Tuning of shear thickening behavior and elastic strength of polyvinylidene fluoride via doping of ZnO-graphene

ZnO rice like nonarchitects are grafted on the graphene carbon core via a rapid microwave synthesis route. The prepared grafted systems are characterized via XRD, SEM, RAMAN, and XPS to examined the structural and morphological parameters. Zinc oxide grafted graphene sheets (ZnO-G) are further doped in β-phase of polyvinylidene fluoride (PVDF) to prepare the polymer nanocomposites (PNCs) via mixed solvent approach (THF/DMF). β-phase confirmation of PVDF PNCs is done by FTIR studies. It is observed that ZnO-G filler enhances the β-phase content in the PNCs. Non-doped PVDF and PNCs are further studied for rheological behavior under the shear rate of 1–100 s⁻¹. Doping of ZnO-G dopant to the PVDF matrix changes its discontinuous shear thickening (DST) behavior to continues shear thickening behavior (CST). Hydrocluster formation and their interaction with the dopant could be the reason for this striking DST to CST behavioral change. Strain amplitude sweep (10⁻³% -10%) oscillatory test reveals that the PNCs shows extended linear viscoelastic region with high elastic modulus and lower viscous modulus. Effective shear thickening behavior and strong elastic strength of these PNCs present their candidature for various fields including mechanical and soft body armor applications.     

An efficient verifiable (t,n)-threshold secret image sharing scheme with ultralight shares

Multimedia Tools and Applications - A secret sharing scheme partitions a secret into a set of shares and distributes them among the eligible participants, with each participant receiving one share...     

Modeling of laser keyhole welding: Part I. mathematical modeling,numerical methodology,role of recoil pressure,multiple reflections,and free surface evolution

A three-dimensional laser-keyhole welding model is developed, featuring the self-consistent evolution of the liquid/vapor (L/V) interface together with full simulation of fluid flow and heat transfer. Important interfacial phenomena, such as free surface evolution, evaporation, kinetic Knudsen layer, homogeneous boiling, and multiple reflections, are considered and applied to the model. The level set approach is adopted to incorporate the L/V interface boundary conditions in the Navier-Stokes equation and energy equation. Both thermocapillary force and recoil pressure, which are the major driving forces for the melt flow, are incorporated in the formulation. For melting and solidification processes at the solid/liquid (S/L) interface, the mixture continuum model has been employed. The article consists of two parts. This article (Part I) presents the model formulation and discusses the effects of evaporation, free surface evolution, and multiple reflections on a steady molten pool to demonstrate the relevance of these interfacial phenomena. The results of the full keyhole simulation and the experimental verification will be provided in the companion article (Part II).     

Modeling energy and agriculture interactions—I: A rural energy systems model

Since many of the factors related to rural energy systems are gradually being quantified, there is a need to construct a model that integrates a number of these factors simultaneously in a consistent framework. Therefore, a general linear programming model is developed to capture energy and agricultural interactions existing in the rural areas of developing countries. Energy used for agriculture includes fertilizers, irrigation, and mechanization. Several technological choices of each of the above are considered and so are several crop commodities, several types of livestock, and farmers of different income groups along with their assets, i.e. land holdings, livestock, etc. The by-products of agriculture, i.e. biomass, such as crop residues, animal dung, wood, etc., can be used to generate energy. On the demand side the use of them for feed, fuel, and fertilizer must be considered. Thus, the household sector (which is the largest user of noncommercial energy), as well as the rural industries sector, is intimately related to the agriculture sector. Twelve different energy sources and several conversion technologies, such as biogas, charcoal kilns, alcohol distilleries, etc., are considered. The model is applicable to low-income, biomass-scarce developing countries. However, different types of countries will require different approximations, and their needs for detailing some aspects or other may vary. The model is suitable for policy purposes because it considers several income groups separately and considers how different changes affect each of them.     

