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1.
Real‐time monitoring by proton relaxometry of radical polymerization reactions of acrylamide in aqueous solution 下载免费PDF全文
Elton Jorge da Rocha Rodrigues Roberto Pinto Cucinelli Neto Pedro José Oliveira Sebastião Maria Inês Bruno Tavares 《Polymer International》2018,67(6):675-683
The potential of time‐domain nuclear magnetic resonance (TD‐NMR) for the real‐time monitoring of solution radical polymerizations is demonstrated. A model system composed of a redox‐pair initiator system, acrylamide as monomer and water as solvent was investigated. A second‐generation continuous wave free precession technique was employed to measure the longitudinal relaxation time constant (T1) of the samples throughout the polymerization reactions. This parameter was shown to be sensitive to the reactant feed free‐radical enhancement of the water molecule relaxation time, making it a good probe to monitor monomer conversion in real time in an automated, non‐destructive fashion. It was found that the T1 value was better than the transverse relaxation time constant (T2) for describing the evolution of the polymerization reactions, due to its greater sensitivity to paramagnetic effects. The TD‐NMR signal variation observed was linked to the formation, propagation and termination steps of the radical polymerization kinetics scheme. These first results may contribute to the application of real‐time monitoring of radical polymerization reactions employing low‐cost and robust TD‐NMR spectrometers. © 2018 Society of Chemical Industry 相似文献
2.
Caio Felippe Curitiba Marcellos Camila M. Senna Figueiredo Frederico W. Tavares Maurício Bezerra de Souza Jr. Paulo Laranjeira da Cunha Lage João Francisco Cajaiba da Silva Argimiro R. Secchi Amaro G. Barreto Jr. 《加拿大化工杂志》2020,98(11):2435-2450
An experimental methodology for inferring brine dissolution rate in monoethylene glycol (MEG) solutions at different temperatures using a webcam combined with a mathematical model is presented. The measurement system is designed to track the RGB (red, green, and blue) colour variations during the dissolution process. A dynamic model augmented with the population balance equation is applied to describe the dissolution process. Moreover, the dissolution rate is consistently related to the temperature and MEG concentration through the driving force based on the Gibbs energy and chemical affinity. The applied low-cost measurement apparatus proved to be a useful resource for tracking the dissolution dynamics in a wide range of undersaturation. 相似文献
3.
Cyclo 3 Fort is used in the treatment of chronic venous insufficiency. In this study, the effects of Cyclo 3 Fort, 2, 10 and 50 mg/kg, were studied in cheek pouch preparations from diabetic hamsters. The mean arteriolar diameter in animals receiving Cyclo 3 Fort, 10 and 50 mg/kg, was significantly greater than in control animals (p < 0.05), and the mean venule diameter was significantly lower in animals receiving the 50 mg/kg dose than in the control group. This suggests that Cyclo 3 Fort, 50 mg/kg/day, has a venotonic effect in diabetic animals. The venoarteriolar reflex was studied by measuring the internal diameter of arterioles during venular occlusion. The reflex was impaired in animals treated with either placebo or 2 mg/kg, but this was reversed by treatment with Cyclo 3 Fort, 10 and 50 mg/kg. 相似文献
4.
Alexandre Szklo Giovani Machado Roberto Schaeffer Jacqueline Mariano Janaí na Sala Marina Tavares 《Catalysis Today》2005,106(1-4):123-128
This paper assesses the impacts of a GTL plant on the expansion of Brazil's oil refining segment. The GTL plant (50,000 bpd) was sized to start up operations in 2015, producing diesel and naphtha through the indirect route (FT-synthesis). This plant will consume the non-associated natural gas production from the recent discoveries at the Santos Basin (around 419 Bm3), and the associated gas production from the Campos Basin. Both basins are located in the Southeast of Brazil, the most populated, rich and industrialized region of the country. Two different criteria for refinery expansion were simulated in order to meet oil product demand scenarios. Findings show that depending on the refinery expansion criteria considered GTL will play a fundamental hole to meet the oil product demand forecast to Brazil in the next 10 years. 相似文献
5.
A new CMOS VLSI implementation of an asymmetric programmable sigmoid neural activation function, as well as of its derivative, is presented. It consists of two coupled PMOS and NMOS differential pairs with different programmable bias currents that set the upper and lower limits of the sigmoid. The circuit works in the weak inversion region, for low power consumption and exponential envelope, or in strong inversion to achieve higher speeds. The results obtained from the theoretical transfer function, and from the simulations of the circuit implemented in AMI's 0.35 /spl mu/m technology, show a very good match. 相似文献
6.
