Inkjet printing of photocatalytically active TiO2 thin films from water based precursor solutions

In this work, aqueous chemical solution deposition route suited for inkjet printing is used for the synthesis of photocatalytically active TiO₂ coatings. Environmentally friendly precursor solutions with electromagnetic ink-jet printing, allows cheap and simple processing of TiO₂ films on glass. The hydrolysis reaction of water sensitive titanium alkoxide (Ti-alkoxide) precursor is controlled by adding complexing agents as citric acid and triethanolamine prior to water addition, and aqueous stable solutions are achieved. The pH of the solutions is brought to neutral to guarantee flexible processing, avoid damage to substrates and equipment. Solution parameters are adapted to obtain optimal gelation conditions and good jettability. The influence of processing parameters on the phase formation and surface morphology is studied by thermogravimetric analysis and differential thermal analysis (TGA/DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The photocatalytic activity of the films is evaluated by the degradation of methyl orange.     

采用水基前驱溶液喷墨印刷制备光催化活性TiO2薄膜

摘译 近年来,作为一种高能量带隙半导体,二氧化钛(TiO2)由于在紫外光照射下具有良好的光催化活性,已引起科研人员的广泛关注.由于TiO2无色透明,具有广泛的应用前景,如薄的TiO2涂层可用于创建自清洁、防雾、超亲水表面.同时,也能用于太阳能电池等光电子行业. 化学溶液沉积法因具有相对简单的大面积生产工艺,且较低的制膜成本和高可用性,成为TiO2薄膜制备常用的方法之一.针对另一种TiO2制备方法,即溶胶凝胶法,大量研究文献主要关注乙醇的水解控制.然而,工业需求鼓励开发水基前驱设计.其难度在于钛醇盐与水的高反应性.在有机介质中,加入少量的水往往导致水解.因此,需要采用络合剂作为稳定剂,阻止纯水中的水解反应和避免由此产生的产物沉淀.     

Linking Performance and Collective Action—the Case of the Office du Niger Irrigation Scheme in Mali

Increasing irrigation efficiency in irrigation schemes has always been high on the agenda of policy makers. Despite quite some ‘social’ experiments, whereby large portions of management were carried over to the farmer level, results often remained disappointing. This paper explores why this came about for a case study in the Office du Niger irrigation scheme in Mali. Since Irrigation Management Transfer, farmers are responsible for the tertiary level, but collective action for water management remains below expectations. This paper applies an analytical framework based on the conceptual model developed by van Noordwijk et al. (Conserv Ecol 5:21, 2002) and proceeding in two steps. Firstly, an interview-based stakeholder analysis assesses the objectives and mental models of farmers and the central management regarding water management. It appears from the interviews that the central management wants to increase irrigation efficiency through fully-fledged collective action, whereas farmers value the latter only when it favours easy irrigation. Secondly, the relation between collective action and performance was tested through a field study on a sample of 36 tertiary blocks. Results indicate that only collective action at the inlet of the tertiary canal, currently implemented on less than a third of the tertiary blocks, increases irrigation efficiency (with 14%). Collective action for water allocation is implemented within almost three quarters of tertiary blocks and effectively reduces irrigation problems. However, if they lack the necessary social capital, not all farmers can establish collective action when needed. Based on this analysis, the paper proposes a mix of incentives and measures to resolve the conflict between farmers and the central management to their mutual benefit.     

