Large Area Self-Assembled Ultrathin Polyimine Nanofilms Formed at the Liquid–Liquid Interface Used for Molecular Separation

Separation membranes with higher molecular weight cut-offs are needed to separate ions and small molecules from a mixed feed. The molecular sieving phenomenon can be utilized to separate smaller species with well-defined dimensions from a mixture. Here, the formation of freestanding polyimine nanofilms with thicknesses down to ≈14 nm synthesized via self-assembly of pre-synthesized imine oligomers is reported. Nanofilms are fabricated at the water–xylene interface followed by reversible condensation of polymerization according to the Pieranski theory. Polyimine nanofilm composite membranes are made via transferring the freestanding nanofilm onto ultrafiltration supports. High water permeance of 49.5 L m^-2 h⁻¹ bar⁻¹ is achieved with a complete rejection of brilliant blue-R (BBR; molecular weight = 825 g mol⁻¹) and no more than 10% rejection of monovalent and divalent salts. However, for a mixed feed of BBR dye and monovalent salt, the salt rejection is increased to ≈18%. Membranes are also capable of separating small dyes (e.g., methyl orange; MO; molecular weight = 327 g mol⁻¹) from a mixed feed of BBR and MO. Considering a thickness of ≈14 nm and its separation efficiency, the present membrane has significance in separation processes.     

Effect of Starting As-cast Structure on the Microstructure–Texture Evolution During Subsequent Processing and Finally Ridging Behavior of Ferritic Stainless Steel

Metallurgical and Materials Transactions A - Effect of the initial as-cast structure on the microstructure–texture evolution during thermomechanical processing of 409L grade ferritic...     

Application of RCM to a medium scale industry

The factors which are assuming considerable importance in cost effective decision making of operation of any industrial enterprise are in the order of significance liability, safety and environmental conditions. Hence, preventive maintenance (PM) optimisation is providing wide opportunities and challenges to everyone involved in all aspects of operation of industrial enterprise. Reliability centred maintenance (RCM) methodology offers the best available strategy for PM optimisation. It incorporates a new understanding of the ways in which equipment fails.In this paper, the concept of RCM has been applied to steel melting shop of a medium scale steel industry. By systematically applying the RCM methodology, failures, failure causes and effects on the system are analysed. To preserve the system function, PM categories are suggested for various failure modes in the components such as (1) time directed (2) condition directed (3) failure finding (4) run to failure. Features of predictive maintenance of a medium scale steel industry are deduced through this paper in a rather generalised form.     

Interaction of lanthanide and actinide with BaHfO3 perovskite: A case study with cerium and uranium

Speciation of actinide (An) and lanthanide (Ln) in technologically important ceramics is very important from both fundamental as well as technological aspects. The intrinsic structural flexibility of perovskite containing AO₆ and BO₁₂ polyhedra makes them suitable and rich hosts for An and Ln. In this work, emphasis was given to deciphering information such as oxidation state, local dopant site, charge compensating defects, excited state kinetics, and so forth in BaHfO₃ (BHO) related to dopant uranium (BHO-U) and cerium (BHO-Ce). Several spectroscopic techniques namely, time-resolved photoluminescence (TRPL), positron annihilation lifetime spectra (PALS), and thermoluminescence (TL) spectroscopy coupled with density functional theory (DFT) were employed to probe the same. Ce and U though are distributed at both Ba and Hf sites, Ce prefers the former, while U prefers the latter site. Uranium on the other hand stabilizes as U⁶⁺ in the form of octahedral uranate ion giving green emission. PALS suggested the formation of defects in BHO-Ce and BHO-U with oxygen vacancies predominating in the former whereas BHO-U perovskites are loaded with cation vacancies and vacancy clusters. These cation vacancies are responsible for lower TL output in BHO-U. TL measurements also suggested cerium doping leads to a higher density of deeper traps in BHO-Ce compared to uranium doping in BHO-U which is in concurrence with DFT results and may have implications in designing afterglow phosphors based on perovskite. We believe this work would have a long-term impact on exploring the potential of perovskite for nuclear waste host and afterglow phosphors applications.     

The Role of Nonuniformity in Convective Heat and Mass Transfer through Porous Media,Part 1

Through-air drying is commonly used in the drying of high-quality tissue and towel products. A representative elementary volume method was used to model the fluid flow and heat and mass transfer during through drying in heterogeneous porous biobased materials such as tissue and towel products. Results of flow both upstream and downstream of a modeled porous sheet allowed visualization of the effects of mixing at the top and bottom of the porous medium. The effect of initial nonuniformity on fluid flow and convective heat and mass transfer in heterogeneous porous media was studied. The effect of material nonhomogeneity and associated transport properties on moisture content of the porous material as a function of drying time was studied. Modeling results indicate that for the first time it is possible to simulate the effect of nonuniformity on fluid flow and convective heat and mass transfer in porous media during through-air drying of paper. Moisture and structural nonuniformity contributing to nonuniformity in air flow might contribute significantly to drying nonuniformity. Depending on the moisture regimes and degree of saturation of the convective medium, heat and mass transfer coefficients may have varying effects on the overall drying.     

