CO2激光直接钻孔工艺的前后处理

近几年,电子产品朝轻,薄,短,小化迅速发展,印制线路板也随着这股潮流朝向高密度封装方向发展。尤其是积层板总数的增加和导通孔以及连接盘的小径化也日益显著。对于积层线路板而言,用来加工层间连接的盲通孔(BVH)的激光方法取决于导通孔和连接盘径。激光器分为CO2激光和UV-Yag激光两种。导通孔径为60μm以上时,则一般用CO2激光加工。由于铜在CO2激光的波长(9.3μm～10.3μm)领域中的吸收比很低,因此"保形法"(在表面铜箔上,蚀刻出需要的加工孔径(开铜窗),再以激光打掉树脂)成为了现在的主流。然而,由于保形法需要蚀刻开铜窗,因此增加了形成图形的工序,而且导通孔的定位取决于下层的定位标记,容易发生错位。随着积层板层数的增加,导通孔和连接盘的小径化发展,越来越需要提高加工速度和定位精度。因此,同时对铜和树脂进行加工的"直接钻孔法"开始被关注。直接钻孔法是根据格柏数据进行导通孔的定位,因此,即使导通孔/连接盘径越趋小型化,也不会发生错位,是一种能够推进多层化,高密度化的先端技术。本文讲述了以直接钻孔法形成高可靠度导通孔时所需的技术和药品。     

Supramolecular Ligands for Histone Tails by Employing a Multivalent Display of Trisulfonated Calix[4]arenes

Post‐translational modification of histone tails plays critical roles in gene regulation. Thus, molecules recognizing histone tails and controlling their epigenetic modification are desirable as biochemical tools to elucidate regulatory mechanisms. There are, however, only a few synthetic ligands that bind to histone tails with substantial affinity. We report CA2 and CA3, which exhibited sub‐micromolar affinity to histone tails (especially tails with a trimethylated lysine). Multivalent display of trisulfonated calix[4]arene was important for strong binding. CA2 was applicable not only to synthetic tail peptides but also to endogenous histone proteins, and was successfully used to pull‐down endogenous histones from nuclear extract. These findings indicate the utility of these supramolecular ligands as biochemical tools for studying chromatin regulator protein and as a targeting motif in ligand‐directed catalysis to control epigenetic modifications.     

Thermal strain of high strength polyethylene fiber in low temperature

High strength polyethylene fiber (Toyobo, Dyneema® fiber: hereinafter abbreviated to DF) has a negative thermal expansion coefficient. Relation between fiber structure and thermal strain of DF used as reinforcement of DF reinforced plastic (DFRP) for cryogenic use was investigated. The crystallinities and orientation angles of several kinds of polyethylene fibers having different modulus from 15 to 134Gpa (herein after abbreviated to DFs) were measured by NMR and X‐ray. We obtained the parameters of the mechanical series‐parallel model composed of crystal and amorphous by crystallinity and modulus. Thermal expansion coefficients of DFs were estimated by mechanical series‐parallel model. All DFs having different modulus showed negative thermal expansion coefficients in the temperature range from 180 to 300K, and absolute values of those markedly increased by increasing tensile modulus of DF. The estimated thermal expansion coefficients showed negative values, and thermal strains showed a similar curve to observed ones mostly. Average thermal expansion coefficients in the temperature range from 180 to 300K estimated by mechanical model agreed with the observed ones. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2918–2925, 2004     

Radical-induced degradation mechanism of perfluorinated polymer electrolyte membrane

The degradation mechanism induced by radicals was investigated for Nafion^®-117 by solution analysis. Nafion^® was exposed independently to three kinds of radicals, OH, H and O₂⁻ which were produced separately by γ-irradiation. Based on the eluted elements, the scission site in the membrane was analyzed. The results showed that the scission site was classified into two and these locations were closely relating to oxidative and reductive reactions. The decreasing rate of proton conductivity was more significant under the influence of reductive radicals. The progression of the unzipping reaction of main chain was suggested to be initiated by the production of tertiary carbon radical by reductive radicals such as H and O₂⁻ with the aid of OH. The structural degradation such as collapse of cluster and the cluster decomposition as well as the performance degradation was found to be initiated by such reductive radicals.     

