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The devolatilization and volatile combustion of a single coal particle in spouted and spout-fluid beds have been studied. The results showed that the flame extinction time increases with the particle diameter, and decreases with the bed temperature. When the bed temperature and the air flow rate were fixed, the operation modes (spouted or spout-fluid bed) showed less effect on the mean flame extinction time. A mathematical model of the spouted bed mode for preignition and postignition periods has also been developed assuming the devolatilization rate to be controlled by heat transfer and multireaction pyrolysis kinetics based on volatile products. Ignition, heat transfer back from the volatile flame to the particle surface, variation in flame temperature, and the hydrodynamics of SB are taken into account. The model predictions, with some adjusting parameters, were in good agreement with experimental results. 相似文献
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The objective of this study is to determine the chemical kinetics of desulphurization of Thai limestone in an atmospheric fluidized bed combustor (AFBC). The experiments, which employed the batch technique using the limestone samples from six major sources in Thailand, were performed in a laboratory‐scale AFBC. The results obtained were analysed and correlated in the form of apparent reaction rate and deactivation rate constants as a function of operating conditions of the furnace and their properties, respectively. The formulae derived from these correlations were kept as general as possible in order that they could be used as input parameters for the selected mathematical model of desulphurization in an AFBC that is suitable for practical use. The predicted results were in good agreement with the experimental data reported in the literature. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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The proposed mode of consideration of the steel-concrete interaction (Part I) is applied to real-life engineering structures. Two structures recently investigated numerically at Vienna University of Technology are considered: (1) the reinforced concrete (RC) cooling tower III Ptolema?s SES (Greece) and (2) a part of the shotcrete tunnel lining installed at the Lainzer tunnel (Austria). In both examples, the uniaxial fracture criterion used in Part I is replaced by the maximum stress (Rankine) criterion. Together with the Drucker-Prager criterion, which is used for the simulation of compressive failure of concrete/shotcrete, it defines the space of admissible stress states in the framework of multisurface plasticity. For the simulation of early-age fracture of shotcrete, consideration of the steel-concrete interaction presented in Part I of this paper is extended towards young shotcrete. Similar to the benchmark problem investigated in Part I of this paper, several analyses with different degrees of consideration of the steel-concrete interaction are performed. The obtained results give insight into the influence of the steel-concrete interaction on the load-carrying behavior of the investigated structures. 相似文献
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在长途通信网和市话通信网中光纤通信网代替电缆通信网已成为被世界所公认的事实。此时因为通信距离影响,导致利用率的不断下降,所以为光纤通信取得进一步发展,必须寻找新的途径,采用新的技术。本文首先简要概述光纤通信技术特点,然后阐明光纤通信新技术的实践应用,最后进行对光纤通信新技术的研究探讨。 相似文献
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Rodrigo F. Ortiz-Meoz Liping Wang Rosalie Matico Anna Rutkowska-Klute Martha De la Rosa Sabrina Bedard Robert Midgett Katrin Strohmer Douglas Thomson Cunyu Zhang Makda Mebrahtu Jeffrey Guss Rachel Totoritis Thomas Consler Nino Campobasso David Taylor Tia Lewis Kurt Weaver Marcel Muelbaier John Seal Richard Dunham Wieslaw Kazmierski David Favre Giovanna Bergamini Lisa Shewchuk Alan Rendina Guofeng Zhang 《Chembiochem : a European journal of chemical biology》2021,22(3):516-522
Indoleamine-2,3-dioxygenase 1 (IDO1) is a heme-containing enzyme that catalyzes the rate-limiting step in the kynurenine pathway of tryptophan (TRP) metabolism. As it is an inflammation-induced immunoregulatory enzyme, pharmacological inhibition of IDO1 activity is currently being pursued as a potential therapeutic tool for the treatment of cancer and other disease states. As such, a detailed understanding of the mechanism of action of IDO1 inhibitors with various mechanisms of inhibition is of great interest. Comparison of an apo-form-binding IDO1 inhibitor (GSK5628) to the heme-coordinating compound, epacadostat (Incyte), allows us to explore the details of the apo-binding inhibition of IDO1. Herein, we demonstrate that GSK5628 inhibits IDO1 by competing with heme for binding to a heme-free conformation of the enzyme (apo-IDO1), whereas epacadostat coordinates its binding with the iron atom of the IDO1 heme cofactor. Comparison of these two compounds in cellular systems reveals a long-lasting inhibitory effect of GSK5628, previously undescribed for other known IDO1 inhibitors. Detailed characterization of this apo-binding mechanism for IDO1 inhibition might help design superior inhibitors or could confer a unique competitive advantage over other IDO1 inhibitors vis-à-vis specificity and pharmacokinetic parameters. 相似文献
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有机改性蒙脱土/木粉/PVC复合材料的阻燃性研究 总被引:2,自引:0,他引:2
将有机改性蒙脱土(OMMT)加入PVC木塑体系,制备了有机蒙脱土/木粉/聚氯乙烯(OMMT/WF/PVC)纳米复合材料。采用锥形扫描量热测试法研究了OMMT用量对WF/PVC复合材料阻燃性能的影响。结果表明,添加OMMT可明显降低木塑的初始热失重率,但使快速热分解的开始时间提前,大大提高样品的燃烧残余率,显著延迟木塑的点燃时间和燃烧热峰值产生时间,OMMT起到了有效的阻燃作用。OMMT的加入还降低了总燃烧热,但燃烧热峰值有所增加,并使发烟量有所增加,CO和CO2产率也随之提高,增加了木塑燃烧的烟气危害性。 相似文献