Multifunctional photonic switching operation of 1500 nm Y-coupledcavity laser (YCCL) with 28 nm tuning capability

The authors present new results on extended electrical tuning, fast spatial switching, and optically controlled wavelength conversion characteristics for the recently developed InP-based Y-laser structure. The devices have a 80 nm thick bulk InGaAsP active layer and are completely grown by metalorganic vapor phase epitaxy. The facets at both ends of the chip are as-cleaved without antireflective coating. The addressable range for electrically controlled wavelength switching was extended to the record value of 28 nm. When operated as a lossless 1:2 optical space switch, fiber-to-fiber gain >0 dB, extinction ratio >50 dB and high speed operation up to 1 Gb/s were shown. Optically triggered tunable wavelength conversion including dynamic operation was also demonstrated     

CONTINUOUS FERMENTATION OF GLUCOSE SOLUTIONS

Use of a continuous-flow plug fermentor to ferment glucose solutions was found to be possible only with unrefined commercial glucose and not with pure glucose. Even when the former was used problems were encountered due to a gradual increase in back pressure across the yeast bed. With the commencement of glucose metabolism in the yeast bed, ‘shock’ excretion of potassium and magnesium ions as well as of low molecular weight nitrogenous material was observed. The product from the fermentor contained an abnormally high level of α-diketones viz., 1–3 mg/litre.     

A novel simultaneous unipolar multispectral integrated technology approach for HgCdTe IR detectors and focal plane arrays

In the last few years Rockwell has developed a novel simultaneous unipolar multispectral integrated HgCdTe detector and focal plane array technology that is a natural and relatively straightforward derivative of our baseline double layer planar heterostructure (DLPH) molecular beam epitaxial (MBE) technology. Recently this technology was awarded a U.S. patent. This simultaneous unipolar multispectral integrated technology (SUMIT) shares the high performance characteristics of its DLPH antecedent. Two color focal plane arrays with low-10¹³ cm⁻²s⁻¹ background limited detectivity performance (BLIP D^*) have been obtained for mid-wave infrared (MWIR, 3–5 m) devices at T>130 K and for long-wave infrared (LWIR, 8–10 m) devices at T∼80 K.     

Chromatographische Untersuchungen zur Polydispersität von Hydroxyethylstärke

Chromatographic Studies on the Polydispersity of Hydroxyethyl Starch. A representative sample of clinically used hydroxyethyl starch was separated by semipreparative HPSEC into narrow fractions in the range of approx. 3.000 to 800.000 D. The original sample and selected fractions were characterised by gaschromatographic methylation analysis according to their substitution degrees MS and DS, which were differentiated by the substitution positions at C2, C3 and C6 of the anhydroglucoses and their kind of glycosidic bonding α-1, α-1,4 or α-1,4,6, respectively. Furthermore, polydispersity in relations to the degree of branching was determined. Mark-Houwink and molecular weight distribution parameters determined by multi-detection HPSEC are reported. The presented data demonstrate a extensive homogeneity of the original sample. The clinical relevance is discussed.     

Losses in GaInAs(P)/InP and GaAlSb(As)/GaSb lasers--The influence of the split-off valence band

GaInAs(P)/InP and GaAlSb(As)/GaSb are interesting material systems for long wavelength optical fiber communication. However lasers fabricated from these materials exhibit a substantially higher temperature dependence of the threshold current than GaAs/ GaAlAs lasers ("T0-problem"). lntervalence band absorption and CHSH-Auger-recombination have been suggested as two possible causes for the strong temperature dependent losses in long wavelength lasers. Both mechanisms, if present, should lead to a population of the split-off valence band. In GaInAsP/InP lasers, we have studied this population by directly observing the radiative high-energy recombination of electrons with holes in the split-off valence band. In the case of the band structure of GaAlSb(As), the band gap energy E0is close or equal to the spin-orbit splitting energy Δ0, which favors hole-Auger recombination and intervalence band absorption, as confirmed by our experimental results.     

Electroantennographic and behavioral responses of the sphinx moth Manduca sexta to host plant headspace volatiles

Coupled gas chromatography with electroantennographic detection (GC-EAD) using antennae of adult female Manduca sexta was employed to screen for olfactory stimulants present in headspace collections from four species of larval host plants belonging to two families: Solanaceae—Lycopersicon esculentum (tomato), Capiscum annuum (bell pepper), and Datura wrightii; and Martyniaceae—Proboscidea parviflora. Headspace volatiles were collected from undamaged foliage of potted, living plants. GC–EAD revealed 23 EAD-active compounds, of which 15 were identified by GC-mass spectrometry. Identified compounds included aliphatic, aromatic, and terpenoid compounds bearing a range of functional groups. Nine EAD-active compounds were common to all four host plant species: (Z)-3-hexenyl acetate, nonanal, decanal, phenylacetaldehyde, methyl salicylate, benzyl alcohol, geranyl acetone, (E)-nerolidol, and one unidentified compound. Behavioral responses of female moths to an eight-component synthetic blend of selected tomato headspace volatiles were tested in a laboratory wind tunnel. Females were attracted to the blend. A comparison of responses from antennae of males and females to bell pepper headspace volatiles revealed that males responded to the same suite of volatiles as females, except for (Z)-3-hexenyl benzoate. EAD responses of males also were lower for (Z)- and (E)-nerolidol and one unidentified compound. Electroantennogram EAG dose–response curves for the 15 identified EAD-active volatiles were recorded. At the higher test doses (10–100 g), female antennae yielded larger EAG responses to terpenoids and to aliphatic and aromatic esters. Male antennae did respond to the higher doses of (Z)-3-hexenyl benzoate, indicating that they can detect this compound. On the basis of ubiquity of the EAD-active volatiles identified to date in host plant headspace collections, we suggest that M. sexta uses a suite of volatiles to locate and identify appropriate host plants.     

