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1.
Polyaniline (PANI) was synthesized by chemical oxidative polymerization of aniline dissolved in aqueous phosphoric acid. The polymer was characterized by UV–Visible spectroscopy (UV–Vis), thermal gravimetric analysis (TGA) and Fourier transform infrared spectroscopic (FTIR) techniques. Hardener free epoxy coating was formulated with 10% PANI. The curing process of epoxy resin by PANI was analyzed using FTIR and a suitable mechanism of curing was suggested. The corrosion protective performance of conventional polyamide cured epoxy and PANI cured epoxy coating on steel has been assessed in 3% NaCl by electrochemical impedance spectroscopy (EIS). The self-healing property of the PANI cured epoxy coating on steel in 3% NaCl was studied by scanning vibrating electrode technique (SVET). 相似文献
2.
S. Dhanasekaran Aravind Vadiraj G. Balachandran M. Kamaraj 《Transactions of the Indian Institute of Metals》2010,63(5):779-785
Austempering of a ferrite-pearlitic grade of ductile iron was carried out to assess the potential use of the material for
crank shaft application reported. A commercial material was austempered at 340°C to realize the properties. The austempered
ductile iron gave good strength although the ductility values were lower. The material developed had complete ausferritric
structure free of pearlite. The various phase constitution and phase transformation associated with the treatment and during
mechanical deformation was examined. Using XRD analysis the volume fraction of the austenite in the matrix was estimated.
The various aspects of processing a commercial cast iron during ausetmpering, the phase transformation, microstructural evolution
have been examined along with the property of the material. The mechanical behaviour of the material and the scope for further
improvement is discussed. 相似文献
3.
Alloyed gray cast iron of varying compositions was studied for their wear behavior. In general, the alloyed gray irons studied have higher graphite volume fraction (∼20%) with Type-A graphite flake morphology. Base cast iron showed two to three times higher wear rates than the alloyed gray irons. Tensile strength and wear rates show decreasing trend with increase in graphite and carbide volume fraction. Wear track analysis shows three body abrasive wear mode resulting in debris generation and smudging along the wear tracks. The graphite gets released during sliding to form films along the wear tracks and then forms irregular debris. 相似文献
4.
High temperature superconducting LaBa2Cu3O7−δ has been prepared by ceramic and nitrate methods to understand the influence of preparation conditions on superconductivity.
The characterization was carried out by X-ray diffraction and magnetic susceptibility measurements.T
c onset was observed at 88 K. Meissner effect has been observed above the liquid nitrogen temperature. 相似文献
5.
6.
T. Manisekaran M. Kamaraj S.M. Sharrif S.V. Joshi 《Journal of Materials Engineering and Performance》2007,16(5):567-572
Hydroturbine steels, such as 13Cr-4Ni martensitic steels, are generally subjected to heavy-erosive wear and loss of efficiency
due to solid particulate entrainment in the water. Surface-modified steels have proven to give better performance in terms
of erosive wear resistance. In the present study, an attempt is made to investigate the effect of angle of impingement and
particle size on slurry-jet erosion behavior of pulsed plasma nitrided and laser hardened 13Cr-4Ni steels. Laser hardening
process has shown good performance at all angles of impingement due to martensitic transformation of retained austenite. Plastic
deformation mode of material removal was also an evident feature of all laser-hardened surface damage locations. However,
pulsed-plasma nitrided steels have exhibited chip formation and micro-cutting mode of erosive wear. Erosion with 150-300 μm
size was twice compared to 150 μm size slurry particulates. 相似文献
7.
8.
9.
Fretting fatigue is an adhesive wear mechanism caused by repetitive tangential micro-oscillation between two contacting materials
pressed together under cyclic load. Bioimplants, such as hip joints and bone plates, are prone to undergo fretting fatigue
failures during their service within the body. This article presents the fretting fatigue damage characterization of physical
vapor deposition (PVD) TiN-coated biomedical titanium alloys (Ti-6Al-4V and Ti-6Al-7Nb) subjected to cyclic loads. The PVD
TiN layer delayed the damage because of superior tribological properties compared with uncoated alloys. Delamination and abrasive
wear damage of TiN at contact caused failure of the alloy. Friction coefficient curves of the PVD TiN-coated pair showed an
irregular pattern caused by the influence of wear particulates and Ringer fluid at the contact. 相似文献
10.
Bonghyun Jo Hansol Park Eswaran Kamaraj Sewook Lee Bumho Jung Sivaraman Somasundaram Gyeong G. Jeon Kyu-Tae Lee Namdoo Kim Jong H. Kim Bong-Gi Kim Tae Kyu Ahn Sanghyuk Park Hui Joon Park 《Advanced functional materials》2021,31(5):2007180
Intrinsic characteristics of organic semiconductor-based hole transport materials (HTMs) such as facile synthesizability, energy level tunability, and charge transport capability have been highlighted as crucial factors determining the performances of perovskite photovoltaic (PV) cells. However, their properties in the excited state have not been actively studied, although PVs are operated under solar illumination. Here, the characteristics of organic HTMs in their excited state such as transition dipole moment can be a decisive factor that can improve built-in potential of PVs, consequently enhancing their charge extraction property as well as reducing carrier recombination. Moreover, the aggregation property of organic semiconductors, which has been an essential factor for high-performance organic HTMs to improve their carrier transport property, can induce a synergistic effect with their excited state property for the high-efficiency perovskite PVs. Additionally, it is also confirmed that their optical bandgaps, manipulated to have their absorption in the UV region, are beneficial to block UV light that degrades the quality of perovskite, consequently improving the stability of perovskite PV in p–i–n configuration. As a proof-of-concept, a model system, composed of triarylamine and imidazole-based organic HTMs, is designed, and it is believed that this strategy paves a way toward high-performance and stable perovskite PV devices. 相似文献