Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.     

Model Validation for Bridge-Road-Vehicle Dynamic Interaction System

The dynamic response of highway bridges subjected to moving truckloads has been observed to be dependent on (1) dynamic characteristics of the bridge; (2) truck configuration, speed, and lane position on the bridge; and (3) road surface roughness profile of the bridge and its approach. Historically, truckloads were measured to determine the load spectra for girder bridges. However, truckload measurements are either made for a short period of time [for example, weigh-in-motion (WIM) data] or are statistically biased (for example, weigh stations) and cost prohibitive. The objective of this paper is to present results of a 3D computer-based model for the simulation of multiple trucks on girder bridges. The model is based on the grillage approach and is applied to four steel girder bridges tested under normal truck traffic. Actual truckload data collected using a discrete bridge WIM system are used in the model. The data include axle loads, truck gross weight, axle configuration, and statistical data on multiple presence (side by side or following). The results are presented as a function of the static and dynamic stresses in each girder and compared with code provisions for dynamic load factor. The study provides an alternate method for the development of live-load models for bridge design and evaluation.     

Evaluation of Laminated Circular Elastomeric Bearings

This paper evaluates the behavior and performance of laminated circular elastomeric bearings and compares them to those of square and rectangular bearings. The study included an experimental evaluation and a nationwide survey of state Department of Transportations on the use and performance of circular bearings and bearings in general in their states. The experimental investigation studied the bearings' behavior in compression, compression and rotation, and compression and shear. Results from this limited study showed that the three bearings have similar stress-strain behavior in compression and they are in agreement with the AASHTO LRFD guide stress–strain curves. In compression and rotation, the AASHTO LRFD substructure moments are slightly less than the measured values for circular bearings and rectangular bearings rotated about their strong axis for a compressive stress of 10.3?MPa (1.5?ksi) and slightly higher than those of rectangular bearings rotated about their weak axis. In compression and shear, the shear stiffness of circular and square bearings is in agreement with theoretical values within the range of design displacements. Results from the survey showed that many states are using circular bearings and more states would consider using them, however no maintenance or monitoring data were available on their short-term and long-term performance.     

Effects of the cryogenic cooling on the fatigue strength of the AISI 304 stainless steel ground components

For environmental considerations, the substitution of the conventionally used oil-based grinding fluids has nowadays become strongly recommended. Although several alternatives have been proposed, cryogenic cooling by liquid nitrogen is the non-polluting coolant that has been given relatively more attention because of its very low temperature. In this investigation, in order to contribute to developing this promising cooling mode, its beneficial effects on the ground surface integrity of the AISI 304 stainless steel and their consequences on the fatigue lifetime are explored. Results of this investigation show that grinding under cryogenic cooling mode generates surfaces with lower roughness, less defects, higher work hardening and less tensile residual stresses than those obtained on surfaces ground under oil-based grinding fluid. These surface enhancements result into substantial improvements in the fatigue behaviour of components ground under this cooling mode. An increasing rate of almost 15% of the endurance limit at 2 × 10⁶ cycles could be realized. SEM analyses of the fatigue fracture surfaces have shown that the fatigue cracks observed on the specimens ground under cryogenic cooling are shorter (i.e., 30-50 μm) than those generated under oil-based cooling mode (i.e., 150-200 μm). The realized improvements in the surface integrity and in the fatigue behaviour are thought to be related to the reduction of the grinding zone temperature observed under cryogenic cooling, as no significant differences between the grinding force components for both cooling modes have been observed.     

