Preparation of a functional nanofibrous polymer membrane incorporated with poly(2-aminothio phenol) stabilized gold nanoparticles

Functional nanofibrous polymer membranes were prepared by incorporating poly(2-aminothio phenol) (P2AT) stabilized Au NPs onto electrospun polyvinylidene fluoride (PVdF) nanofibers (designated as P2AT-Au NPs@PVdF-NFM). The preparation of P2AT-Au NPs@PVdF-NFM involves two steps: loading of 2AT (monomer) into electrospun PVdF nanofibrous membrane and polymerization of 2AT by gold chloride. P2AT and Au NPs were simultaneously formed into the electrospun PVdF-NFM. Transmission electron microscope image of P2AT-Au NPs@PVdF-NFM informs the presence of Au NPs (with sizes ~10 nm) onto PVdF-NFM.     

Hydrothermal synthesis of one-dimensional tungsten oxide nanostructures using cobalt ammonium sulfate as a structure-directing agent

Hydrothermal synthesis of one-dimensional tungsten oxide nanostructures was performed using cobalt ammonium sulfate as a structure-directing agent, and the effect of the concentration of cobalt ammonium sulfate on the characteristics of the tungsten oxide nanostructures was investigated. XRD measurements showed that hexagonal tungsten oxide (h-WO₃) structures were obtained at a higher concentration of cobalt ammonium sulfate (0.2 M), while cubic tungsten oxide (c-WO₃) structures were obtained at a lower concentration of cobalt ammonium sulfate (0.01M). Mixed structures of h-WO₃ and c-WO₃ were observed at an intermediate concentration of cobalt ammonium sulfate. Morphological studies revealed that h-WO3 appeared as nanowires with a diameter of about 40 nm and an average length of 1 μm. c-WO₃ was shaped in pillar-like nanorods with a diameter of about 30 nm. A red-shift in the UV/Vis absorption peak was observed with different phases of tungsten oxide nanostructures.     

Effect of Y2O3 on Spark Plasma Sintering Kinetics of Nanocrystalline 9Cr-1Mo Ferritic Oxide Dispersion-Strengthened Steels

Nanocrystalline mechanically alloyed powders of 9Cr-1Mo ferritic steels with and without yttria dispersoids were densified using spark plasma sintering (SPS) to near-theoretical density at a temperature of 1073 K (800 °C). Studies on densification behaviour revealed that steels with dispersoids densified faster when compared to Fe-9Cr-1Mo steel. The evaluation of densification mechanisms during SPS reveals that grain boundary and lattice diffusion to be predominant at relative densities ranging from >0.7 to 0.9 in both the alloys.     

Microstructure and Mechanical Properties of Nanostructured Al-4Cu Alloy Produced by Mechanical Alloying and Vacuum Hot Pressing

Bulk nanostructured Al-4 wt pct Cu alloy with high compression strength (879 MPa) was produced by mechanical alloying followed by vacuum hot pressing (VHP). The hot-pressed compacts were nanostructured with a grain size of 50 nm and were densified to more than 99 pct of the theoretical density. Contributions from different strengthening mechanisms were estimated using simplified models and were compared with the experiment.     

Studies on some trace and minor elements in blood. A survey of the Kalpakkam (India) population. Part I: Standardization of analytical methods using ICP-MS and AAS

Blood is one of the widely used specimens for biological trace element research because of its biological significance and ease of sampling. We have conducted a study of the blood of the Kalpakkam township population for trace and minor elements. For this purpose, analytical methods have been developed and standardized in our laboratory for the elemental analysis of blood plasma and red cells. Inductively coupled plasma-mass spectrometry (ICP-MS), a relatively new technique, has been applied for the analysis of trace elements. Details regarding spectral interference and matrix interference encountered in the analysis of blood and the methods of correcting them have been discussed. Flame atomic absorption spectrometry (AAS)/atomic emission spectrometry (AES) has been applied for the determination of minor elements. Precision and accuracy of these methods have also been discussed.     