Ana MRB Xavier Ana Paula M Tavares Margarida SM Agapito Dmitry V Evtuguin 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(12):1602-1608
BACKGROUND: A sequential batch reactor (SBR) was used for eucalypt kraft pulp effluent treatment with Trametes versicolor. A 23 full factorial design and response surface methodology were applied to optimise the batch fermentation conditions. Effluent concentration, culture medium and inoculum age were the factors selected for this study in order to optimise the reduction of chemical oxygen demand (COD). RESULTS: The presence of Trametes Defined Medium (TDM) in the fermentation was required to obtain a significant COD reduction. Experiments in the batch reactor confirmed, in general, the predicted results of optimisation developed from Erlenmeyer batch assays. The T. versicolor culture remained active during 42 days of study in the SBR, providing approximately 80% of COD reduction. CONCLUSION: Trametes versicolor may be considered as very promising for the biological treatment of effluents from kraft pulp mills in an SBR system instead of the activated sludge mixed cultures traditionally used. Copyright © 2008 Society of Chemical Industry 相似文献
7.
The Simulation of Impact Loads on Beam-type Structures using a Pseudo-dynamic Procedure 总被引:5,自引:0,他引:5
F. J. Q. Melo J. A. O. Carneiro P. P. Camanho C. L. Tavares A. A. Fernandes 《Strain》2004,40(1):13-23
Abstract: This study proposes an alternate method for the analysis of beams with solid cross-section or built as a framed structure and subjected to transverse impact loads from an external striker. The procedure used in the analysis is a combination of two essential tools using pseudo-dynamic techniques. The method reported here involves only one degree of freedom for the structure modelling and assumes an elastic contact between an external striker and the beam structure, which in reality does not happen. As only one degree of freedom is considered in the analysis, some important limitations are inherent to the method proposed here. Essentially, there is the difficulty of modelling the displacement field associated with the transient structure behaviour accurately, as a consequence of fast-rate impact loads. Another difficulty faced by the method refers to a local structure behaviour associated with contact loads. The present method can deal with large displacements in transversely loaded beams associated to a collapse mechanism having a simple geometry and defined with precision from a single parameter. This ensures reasonable accuracy in the evaluation of the strain energy absorbing capacity of transversely impacted beam structures using a single degree of freedom model in a pseudo-dynamic procedure. 相似文献
8.
The present paper uses a classical Galerkin weighted residual formulation to obtain the approximate analytical solution of a thermally loaded beam executing free flexural vibrations. The approach used is one where the time variable is considered in the same manner as the spatial variable, and is included in the basis functions. The basis functions used in the approach are polynomials obtained from the terms of a power series, with the condition of nullity on the boundary. This choice simplifies the algebraic manipulations considerably and yields close form expressions for components of the system matrix. The latter also simplifies the numerical computation of coefficients of the approximating polynomial. The approach provides benefits in terms of increased accuracy and lower computational costs. 相似文献
9.
Influence of pencil lead hardness on voltammetric response of graphite reinforcement carbon electrodes 总被引:1,自引:0,他引:1
Paulo Henrique Campos Prado Tavares Paulo Jorge Sanches Barbeira 《Journal of Applied Electrochemistry》2008,38(6):827-832
This work studied the voltammetric response of graphite reinforcement electrodes made of different pencil lead hardness. The
studies showed that harder graphite leads, regardless of their manufacturer, are more appropriate as electrode material for
voltammetric purposes due to their higher peak currents, increasing sensitivity and reproducibility, with ΔEp closer to the theoretical value for a reversible system. 相似文献
10.
Collagenous material was obtained from chicken feet skins and tendons, defatted with ethylic ether and treated with 0.05 M and 0.6 M NaCl solutions. Part of the material was dried at 35 degrees C in a forced air convection oven and another was freeze-dried. The air dried material had 77.2 g/100 g of collagen and the freeze-dried material 76.7 g/100 g. Both dehydrated materials showed the same behaviour for gel formation and cold water holding capacity. The material air dried had higher emulsifying capacity than the freeze-dried one. The collagen of freeze-dried material had higher solubility in 0.5 M acetic acid and water at 70 degrees C than air dried material. Gel strength, emulsion stability and water holding capacity at 60 degrees C were higher for freeze-dried material. The results indicate the potential use of these materials as functional ingredients in meat products. 相似文献