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排序方式: 共有195条查询结果,搜索用时 15 毫秒
1.
Katja F. Hellendahl Felix Kaspar Dr. Xinrui Zhou Zhaoyi Yang Prof. Dr. Zhen Huang Prof. Dr. Peter Neubauer Dr. Anke Kurreck 《Chembiochem : a European journal of chemical biology》2021,22(11):2002-2009
Selenium-modified nucleosides are powerful tools to study the structure and function of nucleic acids and their protein interactions. The widespread application of 2-selenopyrimidine nucleosides is currently limited by low yields in established synthetic routes. Herein, we describe the optimization of the synthesis of 2-Se-uridine and 2-Se-thymidine derivatives by thermostable nucleoside phosphorylases in transglycosylation reactions using natural uridine or thymidine as sugar donors. Reactions were performed at 60 or 80 °C and at pH 9 under hypoxic conditions to improve the solubility and stability of the 2-Se-nucleobases in aqueous media. To optimize the conversion, the reaction equilibria in analytical transglycosylation reactions were studied. The equilibrium constants of phosphorolysis of the 2-Se-pyrimidines were between 5 and 10, and therefore differ by an order of magnitude from the equilibrium constants of any other known case. Hence, the thermodynamic properties of the target nucleosides are inherently unfavorable, and this complicates their synthesis significantly. A tenfold excess of sugar donor was needed to achieve 40−48 % conversion to the target nucleoside. Scale-up of the optimized conditions provided four Se-containing nucleosides in 6–40 % isolated yield, which compares favorably to established chemical routes. 相似文献
2.
Direct charging of thin slabs of low carbon steel (0.05%C) was investigated by using laboratory tests on a thin-slab-casting Simulator linked with the hot deformation Simulator (Wumsi). Starting with a different initial thickness of simulated thin slabs (45 down to 25 mm) the total strain ?∑ was varied. Hot deformation schedules (with and without roughing) with different finishing temperatures TF lead to some differences in the hot strip microstructure. Nevertheless, after cold rolling and batch annealing, a rather uniform pancake-structure and a pronounced {111}-texture were achieved in the cold strip without any significant relation to the processing routs. The measurement of final mechanical properties proved that a good deep drawability of cold strip can be achieved with direct charging of thin slabs, well comparable to that after a conventional cold charging of thick slabs. 相似文献
3.
Radko Kaspar 《国际钢铁研究》2003,74(5):318-326
By using a thin slab casting simulator combined with the hot deformation simulator WUMSI, laboratory tests were performed to investigate the microstructure processes and mechanical properties in the process of thin slab direct rolling (TSDR). The paper shows the possibilities to improve the initial as‐cast state of microstructure prior to hot rolling (microvoids, dendritic structure, austenite grain size, state of precipitation). The main part of the study is dedicated to the role of microalloying and sulphur for the austenite grain control and for the precipitation hardening in the final structure. On examples of selected low carbon steel grades the effect of the variation of the process parameters of hot rolling and cooling on the microstructure and mechanical properties is presented. 相似文献
4.
Forrer P Binz HK Stumpp MT Plückthun A 《Chembiochem : a European journal of chemical biology》2004,5(2):183-189
Consensus design is a valuable protein-engineering method that is based on statistical information derived from sequence alignments of homologous proteins. Recently, consensus design was adapted to repeat proteins. We discuss the potential of this novel repeat-based approach for the design of consensus repeat proteins and repeat protein libraries and summarize recent results from such experiments. 相似文献
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Previous findings suggested that banner ads have little or no impact on perceptual behavior and memory performance in search tasks, but only in browsing paradigms. This assumption is not supported by the present eye-tracking study. It investigates whether task-related selective attention is disrupted depending on the animation intensity of banner ads when users are in a search mode as well as the impact of banner animation on perceptual and memory performance. 相似文献
7.
Hydrogen is a promising alternative for current energy carriers. Compressed gas cylinders are the storage systems closest to the commercialization of hydrogen in vehicles. The safety factors in current standards are seen as restrictive for further growth and competitiveness of hydrogen infrastructure. A probabilistic approach can be employed in order to give a rational background to the safety factors. However, an acceptable probability of failure needs to be estimated before calculating the safety factors. The discussion of determining the acceptable probability must include the mass of hydrogen since this determines the consequences of an accident. It is concluded that an annual probability of failure of 10−7 would be appropriate for small pressure vessels containing a few kilograms of hydrogen. Larger pressure vessels of a few hundred kilograms or more should be designed for an annual probability 10−8. 相似文献
8.
Water Sorption and Diffusion in (Reduced) Graphene Oxide‐Alginate Biopolymer Nanocomposites 下载免费PDF全文
Karolis Vilcinskas Jure Zlopasa Kaspar M. B. Jansen Fokko M. Mulder Stephen J. Picken Ger J. M. Koper 《大分子材料与工程》2016,301(9):1049-1063
The water sorption and diffusion in (reduced) graphene oxide‐alginate composites of various compositions is analyzed. Water sorption of sodium alginate can be significantly reduced by the inclusion of graphene oxide sheets due to the formation of an extensive hydrogen bonding network between oxygenated groups. Crosslinking alginate with divalent metal ions and the presence of reduced graphene oxide can further improve the swelling resistance due to the strong interactions between metal ions, alginate, and filler sheets. Depending on conditions and composition, the overall water barrier properties of alginate composites improve upon (reduced) graphene oxide filling, making them attractive for moisture barrier coating applications. Water sorption kinetics in all alginate composites indicate a non‐Fickian diffusion process that can be accurately described by the Variable Surface Concentration model. In addition, the water barrier properties of sodium alginate‐graphene oxide composites can be adequately predicted using a simple model that takes the orientational order of filler sheets and their effective aspect ratio into account.
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10.
J.H. Argyris L.E. Vaz K.J. Willam 《Computer Methods in Applied Mechanics and Engineering》1978,16(2):231-277
The objective of the paper is an assessment of the incremental solution methods for the analysis of inelastic rate problems. In particular, the possibilities of the initial load method are explored to improve the accuracy and stability of the traditional explicit operators by higher-order time expansions and implicit weighting schemes.The convergence limitations are examined for different classes of inelastic growth laws (viscous flow, viscoelasticity, viscoplasticity) which restrict the time step because of the iterative solution of the implicit algorithm. The range and rate of convergence of the initial load method (constant stiffness predictor-corrector iteration) is enlarged by tangential gradient techniques which account for the inelastic response in the structural stiffness matrix. In this way the time step restriction disappears although at a considerable increase of computational expense because of the costly computation and decomposition of structural gradients within each iteration cycle (Newton-Raphson methods).As compared to the linear single-step methods, the cubic Hermitian time expansions furnish far better accuracy than the traditional linear expansions for very little increase of computational cost. Stability and convergence limits correspond to those of the lower-order operators, whereby the implicit midstep of backward weighting schemes are most advantageous. In this context it is worth noting that aging or strain-hardening effects in the inelastic growth law reduce dramatically the time step restrictions of the iterative initial load solution methods (predictor-corrector schemes), as compared to the simplest creep model in which the inelastic growth law depends only on stress, e.g. for viscous flow and viscoplasticity. 相似文献