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Niamh Harbourne Eunice Marete Jean Christophe Jacquier Dolores O'Riordan 《Food research international (Ottawa, Ont.)》2013,50(2):480-486
Recently phytochemical constituents have attracted a lot of interest as sources of functional ingredients in food product formulations. However, before being incorporated into foods or beverages the stability of these bioactive constituents during post-harvest preservation procedures, in food matrices and during processing and storage must be considered. This review will focus on the stability of phytochemical constituents of herbs with anti-inflammatory properties, including chamomile, meadowsweet, feverfew and willow. These herbs contain a relatively high content of phenolic compounds in comparison to common fruits and vegetables. They have been traditionally used to make teas or infusions that are consumed as a remedy for pain and inflammation. Effects of preservation and extraction conditions on the level of bioactive constituents will be reviewed. The storage conditions (temperature) and thermal processing at pH levels encountered in food products will also be examined. 相似文献
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Milders Maarten; Sahraie Arash; Logan Sarah; Donnellon Niamh 《Canadian Metallurgical Quarterly》2006,6(1):10
A central question in perception is how stimuli are selected for access to awareness. This study investigated the impact of emotional meaning on detection of faces using the attention blink paradigm. Experiment 1 showed that fearful faces were detected more frequently than neutral faces, and Experiment 2 revealed preferential detection of fearful faces compared with happy faces. To rule out image artifacts as a cause for these results, Experiment 3 manipulated the emotional meaning of neutral faces through fear conditioning and showed a selective increase in detection of conditioned faces. These results extend previous reports of preferential detection of emotional words or schematic objects and suggest that fear conditioning can modulate detection of formerly neutral stimuli. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
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In this work, the up-down counter detector for the acquisition of GPS signals is modified to use dual-thresholds for each trial. Closed form expressions for the mean and variance of the dwell time and the probabilities of detection and false alarm are derived. The new detector has a significantly smaller mean dwell time than the conventional single-threshold up-down counter and a lower dwell time variance when signals are weak. Further, the new detector has a low computational load, when compared to the optimal sequential probability ratio test (SPRT), whose main disadvantage is its computational complexity. 相似文献
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Niamh Holland June Frisby Eleanor Owens Helen Hughes Patrick Duggan Peter McLoughlin 《Polymer》2010,51(7):1578-68
This is the first in-depth study examining the effect of morphology on the performance of 2-aminopyridine (2-apy) imprinted polymers. A series of polymers were prepared by varying the amount of crosslinking monomer (EGDMA) whilst the other polymer components remained constant. Physical characterisation was carried out using conventional techniques, such as nitrogen sorption porosimetry and solvent swelling studies. The use of a novel thermal desorption GC-MS technique suggested higher levels of polymer degradation with prolonged exposure to elevated temperatures for those polymers formed with lower amounts of EGDMA. The thermal desorption GC-MS profiles obtained correlated with the physical characteristics of the polymers, where higher levels of polymer bleed was found to occur with larger average pore diameters. Polymer physical characteristics were also found to correlate with the binding parameters (number of binding sites and polymer-template association energy) obtained from the Langmuir-Freundlich Isotherm (L-FI) and affinity distribution spectra (AD). The flexibility of the polymers formed from lower amounts of EGDMA combined the swelling effect of the solvents on the polymers resulted in an increase in affinity, which was both specific and non-specific in nature. 相似文献
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The attachment of mouse immunoglobulin G (IgG) and anti-mouse IgG antibodies onto carbon nanotubes (CNTs), using either non-covalent or covalent means was investigated. The resultant CNTs were characterised using a variety of techniques including enzyme-linked and fluorescence-linked immunoassays, UV-visible-NIR and Raman spectroscopy, transmission electron microscopy and cyclic voltammetry. TEM images of the adsorbed antibody on the CNTs show that the covalent modification approach was successful, whereas the non-covalent approach resulted in no electrochemically detectable labelled antibody. Direct electrical communication between CNTs covalently linked to peroxidase-labelled antibodies was observed during cyclic voltammetry, which suggests applications in developing carbon-nanotube-based immunosensors. 相似文献
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A casein hydrolysate protects mice against high fat diet induced hyperglycemia by attenuating NLRP3 inflammasome‐mediated inflammation and improving insulin signaling
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Niamh P. Healy Anna M. Kirwan Maeve A. McArdle Kieran Holohan Alice B. Nongonierma Deirdre Keane Stacey Kelly Lucia Celkova Claire L. Lyons Fiona C McGillicuddy Orla M Finucane Brian A. Murray Philip M. Kelly Lorraine Brennan Richard J. FitzGerald Helen M. Roche 《Molecular nutrition & food research》2016,60(11):2421-2432
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Buchanan HA Daéid NN Meier-Augenstein W Kemp HF Kerr WJ Middleditch M 《Analytical chemistry》2008,80(9):3350-3356
Drug profiling, or the ability to link batches of illicit drugs to a common source or synthetic route, has long been a goal of law enforcement agencies. Research in the past decade has explored drug profiling with isotope ratio mass spectrometry (IRMS). This type of research can be limited by the use of substances seized by police, of which the provenance is unknown. Fortunately, however, some studies in recent years have been carried out on drugs synthesized in-house and therefore of known history. In this study, 18 MDMA samples were synthesized in-house from aliquots of the same precursor by three common reductive amination routes and analyzed for 13C, 15N, and 2H isotope abundance using IRMS. For these three preparative methods, results indicate that 2H isotope abundance data is necessary for discrimination by synthetic route. Furthermore, hierarchical cluster analysis using 2H data on its own or combined with 13C and/or 15N provides a statistical means for accurate discrimination by synthetic route. 相似文献
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Niamh Willis‐Fox Etienne Rognin Christoph Baumann Talal A. Aljohani Robert Gstl Ronan Daly 《Advanced functional materials》2020,30(27)
Mechanical forces can drive chemical transformations in polymers, directing reactions along otherwise inaccessible pathways, providing exciting possibilities for developing smart, responsive materials. The state‐of‐the‐art test for solution‐based polymer mechanochemistry development is ultrasonication. However, this does not accurately model the forces that will be applied during device fabrication using processes such as 3D printing or spray coating. Here, a step is taken toward predictably translating mechanochemistry from molecular design to manufacturing by demonstrating a highly controlled nozzle flow setup in which the shear forces being delivered are precisely tuned. The results show that solvent viscosity, fluid strain rate, and the nature of the breaking bond can be individually studied. Importantly, it is shown that the influence of each is different to that suggested by ultrasonication (altered quantity of chain breakage and critical polymer chain length). Significant development is presented in the understanding of polymer bond breakage during manufacturing flows to help guide design of active components that trigger on demand. Using an anthracene‐based mechanophore, the triggering of a fluorescence turn‐on is demonstrated through careful selection of the flow parameters. This work opens the avenue for programmed chemical transformations during inline manufacturing processes leading to tunable, heterogeneous final products from a single source material. 相似文献