Facile construction of composition-tuned ruthenium-nickel nanoparticles on g-C3N4 for enhanced hydrolysis of ammonia borane without base additives

Developing high-efficiency and low-cost catalysts for hydrogen evolution from hydrolysis of ammonia borane (AB) is significant and critical for the exploitation and utilization of hydrogen energy. Herein, the in-situ fabrication of well-dispersed and small bimetallic RuNi alloy nanoparticles (NPs) with tuned compositions and concomitant hydrolysis of AB are successfully achieved by using graphitic carbon nitride (g-C₃N₄) as a NP support without additional stabilizing ligands. The optimized Ru₁Ni_7.5/g-C₃N₄ catalyst exhibits an excellent catalytic activity with a high turnover frequency of 901 min^?1 and an activation energy of 28.46 kJ mol^?1 without any base additives, overtaking the activities of many previously reported catalysts for AB hydrolysis. The kinetic studies indicate that the AB hydrolysis over Ru₁Ni_7.5/g-C₃N₄ is first-order and zero-order reactions with respect to the catalyst and AB concentrations, respectively. Ru₁Ni_7.5/g-C₃N₄ has a good recyclability with 46% of the initial catalytic activity retained even after five runs. The high performance of Ru₁Ni_7.5/g-C₃N₄ should be assigned to the small-sized alloy NPs with abundant accessible active sites and the synergistic effect between the composition-tuned Ru–Ni bimetals. This work highlights a potentially powerful and simple strategy for preparing highly active bimetallic alloy catalysts for AB hydrolysis to generate hydrogen.     

测井新技术在四川油气勘探开发中的应用

综述随着四川盆地油气勘探深入所面临的油气领域复杂和困难的技术问题，介绍应用测井新技术为四川油气开发解决了大量的技术难题，特别是在复杂缝，洞型储层的评价，井旁地质构造形态精细分析和地质，测井，地震多学科结合储层横向预测等3个方面所取得的良好应用效果。     

Research issues in genomic signal processing

Genomic signal processing (GSP) concerns the processing of genomic signals. It may be defined as the analysis, processing, and use of genomic signals to gain biological knowledge and the translation of that knowledge into systems-based applications. In this article, the authors discuss the key research issues for GSP. It is important to recognize that "genomic signal processing" is not a name for genomic bioinformatics nor for the application of signal processing methods in genomics. We note that the research issues pertaining to GSP fit within the overall challenges confronting research in the area of multimodal biomedical systems.     

Channel-carrier mobility parameters for 4H SiC MOSFETs

In this paper, mobility parameters for enhancement-mode N-channel 4H SiC MOSFETs are extracted and implemented into 2-D device simulation program and SPICE circuit simulator. The experimental data were obtained from lateral N-channel 4H SiC MOSFETs with nitrided oxide–semiconductor interfaces, exhibiting normal mobility behavior. The presence of increasing interface-trap density (D_it) toward the edge of the conduction band is included during the 2-D device simulation. Using measured distribution of interface-trap density for simulation of the transfer characteristics leads to a good agreement with the experimental transfer characteristic.     

空气井测井响应现象分析与探讨

空气钻井作为一种新的钻井技术已在四川油田川东地区的zbl井首次投入使用。2003年2月1日，四川测井公司数控分公司对该井进行了测井施工作业，采集了合格的井径、自然伽马、补偿声波、补偿中子、补偿密度和深浅双侧向资料。针对空气井测井中出现的现象进行了分析与探讨，旨在为今后空气井测井系列的选择与解释奠定基础。     

激光焊接对接拼缝测量的微景深方法

对于复杂微细、错边量小的激光焊接拼缝测量,现有的视觉传感器方法不能稳定、可靠地提取出拼缝的中心位置、拼缝宽度等信息。为此,提出了基于微景深的激光焊接对接拼缝测量方法,该方法采用高倍光学放大镜头、工业CCD(Charge Coupled Device)/CMOS(Complementary Metal-Oxide-Semiconductor Transistor)相机和LED(Light-Emitting Diode)外部照明装置,以光学成像光轴与被测表面法矢呈45°的方式,组成的对接拼缝的非接触测量系统,既解决了显微放大时景深很小、测量范围小的问题,又解决了狭窄拼缝高光学放大倍数拼缝检测的难题。实验结果表明,该系统可快速准确地提取出拼缝中心坐标、拼缝宽度以及拼缝局部表面法矢。拼缝宽度测量精度优于5 μm,拼缝中心测量精度优于6 μm,可识别的最小拼缝宽度为0.02 mm,完全满足激光焊接对接狭窄拼缝的检测与自动跟踪的要求。     

一种基于CGAN-CNN的同步电机转子绕组匝间短路故障诊断方法

由于同步电机故障样本数量较少,为解决同步电机故障诊断中普遍存在的样本不平衡问题,提出了一种基于条件生成式对抗网络(CGAN)和卷积神经网络(CNN)的同步电机转子绕组匝间短路故障诊断方法.首先,对传感器收集到的数据进行预处理,对正常样本和故障样本分别添加标签后输入CGAN中生成大量新样本,将生成的新样本与原始样本混合并划分训练集和测试集;然后,利用CNN训练平衡后的数据集,充分、精准地提取有效故障特征;最后,在输出端利用Softmax分类器输出故障分类结果.通过实验证明,与非平衡数据集相比,利用平衡数据集后的故障识别准确率十分稳定且达到99.5％以上,同时与平衡的原始样本数据相比,生成样本避免了噪声和其他干扰,故障诊断的准确率也更高.