Auslegungskonzept für pulsierte Siebboden-Extraktoren

A concept for the design of pulsed sieve-plate extractors . A concept is presented for the design of pulsed sieve-plate extractors (PSE) according to which the column diameter is calculated via the flooding load and the column length by concentration profiles using the well known backmixing models. This concept requires some parameters to describe the hydrodynamic and mass transfer behaviour. The parameters depend on physical properties, operating conditions, and extractor geometry and subject to mutual influence. It is now possible to present correlations and models for prediction of these parameters. The mass transfer term can be determined by Sherwood correlations for single drops, using the Sauter mean drop diameter. The total mass transfer coefficient can be given as a function of column lenght. The calculated concentration profiles agree well with the measured profiles and thus the concept is confirmed.     

Mathematical model for post combustion in smelting reduction

Post combustion in the top space of iron bath smelting reduction furnaces is analysed with three-dimensional mathematical modelling. Momentum transport and continuity equations in combination with a k-? model of turbulence are numerically solved for the gas flow field. Combustion reactions are modelled by a set of transport equations based on the SCRS combustion model and its extension to the k-?-g model. A two-stage combustion scheme is formulated to include carbon transfer and combustion. Heat transfer to bath and droplets is approximated including radiation. Computation results for rectangular reactors are presented with velocity patterns and combustion fields. The complex shapes of post combustion flames are demonstrated. Process parameters are varied to study their influence on combustion and heat transfer to the bath. Effects of the injection geometry are illustrated.     

Flow fields in electromagnetic stirring of rectangular strands with linear inductors: Part II. computation of flow fields in billets,blooms, and slabs of steel

The model presented in Part I of this series of papers is used to compute flow velocities in the longitudinal stirring of steel blooms and billets, and in the horizontal stirring of steel slabs. In longitudinal stirring of blooms and billets the reverse flow is on the side of the strand opposite to the inductor. The effects of penetration depth of the electromagnetic force, of the force itself, of the length of the stirrer, and of the width of the liquid core were determined. In horizontal stirring of slabs the reverse flow takes place outside of the stirrer region, forming the so-called butterfly stirring pattern. The characteristics of this flow field depend to a considerable extent on the width of the stirrer. The effects of stirrer width, of thickness of the liquid core, of force and of width of the slab were elucidated. The maximum velocities in both types of stirring are represented as simple formulae.     

Method for quantifying nitromethane in blood as a potential biomarker of halonitromethane exposure

The cytotoxicity and genotoxicity of nitromethane and its halogenated analogues in mammals raise concerns about potential toxicity to humans. This study shows that halonitromethanes are not stable in human blood and undergo dehalogenation to form nitromethane. We quantified nitromethane in human blood using solid-phase microextraction (SPME) headspace sampling coupled with gas chromatography (GC) and high resolution mass spectrometry (HRMS). The limit of detection was 0.01 microg/L with a linear calibration curve spanning 3 orders of magnitude. This method employs isotope dilution to precisely quantify trace amounts of nitromethane (coefficient of variation <6%). At three spiked concentrations of nitromethane, method accuracy ranged from 88 to 99%. We applied this method to blood samples collected from 632 people with no known occupational exposure to nitromethane or halonitromethanes. Nitromethane was detected in all blood samples tested (range: 0.28-3.79 microg/L, median: 0.66 microg/L). Time-course experiments with trichloronitromethane- and tribromonitromethane-spiked blood showed that nitromethane was the major product formed (1 nmole tribromonitromethane formed 0.59 nmole of nitromethane, whereas 1 nmole trichloronitromethane formed 0.77 nmole nitromethane). Nitromethane may form endogenously from peroxynitrite: nitromethane concentrations increased proportionately in blood samples spiked with peroxynitrite. Blood nitromethane can be a biomarker of exposure to both nitromethane and halonitromethanes. This sensitive, accurate, and precise analytical method can be used to determine baseline blood nitromethane level in the general population. It can also be used to study the health impact from exposure to nitromethane and halonitromethanes in occupational environments and to assess trichloronitromethane (chloropicrin) exposure in chemical terrorism investigations.     

Inclusions in continuously cast steel slabs - numerical model and validation

A numerical model for liquid steel flow and inclusion transport and separation in continuous casting moulds is presented, which covers several features simultaneously. The free surface at the meniscus is computed; the submerged entry nozzle is discretised in detail to resolve the outlet geometry; gas injection through the SEN and its effect on liquid steel flow are considered; capture of inclusions within gas bubbles is covered in a simplified approach; the solidifying shell and the process of inclusion entrapment by the growing shell are simulated. Computed flow profiles are compared to experimental results on water and to measurements on liquid steel in a slab caster. Predicted inclusion profiles in solid slabs are compared to empirical findings from literature. Results of the model for various cases will be presented in a subsequent publication.     

Flow fields in electromagnetic stirring of rectangular strands with linear inductors: Part II. computation of flow fields in billets, blooms, and slabs of steel

The model presented in Part I of this series of papers is used to compute flow velocities in the longitudinal stirring of steel blooms and billets, and in the horizontal stirring of steel slabs. In longitudinal stirring of blooms and billets the reverse flow is on the side of the strand opposite to the inductor. The effects of penetration depth of the electromagnetic force, of the force itself, of the length of the stirrer, and of the width of the liquid core were determined. In horizontal stirring of slabs the reverse flow takes place outside of the stirrer region, forming the so-called butterfly stirring pattern. The characteristics of this flow field depend to a considerable extent on the width of the stirrer. The effects of stirrer width, of thickness of the liquid core, of force and of width of the slab were elucidated. The maximum velocities in both types of stirring are represented as simple formulae. Formerly with Institut für Allgemeine Metallurgie, Technische Universit?t Clausthal     

Melting of ESR electrodes

Model for computation of temperature, melting profile and depth of immersion of ESR electrodes. Comparison with experimental results. Energy balance. Dimensionless representation of relations between process parameters. Approximation formula for immersion depth.     

Flow fields in electromagnetic stirring of rectangular strands with linear inductors: Part I. theory and experiments with cold models

A model is presented to compute the electromagnetic force fields and fluid flow fields in electromagnetic stirring of continuously cast strands with rectangular cross-section. The model involves the solution of the Maxwell equations, the Navier-Stokes equations, and the transport equations for the turbulence characteristicsk and e. The procedure of depth-averaging is applied in the treatment of several three-dimensional flows. Experiments were performed to check the computations using mercury as fluid. The spatial distribution of the magnetic induction and of the force density was determined for the laboratory inductor used in the stirring experiments. The flow velocity was measured photographically or with a drag probe, respectively. The agreement between experimental and theoretical data was found to be within 25 pct. It is concluded that the theory is sufficiently reliable to predict the flow fields in electromagnetic stirring of steel strands. In Part II of this paper the model is applied to analyze stirring situations in continuous casting of steel. Formerly with Institut für Allgemeine Metallurgie, Technische Universit?t Clausthal     

Discretization of the expliclt enthalpy method for planar phase change

A procedure to discretize explicit enthalpy formulations for one-dimensional planar phase change problems is derived, which removes numerical oscillations in temperature and phase front position. The technique is based on an enthalpy balance for the control volume containing the phase front in combination with linearized temperature profiles near the phase front. A continuous casting solidification problem and a problem with known analytical solution are applied to demonstrate the effect of the scheme.