Effect of Li+ ions on structure,properties, and actuation of cellulose electro‐active paper actuator

We have reported an electro‐active paper actuator from regenerated cellulose. After dissolving cellulose fibers with a solution of lithium chloride in N,N‐dimethylacetamide, cellulose was regenerated by combining distillation of cellulose solution along with washing with the mixture of deionized water, isopropyl alcohol, and running water. However, the effect of Li⁺ ions on structure, properties, and the actuation behavior of the actuator was not studied. This article describes the changes in these parameters when the Li⁺ ions are removed by subjecting it to different running water exposure time. The structure and properties of cellulose electro‐active paper and its actuation behavior were studied. As Li⁺ ions content reduced from 4354.17 to 10.26 ppm by increasing the exposure time of running water, crystallinity, Young's modulus, and bending displacement decreased. Details about the investigation have been explained. This elimination of ions is important to increase the piezoelectric effect in EAPap by decreasing the ion migration effect. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Multi purpose research reactor

At present Dhruva and Cirus reactors provide the majority of research reactor based facilities to cater to the various needs of a vast pool of researchers in the field of material sciences, physics, chemistry, bio sciences, research & development work for nuclear power plants and production of radio isotopes. With a view to further consolidate and expand the scope of research and development in nuclear and allied sciences, a new 20 MWt multi purpose research reactor is being designed. This paper describes some of the design features and safety aspects of this reactor.     

High power and low cross‐polarization microstrip patch array antenna at S‐band

This article reports the design and development of high power, low cross‐polarization, and high efficiency circularly polarized microstrip patch array antenna at S‐band, proposed for Indian Regional Navigation Satellite System payload. A novel feeding mechanism for truncated corner square patch based on square coaxial line for broadband impedance matching is discussed. Sequential rotation scheme for axial ratio improvement in an array is implemented. High power handling margins in critical regions of square coaxial line for multipaction breakdown is brought out. Measured 19 dB return loss bandwidth of array antenna is 15.6%. Axial ratio of 0.78 dB over global coverage is achieved in the desired frequency band of operation. © 2011 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2012.     

Quantification of response time in poly(vinyl alcohol)–metal complex thermochromic polymeric systems

Thermochromic poly(vinyl alcohol) (PVA)‐based material was synthesized and an extensive study of its thermochromic behavior with respect to response time was carried out. It was observed that it is possible to manipulate the response time by keeping control over chemical and physical parameters. The response time, which is the most important property of a smart material, has in this case been found to be very much influenced by rate of heat transfer into the material. Different compositions of the thermochromic material and their corresponding response time with respect to rate of heat transfer were studied and correlated. First, a theoretical equation was derived and later on it was experimentally verified to quantify the response time in PVA–metal complex‐based thermochromic systems. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4832–4834, 2006     

Eco-friendly electronics,based on nanocomposites of biopolyester reinforced with carbon nanotubes: a review

ABSTRACT

Fabrication of electronic materials from nanocomposite of biopolyesters reinforced with carbon nanotubes can be regarded as the effective alternative for conventional nanocomposites consisting of non-biodegradable polymers. Commercial availability of biopolyester-based nanocomposites is limited because of their high cost compared to other polymers, but the factor of their compostable nature is worthless for environmental protection. Such nanocomposites have potential applications in biodegradable sensors, EMI materials, etc. In this review, the current progress of biopolyester/CNTs nanocomposites in the field of biodegradable electronics is reviewed and also the impact of CNTs dispersion on electrical, thermal and mechanical properties of eco composites is stipulated.     

Text extraction and enhancement of binary images using cellular automata

Text characters embedded in images represent a rich source of information for content-based indexing and retrieval applications. However, these text characters are difficult to be detected and recognized due to their various sizes, grayscale values, and complex backgrounds. Existing methods cannot handle well those texts with different contrast or embedded in a complex image background. In this paper, a set of sequential algorithms for text extraction and enhancement of image using cellular automata are proposed. The image enhancement includes gray level, contrast manipulation, edge detection, and filtering. First, it applies edge detection and uses a threshold to filter out for low-contrast text and simplify complex background of high-contrast text from binary image. The proposed algorithm is simple and easy to use and requires only a sample texture binary image as an input. It generates textures with perceived quality, better than those proposed by earlier published techniques. The performance of our method is demonstrated by presenting experimental results for a set of text based binary images. The quality of thresholding is assessed using the precision and recall analysis of the resultant text in the binary image.