Clarification of a wheat straw‐derived medium with ion‐exchange resins for xylitol crystallization

BACKGROUND: Xylitol bioproduction from lignocellulosic residues comprises hydrolysis of the hemicellulose, detoxification of the hydrolysate, bioconversion of the xylose, and recovery of xylitol from the fermented hydrolysate. There are relatively few reports on xylitol recovery from fermented media. In the present study, ion‐exchange resins were used to clarify a fermented wheat straw hemicellulosic hydrolysate, which was then vacuum‐concentrated and submitted to cooling in the presence of ethanol for xylitol crystallization. RESULTS: Sequential adsorption into two anion‐exchange resins (A‐860S and A‐500PS) promoted considerable reductions in the content of soluble by‐products (up to 97.5%) and in medium coloration (99.5%). Vacuum concentration led to a dark‐colored viscous solution that inhibited xylitol crystallization. This inhibition could be overcome by mixing the concentrated medium with a commercial xylitol solution. Such a strategy led to xylitol crystals with up to 95.9% purity. The crystallization yield (43.5%) was close to that observed when using commercial xylitol solution (51.4%). CONCLUSION: The experimental data demonstrate the feasibility of using ion‐exchange resins followed by cooling in the presence of ethanol as a strategy to promote the fast recovery and purification of xylitol from hemicellulose‐derived fermentation media. Copyright © 2008 Society of Chemical Industry     

,,Rich Internet Applications“ – Eine perfekte Kombination benutzerfreundlicher Schnittstellen mit Webtechnologie

Zusammenfassung  ,,Rich Internet Applications“ (RIA) sind Webapplikationen, die mit einer wesentlich interaktiveren Benutzerschnittstelle ausgestattet sind, als wir das bisher von den auf HTML basierten ,,poor ugly web applications“ (PUWA) gewohnt waren.     

Moderators of nonverbal indicators of deception: A meta-analytic synthesis.

In many legal proceedings, fact finders scrutinize the demeanor of a defendant or witness, particularly his or her nonverbal behavior, for indicators of deception. This meta-analysis investigated directly observable nonverbal correlates of deception as a function of different moderator variables. Although lay people and professionals alike assume that many nonverbal behaviors are displayed more frequently while lying, of 11 different behaviors observable in the head and body area, only 3 were reliably associated with deception. Nodding, foot and leg movements, and hand movements were negatively related to deception in the overall analyses weighted by sample size. Most people assume that nonverbal behaviors increase while lying; however, these behaviors decreased, whereas others showed no change. There was no evidence that people avoid eye contact while lying, although around the world, gaze aversion is deemed the most important signal of deception. Most effect sizes were found to be heterogeneous. Analyses of moderator variables revealed that many of the observed relationships varied as a function of content, motivation, preparation, sanctioning of the lie, experimental design, and operationalization. Existing theories cannot readily account for the heterogeneity in findings. Thus, practitioners are cautioned against using these indicators in assessing the truthfulness of oral reports. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Wave propagation by the passage of two high-speed trains in a tunnel

A numerical simulation of unsteady compressible flow induced by two high-speed trains in oncoming traffic within a tunnel is presented. The computations were carried out by means of a second-order accurate Harten-Yee type upwind TVD scheme. In order to take the effect of friction into account, a source term is included in the governing flow equations. In the computation, moving boundary configurations were used to simulate the two trains passing through the tunnel. As geometrical configuration, the Einmalberg tunnel, where experimental data are available, was selected. The computational results agree reasonably well with their experimental counter-part. The waves interaction and the waves propagation process at the tunnel entrance and exit as well as within the tunnel are addressed. Finally, the influence on the transmitted waves at the tunnel exit portal and the variation of the negative pressure drop during the passage of the two trains are discussed.     

Systemised serendipity for producing computer art

Serendipity applied to Newton's method, and its derivative the Secant Method, produces unusual and beautiful fractal patterns. Serendipity may be systemised, for example, by the introduction of a perturbation parameter P1, [1] to facilitate searches for interesting pattern variations.     

Object-extending class transformations

Reorganisation and evolution of class hierarchies is important for object-oriented system development and has received considerable attention in the literature. The contributions of this paper are: (1) a formal study of a set of extension relations and transformations on class hierarchies; (2) a presentation of a small set of primitive transformations which form a minimal and complete basis for the extension relations; and (3) an analysis of the impact of these transformations at the object level.The study leads to a better understanding of evolution and reuse of object-oriented software and class hierarchies. It also provides a terminology and a means of classification for design reuse. The theory presented in this paper is based on the Demeter data model, which gives a concise mathematical foundation for classes and their inheritance and part-of relationships. Parts of the theory have been implemented in the Demeter System ^TM C++, a CASE tool for object-oriented design and programming.