solutions with initial pH values of 4, 7 and 10 were used to assess the influence of pH conditions on element mobility from the acidic and alkaline fly ashes. The most mobile of the four elements leached were Mo from alkaline fly ashes and B from acidic fly ashes. Arsenic concentration increased with time in leachate solutions from acidic and alkaline fly ashes; however, in solutions in contact with alkaline fly ashes the As concentration, after reaching a maximum, later decreased with time. Selenium mobility shows a similar pattern to that of As, with similar leaching concentrations. Boron has the highest relative mobility of all four elements. A process possibly responsible for the decrease in concentration of B, As and Se in alkaline leaching solutions is the formation of ettringite. Equilibrium between the solid phase (ash) and the leaching solution was not reached in any of the leaching experiments. The pH of the leaching solution is the key factor affecting the mobility of these trace elements in these fly ashes.     

Synthesis and properties of some 9,10-dihydro-7H-imidazo[1,2-b]benz[d,e]isoquinolin-7-one derivatives

The various routes of synthesis of some methoxy- and acetylamino-9,10-dihydro-7H-imidazo[1,2-b]benz[d,e]isoquinolin-7-one derivatives are described. The mixtures of geometric isomers obtained were separated and the chemical constitution of individual isomers was confirmed by the u.v., i.r., n.m.r. and mass spectroscopy. The fluorescence properties of individual isomers were also determined.     

Grain Size Variation in Coatings

An increase in grain size during deposition occurs in physical vapor deposition. Columnar grain structures result as the coating thickens beyond the point of constant grain size (>25 μm). As the deposition is taking place, the grain size of the Ti coating increases from that on the order of 0.01 (Jim to that greater than 1.0 μm. At a certain critical thickness during deposition, t_c, the grain size stabilizes. This study examines the minimum coating thickness required to produce the ultimate grain size. Then this investigation relates the critical thickness to the texture of the coating.     

Hydrophilic polycarbonate chips for generation of oil-in-water (O/W) and water-in-oil-in-water (W/O/W) emulsions

Modification of the surfaces of polycarbonate (PC) with the use of a solution of tin (II) chloride renders them hydrophilic. The surface draping is stable against exposure to water and to alcohols. Exposure to alkanes reduces but does not diminish the effect. The method is compatible—in using the same solvent and temperature—with the hydrophobic modification of PC (Jankowski et al. in Lab Chip 11:1151–1156, 2011). The combination of these methods makes it possible to generate single and multiple monodisperse emulsions with the use of flow-focusing junctions in systems made in PC—a material that is suitable for fabrication of multilayer, high-throughput microfluidic devices.     

Hydrophilic polycarbonate chips for generation of oil-in-water (O/W) and water-in-oil-in-water (W/O/W) emulsions

Modification of the surfaces of polycarbonate (PC) with the use of a solution of tin (II) chloride renders them hydrophilic. The surface draping is stable against exposure to water and to alcohols. Exposure to alkanes reduces but does not diminish the effect. The method is compatible—in using the same solvent and temperature—with the hydrophobic modification of PC Jankowski et al. ( Lab Chip 11:748–752, 2011). The combination of these methods makes it possible to generate single and multiple monodisperse emulsions with the use of flow-focusing junctions in systems made in PC—material that is suitable for fabrication of multilayer, high throughput microfluidic devices.     

Structural damage identification by adding virtual masses

This paper presents a method for damage identification by adding virtual masses to the structure in order to increase its sensitivity to local damages. The main concept is based on the Virtual Distortion Method (VDM), which is a fast structural reanalysis method that employs virtual distortions or pseudo loads to simulate structural modifications. In this paper, the structure with an added virtual mass is called the virtual structure. First, the acceleration frequency response of the virtual structure is constructed numerically by the VDM using local dynamic data measured only by a single excitation sensor and a single acceleration sensor. Second, the value of the additional mass is determined via sensitivity analysis of the constructed frequency responses of the virtual structure with respect to damage parameters; only the natural frequencies with high sensitivity are selected. This process is repeated for all the considered placements of the virtual mass. At last, the selected natural frequencies of all the virtual structures are used together for damage identification of the real structure. A finite element (FE) model of a plane frame is used to introduce and verify the proposed method. The damage can be identified precisely and effectively even under simulated 5 % Gaussian noise pollution.     

Identification of coexistent load and damage

Load reconstruction and damage identification are crucial problems in structural health monitoring. However, it seems there is not much investigation on identification of coexistent load and damage, although in practice they usually exist together. This paper presents a methodology to solve this problem based on the Virtual Distortion Method. A damaged structure is modeled by an equivalent intact structure subjected to the same loads and to virtual distortions which model the damages. The measured structural response is used to identify the loads, the distortions and to recover the stress-strain relationship of the damaged elements. This way both the damage type and extent are identified. The approach can be used off-line and online by repetitive applications in a moving time window. A numerical experiment of a truss with 5% measurement error validates that the two tested damage types (constant stiffness reduction and breathing crack) can be identified along with the loads.     

Formation and characterization of oxynitride glasses in the Si-Ca-Al-O-N and Si-Ca-Al,B-O-N systems

Oxynitride compositions in the Si-Ca-Al-O-N and Si-Ca-Al, B-O-N systems were melted and furnace-cooled in BN crucibles at temperatures from 1650 to 1850° C under dry nitrogen atmosphereS. Glass formation, phase stability and crystallization were studied by characterizing the cooled melts by X-ray diffraction, DTA, and electron microscopy. Oxynitride batches with nitrogen content up to 11 at % formed glasses in the Si-Ca-Al-O-N system. Glasses in the Si-Ca-Al, B-O-N system could be formed only when the B₂O₃ content of the batch was less than 3 wt %. Oxynitride glasses in these boron-containing systems were characteristically inhomogeneous, difficult to process, and prone to crystallization. In both the systems, glasses exhibited glass transitions beginning at 1000° C and crystallization at 1300 to 1500° C. Nitrogen-containing crystalline phases were identified in devitrified glasses via microstructural and micro-mechanical analyses.     

Formulation of Presliding Domain Non-local Memory Hysteretic Loops Based Upon Modified Maxwell Slip Model

In this paper, we investigate formulation of non-local memory effect hysteretic loops in presliding domain of friction by examining the dynamic responses of a single-degree-of-freedom friction oscillator. We modify the Maxwell slip model introducing characteristic features of asperities and perform detailed examination of the system from two perspectives. The first one, termed by us as microscale, presents contribution of each individual asperity to the total friction force, whereas the second one, termed by us as macroscale, concerns friction force behaviour of the whole model treated as the unity, with a special emphasis on non-local memory effect hysteretic loops formulation, complemented by time responses.