Synthesis,Characterization and Application of New Rhodium Complexes for Indirect Electrochemical Cofactor Regeneration

Electroenzymatic synthesis often suffers from electrochemical reaction steps which proceed slower than the coupled enzyme reaction. For indirect electrochemical cofactor regeneration, we here report two new mediators with superior properties compared to the established rhodium complex (2,2′‐bipyridyl)(pentamethylcyclopentadienyl)rhodium [Cp*Rh(2,2′‐bipyridine)]. After constructing a robotic system for fast and reliable cyclic voltammetry measurements, we screened twelve rhodium complexes with substituted 2,2′‐bipyridine ligands for their reduction potentials and catalytic activity towards the reduction of NADP. Promising complexes were investigated in more detail by cyclic voltammetry and under batch electrolysis conditions. The new complexes Cp*Rh(5,5′‐methyl‐2,2′‐bipyridine) and Cp*Rh(4,4′‐methoxy‐2,2′‐bipyridine) reduced NADP to NADPH three times faster than the established mediator, resulting in volumetric productivities of up to 136 mmol L⁻¹ d⁻¹ and turnover frequencies of up to 113 h⁻¹. This increased reaction rate of these new mediators makes indirect electrochemical approach significantly more competitive to other methods of cofactor regeneration. Abbreviations: ADH=alcohol dehydrogenase; Ag|AgCl=silver|silver chloride reference electrode; bpy=2,2′‐bipyridine; ci=current increase; Cp*=pentamethylcyclopentadienyl; CV=cyclic voltammetry; Ep=peak potential; equiv=equivalent; NADP/NADPH=nicotinamide adenine dinucleotide phosphate oxidised/reduced form.     

TRACE VOLATILE CONSTITUENTS OF BEER DIMETHYL SULPHIDE FORMATION IN MALT

Dimethyl sulphide formation in malt occurs primarily during the kilning process, and is significantly dependent upon the maximum kilning temperature. During mashing a considerable fraction of the dimethyl sulphide of malt is transferred to the wort. Since this is not always completely removed by the wort boiling process, the remaining dimethyl sulphide, although decreased during fermentation, may be sufficient to impart a noticeable dimethyl sulphide aroma to the finished beer.     

EVALUATION OF SPAWNING SUBSTRATE ENHANCEMENT FOR WHITE STURGEON IN A REGULATED RIVER: EFFECTS ON LARVAL RETENTION AND DISPERSAL

Site‐specific habitat alterations have improved spawning success and early life stage survival of different fish species, including sturgeon, in regulated rivers. We modified the substrate within a section of river at the only known spawning site used by white sturgeon (Acipenser transmontanus) in the Mid Columbia River, Canada. Existing armoured riverbed conditions were modified using a mixture of larger and smaller angular rock with the assumption that the larger material would remain in place at higher discharges and help retain the smaller material. This increased substrate complexity and the amount of available interstitial spaces. We stocked 2‐day posthatch larvae over both the modified site and at an adjacent control site that represented existing substrate conditions. Our objectives were to determine (i) the extent that stocked larvae remained in both the modified and control sites immediately after release, (ii) the timing of subsequent dispersal of larvae from both sites and (iii) how total length of dispersing larvae changed over time and by site. Results from this work indicated that the modified section of riverbed retained significantly higher numbers of larvae after release compared with the control site. Larvae at the modified site were able to hide and remain within the substrate and initiated downstream drift 15 days after release. With the exception of the first day after release, dispersal from both sites occurred at night. There was a significant effect of time after release and site on the total length of dispersing larvae. The larger variation in total larval length observed at the control site compared with the modified site indicated greater difficulty in hiding within the control substrate. Larvae initiated dispersal from the modified site at a mean size of 17.5 mm, which may indicate an important growth threshold before drift. Results from this work are important for future mitigative efforts for sturgeon in regulated rivers where changes to spawning substrates have occurred. Copyright © 2012 John Wiley & Sons, Ltd.     

Scar formation and ligament healing

OBJECTIVE: To compare the efficacy of IUI husband in natural versus FSH stimulated cycles. DESIGN: Prospective, controlled study. MATERIALS AND METHODS: IUI were performed in 57 infertile couples with natural cycles, and in 16 under FSH and GnRH stimulation (Short protocol). In stimulated patients also hCG and hydrogesteron were given. Indication in both groups was idiopathic infertility. Duration of infertility and the age were comparable. Semen preparation and ovarian monitoring were the same in 2 groups. RESULTS: Three pregnancies in 57 natural IUI cycles (5.3%) and 5 out of 16 cycles in stimulated women (31.2% per cycle-with one triple pregnancy). CONCLUSION: In couples with idiopathic infertility FSH stimulation significantly increases rate of pregnancy and multiple gestation.