The salubrious effects of ascorbic acid on cyclophosphamide instigated lipid abnormalities in fibrosarcoma bearing rats

A new class of silica gel-bound fluorene phases is described. The compounds are synthesized via reaction of fluorenyl lithium with omega-alkenyl bromides leading to 9-(5'-hexenyl)-9H- and 9-(9'-decenyl)-9H-fluorene (1 and 2), followed by hydrosilation reactions with different hydrosilanes. The resulting omega-functionalized silylalkyl fluorenes 3a(T0), 3b(T0), 4a(T0), 4b(T0) and 4c(M0) (Scheme 1) react with surface silanol groups of silica gel to generate the new fluorene phases 3a(Tn)(Qm)y, 3b(Tn)(Qm)y, 4a(Tn)(Qm)y, 4b(Tn)(Qm)y and 4c(M1)(Qm)y. The phases are characterized by employing 1H, 13C and 29Si solid-state nuclear magnetic resonance spectroscopy. Their applicability in high-performance liquid chromatography is proved by the Sander and Wise test (SRM 869). In contrast to conventional n-alkyl phases, pi-pi interactions are additionally involved in the separation process and, therefore, the retention times of the polycyclic aromatic hydrocarbons sample molecules depend on the ligand densities of the applied fluorene phases.     

Diversity among various forms of catechins and its synthesizing enzyme (phenylalanine ammonia lyase) in relation to quality of black tea (Camellia spp.)

BACKGROUND: Quality of tea depends on the cultivar and climatic conditions. Biochemical pathways within the plant and climatic factors can result in noticeable changes in chemical composition, which determine the quality of tea. Black tea quality attributes are influenced by various forms of catechins, namely gallated, non‐gallated, dihydroxylated and trihydroxylated catechins and their ratios. Hence the variations in grouped catechins and their synthesizing enzyme in relation to quality of south Indian black tea grown in different seasons and different cultivars were studied. RESULTS: Gallated, non‐gallated, dihydroxylated, trihydroxylated catechins and catechin index were significantly higher in crop shoots harvested during summer. A significant and wide diversity in various forms of catechins was noticed among the cultivars tested. Among the cultivars, UPASI‐3 registered the higher amount of various forms of catechins and activity of phenylalanine ammonia lyase (PAL), followed by UPASI‐9 and UPASI‐17 respectively, while the lowest amount was exhibited by ‘Assam’ seedlings and TRI‐2043. CONCLUSION: Overall quality as evaluated by tea tasters was positively correlated to the cultivars and seasons tested. This positive correlation can be attributed to higher levels of grouped catechins and PAL activity. Thus the contents of various forms of catechins could be the most important quality parameter of the south Indian black teas. Copyright © 2010 Society of Chemical Industry     

Prediction of cutting force based on machining parameters on AL7075-T6 aluminum alloy by response surface methodology in end milling

Cutting forces modeling is the basic to understand the cutting process, which should be kept in minimum to reduce tool deflection, vibration, tool wear and optimize the process parameters in order to obtain a high quality product within minimum machining time. In this paper a statistical model has been developed to predict cutting force in terms of geometrical parameters such as rake angle, nose radius of cutting tool and machining parameters such as cutting speed, cutting feed and axial depth of cut. Response surface methodology experimental design was employed for conducting experiments. The work piece material is Aluminum (Al 7075-T6) and the tool used is high speed steel end mill cutter with different tool geometry. The cutting forces are measured using three axis milling tool dynamometer. The second order mathematical model in terms of machining parameters is developed for predicting cutting forces. The adequacy of the model is checked by employing ANOVA. The direct effect of the process parameter with cutting forces are analyzed, which helps to select process parameter in order to keep cutting forces minimum, which ensures the stability of end milling process. The study observed that feed rate has the highest statistical and physical influence on cutting force.     

Optimization of machining parameters using genetic algorithm and experimental validation for end-milling operations

Optimization of cutting parameters is valuable in terms of providing high precision and efficient machining. Optimization of machining parameters for milling is an important step to minimize the machining time and cutting force, increase productivity and tool life and obtain better surface finish. In this work a mathematical model has been developed based on both the material behavior and the machine dynamics to determine cutting force for milling operations. The system used for optimization is based on powerful artificial intelligence called genetic algorithms (GA). The machining time is considered as the objective function and constraints are tool life, limits of feed rate, depth of cut, cutting speed, surface roughness, cutting force and amplitude of vibrations while maintaining a constant material removal rate. The result of the work shows how a complex optimization problem is handled by a genetic algorithm and converges very quickly. Experimental end milling tests have been performed on mild steel to measure surface roughness, cutting force using milling tool dynamometer and vibration using a FFT (fast Fourier transform) analyzer for the optimized cutting parameters in a Universal milling machine using an HSS cutter. From the estimated surface roughness value of 0.71 μm, the optimal cutting parameters that have given a maximum material removal rate of 6.0×10³ mm³/min with less amplitude of vibration at the work piece support 1.66 μm maximum displacement. The good agreement between the GA cutting forces and measured cutting forces clearly demonstrates the accuracy and effectiveness of the model presented and program developed. The obtained results indicate that the optimized parameters are capable of machining the work piece more efficiently with better surface finish.