Microstructure and mechanical properties of modified and non-modified stir-cast Al-Si hypoeutectic alloys

The microstructure and mechanical properties of modified and non-modified stir-cast commercial aluminium alloys A-S7G03 and A-S4G have been investigated. Stir casting of these alloys resulted in spherical and/or rosette shape primary -phase, and the eutectic silicon was broken into miniature needle morphology. This stir-cast structure slightly improved the mechanical properties in comparison to those of conventionally cast alloys, however the fracture of the stir-cast alloys revealed intergranular brittle fracture. The addition of 0.02% strontium, in the form of Al-5 mass% Sr master alloy, during stir casting modified the eutectic silicon into a very fine spheroidal morphology, while the -phase particle showed the same morphology as the stir-cast alloys. This novel structure resulted in significant improvement of mechanical properties. The elongation of the modified stir-cast alloys was five times greater than that of the non-modified one. A transgranular mode of fracture was observed for the modified stircast alloys, moreover smooth ripple and dimple patterns were observed reflecting the high ductility of the modified stir-cast alloys.     

Soluble Epoxide Hydrolase Blockade after Stroke Onset Protects Normal but Not Diabetic Mice

Soluble epoxide hydrolase (sEH) is abundant in the brain, is upregulated in type 2 diabetes mellitus (DM2), and is possible mediator of ischemic injury via the breakdown of neuroprotective epoxyeicosatrienoic acids (EETs). Prophylactic, pre-ischemic sEH blockade with 4-[[trans-4-[[(tricyclo[3.3.1.13,7]dec-1-ylamino)carbonyl]amino]cyclohexyl]oxy]-benzoic acid (tAUCB) reduces stroke-induced infarct in normal and diabetic mice, with larger neuroprotection in DM2. The present study tested whether benefit occurs in normal and DM2 mice if tAUCB is administered after stroke onset. We performed 60 min middle cerebral artery occlusion in young adult male C57BL mice divided into four groups: normal or DM2, with t-AUCB 2 mg/kg or vehicle 30 min before reperfusion. Endpoints were (1) cerebral blood flow (CBF) by laser Doppler, and (2) brain infarct at 24 h. In nondiabetic mice, t-AUCB reduced infarct size by 30% compared to vehicle-treated mice in the cortex (31.4 ± 4 vs. 43.8 ± 3 (SEM)%, respectively) and 26% in the whole hemisphere (26.3 ± 3 vs. 35.2 ± 2%, both p < 0.05). In contrast, in DM2 mice, tAUCB failed to ameliorate either cortical or hemispheric injury. No differences were seen in CBF. We conclude that tAUCB administered after ischemic stroke onset exerts brain protection in nondiabetic but not DM2 mice, that the neuroprotection appears independent of changes in gross CBF, and that DM2-induced hyperglycemia abolishes t-AUCB-mediated neuroprotection after stroke onset.     

QoS aggregation for service orchestrations based on workflow pattern rules and MCDM method: evaluation at design time and runtime

Service consumers satisfaction is considered today as one of the main concern to be ensured by service providers, especially with the spread of concurrency and the increase of functionally equivalent services. This satisfaction is closely related to quality of service (QoS) perceived by service consumers. In this context, we propose an approach to determine the satisfaction degree corresponding to the QoS of service-based applications, with regard to service consumers’ QoS expectations. Our approach is based on a preference model, which is built only on the basis of service consumer’s provided information. This preference model is also based on the 2-additive Choquet operator that takes into account preferential dependencies. In this paper, we target both design time and runtime aggregation of QoS of service-based applications.     

Stability and robustness of fuzzy adaptive control of nonlinear systems

In this paper, we propose a new approach that guarantees the stability and robustness of an adaptive control law of a nonlinear system.The control diagram proposed contains a Takagi–Sugeno–Kang fuzzy controller (TSK-FC) and a training block allowing the online adaptation of the FC parameters. The adaptation algorithm used is based on the gradient with minimization of the quadratic error between the system output and that desired by using the direct method of Lyapunov. However, our approach considers the gradient step of each adaptive FC parameter to be bound. This approach was applied to the control of an inverted pendulum. The results obtained confirm well the validity of such an adaptation especially the guarantee of the pendulum stability and the robustness of its control with respect to the disturbances introduced on the FC parameters and the pendulum itself.