Lattice expansion in seamless bilayer graphene constrictions at high bias

Our understanding of sp(2) carbon nanostructures is still emerging and is important for the development of high performance all carbon devices. For example, in terms of the structural behavior of graphene or bilayer graphene at high bias, little to nothing is known. To this end, we investigated bilayer graphene constrictions with closed edges (seamless) at high bias using in situ atomic resolution transmission electron microscopy. We directly observe a highly localized anomalously large lattice expansion inside the constriction. Both the current density and lattice expansion increase as the bilayer graphene constriction narrows. As the constriction width decreases below 10 nm, shortly before failure, the current density rises to 4 × 10(9) A cm(-2) and the constriction exhibits a lattice expansion with a uniaxial component showing an expansion approaching 5% and an isotropic component showing an expansion exceeding 1%. The origin of the lattice expansion is hard to fully ascribe to thermal expansion. Impact ionization is a process in which charge carriers transfer from bonding states to antibonding states, thus weakening bonds. The altered character of C-C bonds by impact ionization could explain the anomalously large lattice expansion we observe in seamless bilayer graphene constrictions. Moreover, impact ionization might also contribute to the observed anisotropy in the lattice expansion, although strain is probably the predominant factor.     

Toward quantum computation: a five-qubit quantum processor

Quantum physics presents intriguing possibilities for achieving computational gains after conventional miniaturization reaches its limits. Accordingly, we describe a nuclear magnetic-resonance quantum computer demonstrating a quantum algorithm that exponentially outperforms classical algorithms     

Dot-To-Dot Design

Basically, this paper discusses how researchers are connecting tiny puddles of electronics in a chip and making them compute in the quantum way.     

Graphene at high bias: cracking, layer by layer sublimation, and fusing

Graphene and few-layer graphene at high bias expose a wealth of phenomena due to the high temperatures reached. With in situ transmission electron microscopy, we observe directly how the current modifies the structure, and vice versa. In some samples, cracks propagate from the edges of the flakes, leading to the formation of narrow constrictions or to nanometer spaced gaps after breakdown. In other samples, we find layer-by-layer evaporation of few-layer graphene, which could be exploited for the controlled production of single layer graphene from multilayered samples. Surprisingly, we even find that two pieces of graphene that overlap can heal out at high bias and form one continuous sheet. These findings open up new avenues to structure graphene for specific device applications.     

Design and Synthesis of a Series of Piperazine‐1‐carboxamidine Derivatives with Antifungal Activity Resulting from Accumulation of Endogenous Reactive Oxygen Species

In this study, we screened a library of 500 compounds for fungicidal activity via induction of endogenous reactive oxygen species (ROS) accumulation. Structure–activity relationship studies showed that piperazine‐1‐carboxamidine analogues with large atoms or large side chains substituted on the phenyl group at the R³ and R⁵ positions are characterized by a high ROS accumulation capacity in Candida albicans and a high fungicidal activity. Moreover, we could link the fungicidal mode of action of the piperazine‐1‐carboxamidine derivatives to the accumulation of endogenous ROS.     

Room-temperature gating of molecular junctions using few-layer graphene nanogap electrodes

We report on a method to fabricate and measure gateable molecular junctions that are stable at room temperature. The devices are made by depositing molecules inside a few-layer graphene nanogap, formed by feedback controlled electroburning. The gaps have separations on the order of 1-2 nm as estimated from a Simmons model for tunneling. The molecular junctions display gateable I-V-characteristics at room temperature.     

Simulating Water Management and Supply Effects at the Office du Niger Collective Canal Irrigation Scheme

This paper demonstrated how a modeling approach can be used to find the optimal mix of farmers’ water management practices to improve irrigation efficiency at the tertiary level in collective canal schemes. The approach is developed for the case of the Office du Niger and based on a field study of 3?years. First, a simulation model is presented in which all relevant physical and social aspects of water management at the farmers’ level are considered. Next, simulations are performed to evaluate the impact on performance of different combinations of management practices and different external conditions. Finally, the combinations are selected that succeed in limiting seasonal water consumption to 1,400?mm and avoiding irrigation problems, but which are also realistic from a farmer’s point of view. Results demonstrate that in the Office du Niger, where seasonal water consumption per hectare should be reduced by about 30%, a tight control of the tertiary intake in combination with a good maintenance of the tertiary canal should be proposed. Although the model software is built especially for the case of the Office du Niger, the concept of the model can be transferred to other irrigation schemes, as it uses only simple hydraulic principles and limited data input.