Converging measurement of horizontal and vertical individualism and collectivism.

The constructs of horizontal (H) and vertical (V) individualism (I) and collectivism (C) were theoretically defined and empirically supported. Study 1 confirmed, via factor analysis, that the 4 constructs, HI, V1, HC, and VC, which were previously found in the United States, which has an individualist culture, also were found in Korea which has a collectivist culture. Study 2 investigated multimethod-multitrait matrices measuring the constructs and generally supported their convergent and divergent validity. Study 3 showed how these 4 constructs relate to previously identified components by H. C. Triandis and colleagues. Study 4 showed the relationships of the measurement of the 4 constructs to some of the measures used by other researchers. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

A restatement and test of Schlosberg's theory of emotion with two kinds of subjects from Greece.

Schlosberg's dimensional theory of emotion, including the dimension of tension-sleep, is tested to compare results obtained previously with American college students with those obtained in this study using Greek Ss. 15 Greek villagers and 15 college students in Athens comprised the 2 experimental groups which differed from each other in educational level and in lifetime movie attendance. The data indicate that Schlosberg's conclusions are now valid for non-Western groups as well as Western. Furthermore an emotion solid can be plotted from data collected by making use of Schlosberg's procedure, but the shape of the solid is not the same as that previously presented by Schlosberg. 18 references. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Cultural variation in the use of current life satisfaction to predict the future.

Three studies examined cultural and situational influences on the tendency for people to use their current life satisfaction to predict future life events. On the basis of the self-enhancement literature, it was predicted that either writing about a positive personal experience or reading about another's negative experience would lead European Americans to focus their attention on internal attributes and thus would lead them to use their current life satisfaction in predicting the future. Conversely, on the basis of the self-criticism literature, it was predicted that these same conditions would lead Asian Americans to focus their attention on external factors and, therefore, would decrease their likelihood of using their current life satisfaction to predict the future. Studies 1 and 2 supported these hypotheses. Study 3 showed that these patterns could be obtained by subliminally priming concepts associated with individualism and collectivism. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Residential mobility, self-concept, and positive affect in social interactions.

The present research examined (a) the link between personal history of residential mobility and the self-concept and (b) the implications of such a link for positive affect in social interactions. Study 1 showed that the personal self was more central to the self-definition of frequent movers than to that of nonmovers, whereas the collective self was more central to the self-definition of nonmovers than to that of frequent movers. Results from a laboratory and a 2-week event sampling study (Studies 2 and 3) demonstrated that frequent movers felt happier when an interaction partner accurately perceived their personal selves, whereas nonmovers felt happier when a partner accurately perceived their collective selves. These findings present the first direct evidence on how personal history of residential mobility is linked to important individual differences in the self and positive affect in social interactions. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The dynamics of daily events and well-being across cultures: When less is more.

The authors examined cultural and individual differences in the relation between daily events and daily satisfaction. In a preliminary study, they established cross-cultural equivalence of 50 daily events. In the main study, participants in the United States, Korea, and Japan completed daily surveys on the 50 events and daily satisfaction for 21 days. The multilevel random coefficient model analyses showed that (a) the within-person association between positive events and daily satisfaction was significantly stronger among Asian American, Korean, and Japanese participants than among European American participants and (b) the within-person association between positive events and daily satisfaction was significantly weaker among individuals high in global life satisfaction than among those low in global life satisfaction. The findings demonstrate a weaker effect of positive events on daily well-being among individuals and cultures high in global well-being. (PsycINFO Database Record (c) 2010 APA, all rights reserved)