The Role of Nonuniformity in Convective Heat and Mass Transfer through Porous Media,Part 2

Nonuniformities in porous materials can play a significant role in the convective and diffusive transport of fluid, heat, and mass. This study provides experimental results and corresponding numerical simulation results. The experiments report continuous data in transient test runs with measurements of temperature and velocity at distributed locations in the domain immediately downstream of the porous materials. An increasing degree of nonuniformity was found to produce a lower drying rate as well as an earlier onset of falling rate drying. The numerical model provides results of the effects of different nonhomogeneities such as distributed holes or distributed regions of varying permeability and moisture content. Comparisons between numerical and experimental test results indicate general agreement with differences with regard to details of the drying curve features. This provides a tool for studying the role of nonuniformity in fluid flow and heat and mass transfer in porous media.     

Manually powered manufacture of keyed bricks

The production of bricks, one of the main components in conventional construction technology, has been carried out by either a hand moulding process or by a fully mechanized process. Both processes have limitations in developing countries. An alternative solution is the use of decentralized non-power-consuming brick making units, utilizing unconventional raw materials which do not require baking to develop strength. A manually energized brick making machine (MEBM) has proven the feasibility of extruding various mixes including a lime-fly ash-sand mixture. The production of bricks with a keyed cross-section is investigated using the MEBM to establish the functional and economic viabilities of the technology to create a construction technology which relies on abundant resources, unskilled labour and zero energy input. La production de briques, l'un des elements essentiels de la construction traditionnelle, est assuree soit par moulage manuel, soit par des procedes entierement mecanises. Les deux procedes montrent leurs limites dans les pays en voie de developpement. Une solution alternative consiste a utiliser des machines decentralisees ne consommant pas d'energie, faisant appel a des matieres premieres non conventionnelles qui n'exigent pas de cuisson pour donner la resistance a la brique. Une machine a fabriquer les briques mue par la force manuelle (manually energized brick making machine - MEBM) a prouve sa capacite a extruder differents melanges comportant un melange de chaux et de sable cendre. La production de briques a section creuse au moyen de la MEBM est a l'etude, afin d'etablir la faisabilite economique et fonctionnelle de cette technique propre a creer une technologie de construction basee sur des ressources abondantes, une main-d'oeuvre non qualifiee et une depense energetique nulle.     

Fires of insulations on tank exteriors

This paper presents a method for calculating radiative heat transfer to an adjacent tank from fire involving insulation on tank exteriors. An approximate method for calculating the radiative flux from an ignition source is also provided. The results are generalized to allow convenient estimates of safe separations for a range of tank sizes, fire intensities, and critical ignition fluxes. Wind effects are not considered in the present study. Factory Mutual Research Corporation     

The burning of large pool fires

A non-intrusive method for obtaining the spatial distributions of radiative properties (i.e.) absorption-emission coefficients and radiation temperatures) in pool fires is described. The method consists of measuring the lateral transmittance and radiance of the fire and performing an Abel inversion on the measurements to obtain absorption-emission coefficients and local radiation temperatures in the fire. Local radiative properties so obtained are used to calculate the flame radiation flux—the dominant heat transfer mode —to the pool surface. The computed flux is in good agreement with the flux inferred from experimentally measured burning rates of the fire. These experiments are performed on a 0.73 m diameter PMMA pool fire. The results presented here show that large pool fires tend to be significantly non-uniform in temperature and species concentrations and the non-uniformities play an important role in determining the burning rate of these fires.     

Reproducible,biocompatible medical materials from biologically derived polysaccharides: Processing and Characterization

Natural polysaccharides like chitosan and dextran have garnered considerable interest in biomedical applications due to their biocompatibility, biodegradability, and nontoxicity. Nonetheless, the development of a reproducible class of medical devices from these materials is challenging and has had limited success. Chitosan and dextran are inherently variable and synthesis using these materials is prone to inconsistencies. In this study, we put forward a robust product development regimen that allows these natural materials to be developed into a reproducible class of biomaterials. First, an array of validated characterization methods (Proton Nuclear Magnetic Resonance, titrations, Ultraviolet spectroscopy, Size Exclusion Chromatography—Multi-Angle Light Scattering, Size Exclusion Chromatography—Refractive Index, and proprietary methods) were developed that allowed rigorous specifications to be set for unprocessed chitosan and dextran, chitosan and dextran intermediates, and chemically modified materials—acrylated chitosan (aCHN) and oxidized dextran (oDEX). Second, a robust and reproducible synthesis scheme involving various in-process controls was developed to chemically modify the unprocessed polysaccharides. Third, purification methods to remove byproducts and low-molecular-weight impurities for both aCHN and oDEX were developed. The study presents a viable strategy for converting variable, natural materials into a reproducible class of biomaterials that can be applied in various biomedical applications. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48454.