Thermochemistry, lattice energetics and stability of hexahalogenohafnates

The enthalpies of thermal dissociation (Δ_dH) and formation (Δ_fH) found in the literature as well as the crystal lattice energies (E_c) of inorganic and organic hexahalogenohafnates (M^I₂(or M^{II)HfX2−₆}; M^I and M^II denote monovalent and divalent cations respectively and X denotes a halogen) are reviewed and discussed. The enthalpies of formation of the salts were evaluated using the above-mentioned Δ_dH values and known enthalpies of formation of products of decomposition. Combination of the enthalpies of formation of hexahalogenohafnates thus obtained or those of the literature with the literature values of the enthalpy of formation of cations and theoretically determined enthalpies of formation of HfX²⁻₆ (or electrostatic lattice energies of the salts) afforded lattice energies of the salts (or enthalpies of formation of gaseous HfX²⁻₆). Values of Δ_fH were also assessed taking theoretically obtained electrostatic lattice energies of the salts and enthalpies of formation of HfX²⁻₆ and literature or theoretically determined values of the enthalpy of formation of gaseous cations. The independent sets of crystal lattice energies and thermochemical radii for HfX²⁻₆ were obtained following the Kapustinskii—Yatsimirskii approach. Combination of the latter method with the thermochemical cycle afforded information on the influence of the dimensions of ions on the thermodynamic stability of hexahalogenohafnates with respect to dissociation and oxidation processes. The thermochemical quantities of experimental and theoretical origin correlate with each other reasonably well, thus increasing their reliability.     

Effective simulation of signals for testing ECG analyzer

In this paper the solution of the specialized measuring system for electrocardiography (ECG) signal recording and introductory recognition is presented. The project aims at designing the complete PC-based Virtual Instrument as a "testing platform" for acquisition, processing, presenting, and distributing ECG data. A new design involving the latest technique in signal simulation was developed to create a controllable model of the electrocardiography signal. Then it was implemented for testing of the developed QRS detection algorithm, based on the time-frequency analysis method. The processing stage involving discrete wavelet transform was used to detect QRS complexes in the ECG signal. By using the controlled signal model and the real ones, the algorithm was shown to be advantageous in reducing ventilation artifacts and motion noise, resulting in good accuracy.     

Effects of Fe2O3 doping on structural and electrical properties of 8 mol% yttria-stabilized zirconia electrolyte for solid oxide fuel cells

Journal of Materials Science: Materials in Electronics - The effects of doping a trace of Fe2O3 on the structural and electrical properties of 8 mol% yttria-stabilized zirconia (8YSZ) are...     

Identification and extraction of brain tumor from MRI using local statistics of Zernike moments

In this article, a novel method is proposed for the detection of brain tumor in magnetic resonance images (MRIs). The features of Zernike moments are used to analyze the MRIs. The image is divided into two parts from the center of the image based on the average value of the pixel located at the center boundary, and new image vectors are formed to extract the tumor. The local statistics values obtained from the low and high order Zernike moments are used to calculate the appropriate threshold value for efficient tumor extraction. The proposed method successfully analyzes the tumor part of the image on testing with different MRIs.     

Downregulation of the pro-apoptotic protein Bak is required for the ras-induced transformation of intestinal epithelial cells

Anoikis is a form of programmed cell death induced in normal epithelial cells by detachment from the extracellular matrix [1] [2] [3]. In epithelial cells of the intestine and other organs, activated rasinduces resistance to anoikis [3] [4], but the actual molecular effectors directly involved in the apoptotic machinery that execute or block anoikis have not yet been identified. Bak, a pro-apoptotic member of the Bcl-2 family, is downregulated in a high proportion of colorectal tumours [5]. In addition, Bak is an important regulator of apoptosis in normal intestinal epithelial cells [6] [7]. Here, we show that activated rasinduces the downregulation of Bak in rat and human intestinal epithelial cells. This ras-induced downregulation of Bak expression could be suppressed by an inhibitor of phosphatidylinositol (PI) 3-kinase, an enzyme already implicated in ras-induced resistance to anoikis [8]. Ectopic expression of Bak in ras-transformed rat intestinal epithelial IEC-18 cells inhibited ras-induced resistance to anoikis and significantly reduced their tumorigenicity. We conclude, therefore, that the ability of rasto downregulate Bak, and the consequent resistance to anoikis, are essential components of the transforming capacity of this oncogene in intestinal epithelial cells.     

Laser Process Proximity Correction for Improvement of Critical Dimension Linearity on a Photomask

We report on the improvement of critical dimension (CD) linearity on a photomask by applying the concept of process proximity correction to a laser lithographic process used for the fabrication of photomasks. Rule‐based laser process proximity correction (LPC) was performed using an automated optical proximity correction tool and we obtained dramatic improvement of CD linearity on a photomask. A study on model‐based LPC was executed using a two‐Gaussian kernel function and we extracted model parameters for the laser lithographic process by fitting the model‐predicted CD linearity data with measured ones. Model‐predicted bias values of isolated space (I/S), arrayed contact (A/C) and isolated contact (I/C) were in good agreement with those obtained by the nonlinear curve‐fitting method used for the rule‐based LPC.     

Sex-role stereotyping in television commercials: A verbal response mode and content analysis.

Evaluated the degree of sex-role stereotyping in TV commercials using both a verbal response mode and a content analysis. A total of 120 commercials (60 daytime and 60 primetime), each depicting an adult male–female dyad verbally interacting, were drawn from a larger sample of commercials aired between October 1983 and January 1984 on the major North American networks. Results of the 2 analyses reveal a more sex-stereotyped pattern of male–female differences in daytime than in primetime commercials. It is concluded that sex-role stereotyping still exists in TV commercials and is present at subtle as well as obvious levels of analysis. (French abstract) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Influence of flow field on sedimentation efficiency in a circular settling tank with peripheral inflow and central effluent

The paper presents an experimental study of suspension flow patterns and velocity field inside a circular settling tank with continuous operation. Research was focused on the impact of a specific flow pattern on the sedimentation efficiency of the prototype settling tank. The latter differed from a common circular settling tank in that it was peripherally fed and had the central draw-off. Experiment was carried out on a settling tank section made of plexiglass and represented a radial slice of a prototype settling tank. The flow field and local suspension concentration was determined by computer-aided visualization. Sedimentation efficiency was assessed relatively by comparison of the amount of settled particles (sludge height measurements) between different types of flow in a certain time period of the settling tank operation. Results showed that there were two types of flow in the settling tank that were initiated by a horizontal or vertical inflow from the distribution ring. The type of inflow (horizontal or vertical) was a function of the suspension height in the settling tank. Significant differences in sedimentation efficiency were observed between both types of flow, particularly at lower inlet suspension concentrations. Horizontal inflow proved to be less efficient in terms of settling.