Rice-like CuO nanostructures for sensitive electrochemical sensing of hydrazine

In this work, a low temperature aqueous chemical growth methodology was used for the fabrication of CuO nanostructures. The as-synthesised nanostructures were then elaborately characterised by number of analytical techniques such as scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). The obtained nanostructures were observed to possess interlaced rice-shaped structural features with the length and width of individual rice determined to be in the range of 200–300 nm and 50–100 nm respectively. The unique nanostructures when utilised as electrode material exhibited excellent electro-catalytic potential towards oxidation of hydrazine in alkaline media. The excellent conductive of CuO added by the high surface area of obtained nanorice-like structures enabled development of highly sensitive (3087 µA mM⁻¹ cm⁻²), selective and stable electrochemical sensor for hydrazine. In addition, the successfully application of the developed sensor in spiked tap, bottled and industrial water samples for the detection of hydrazine suggested its feasibility for practical environmental application.

     

Effect of Varying Amount of Polyethylene Glycol (PEG-600) and 3-Aminopropyltriethoxysilane on the Properties of Chitosan based Reverse Osmosis Membranes

Chitosan and polyethylene glycol (PEG-600) membranes were synthesized and crosslinked with 3-aminopropyltriethoxysilane (APTES). The main purpose of this research work is to synthesize RO membranes which can be used to provide desalinated water for drinking, industrial and agricultural purposes. Hydrogen bonding between chitosan and PEG was confirmed by displacement of the hydroxyl absorption peak at 3237 cm⁻¹ in pure chitosan to lower values in crosslinked membranes by using FTIR. Dynamic mechanical analysis revealed that PEG lowers Tg of the modified membranes vs. pure chitosan from 128.5 °C in control to 120 °C in CS-PEG5. SEM results highlighted porous and anisotropic structure of crosslinked membranes. As the amount of PEG was increased, hydrophilicity of membranes was increased and water absorption increased up to a maximum of 67.34%. Permeation data showed that flux and salt rejection value of the modified membranes was increased up to a maximum of 80% and 40.4%, respectively. Modified films have antibacterial properties against Escherichia coli as compared to control membranes.     

Size and morphology controlled synthesis of gold nanoparticles in green solvent: Effect of reducing agents

The effect of reducing agents on the synthesis of Au(0) metallic nanoparticles (Au NPs) prepared in green solvent medium of β-d-glucose-water dispersions has been reported first. The different equivalent amounts of NaBH₄ and pH values adjusted by NaOH were tested for the reduction of Au salt (HAuCl₄·3H₂O (hydrogen tetrachloroaurate (III) trihydrate) to obtain Au NPs. The type and the amount of reducing agent and the pH of the solution affected the size and morphology of the NPs. Addition of 4 equivalents of NaBH₄ produced homogeneously dispersed 5.3 nm (σ = 0.7) diameter particles. Excess addition of NaBH₄ caused the NPs to settle down as the precipitate forming mesh or wire structure. When salt was reduced by the addition of NaOH (pH = 8.0) the particles were larger (14.2 nm) and less homogeneous (σ = 2.8). At pH = 12.2 the NPs settled at the bottom of the vial when preparation was left overnight. The wire and mesh like structures were obtained at higher pH = 12.2.     

In-vitro antioxidant and antibacterial activities of pumpkin,quince, muskmelon and bottle gourd seeds

Ethanol and chloroform extracts of pumpkin, quince, muskmelon, and bottle gourd seeds were studied for in-vitro antioxidant and antibacterial activities. Crude protein and fat contents of all the seeds compared favorably with high protein legumes and high oil containing oilseeds. Ethanol and chloroform extracts of bottle gourd seeds had highest phenolic content. A direct positive relationship between antioxidant activities and extract concentration was observed with the relationship being more pronounced in chloroform extract of quince seeds (R²?=?0.9685 and 0.9829) followed by ethanol extract of pumpkin seeds (R²?=?0.9666 and 0.9685) as per 1,1-diphenyl-2-picrylhydrazyl and hydrogen peroxide (H₂O₂) method, respectively. Seed extracts were also studied for in-vitro antibacterial activity against Salmonella typhii, Enterococcus sp., Escherichia coli, Bacillus subtilis and Staphylococcus aureus. Ethanol extract of pumpkin seeds inhibited the growth of all bacteria; however, both the extracts of quince seeds did not show any activity against S. typhii, E. coli and S. aureus.     

Design of backtracking search heuristics for parameter estimation of power signals

Neural Computing and Applications - This study presents a novel implementation of evolutionary heuristics through backtracking search optimization algorithm (BSA) for accurate, efficient and robust...     

On increasing the sensitivity of moving average control chart using auxiliary variable

In the statistical process control, the most useful tool to monitor the manufacturing processes in the industries is the control chart. Quality practitioners always desire the charting structure that identifies sustainable changes in the monitoring processes. The sensitivity of the control chart is improved when additional correlated auxiliary information about the study variable is introduced. The regression estimate in the form of auxiliary and supporting variables presents an unbiased and efficient statistic of the mean of the process variable. In this study, auxiliary information-based moving average (AB-MA) control chart is designed for efficient monitoring of shifts in the process location parameter. The performance of the AB-MA control chart is evaluated and compared with existing charts using average run length and other run length characteristics. The comparison reveals that the AB-MA control chart outperforms the competitors in detecting the small and medium changes in the process location parameter. The application of the proposal is also provided to implement it in real situation.     

An enhanced approach for the progressive mean control charts

To maintain and improve the quality of the processes, control charts play an important role for reduction of variation. To detect large shifts in the process parameters, Shewhart control charts are commonly applied but for small shifts, exponentially weighted moving averages (EWMA), cumulative sum (CUSUM), double exponentially weighted moving average (DEWMA), double CUSUM, moving average (MA), double moving average (DMA), and progressive mean (PM) control charts, are used. This study proposes double progressive mean (DPM) and optimal DPM control charts to enhance the performance of the PM chart. As the proposed DPM control charts use information sequentially, hence their performance is compared with natural competitors EWMA, CUSUM, DEWMA, double CUSUM, MA, DMA, and PM control charts. Run length and its different properties are evaluated to compare the performance of the proposed charts and counterparts. Results reveal that proposed optimal DPM outperforms the other charts. An example related to voltage on fixed capacitance level is also provided to illustrate the proposed charts.     

DCE-MRI of hepatocellular carcinoma: perfusion quantification with Tofts model versus shutter-speed model—initial experience

Objective

To quantify hepatocellular carcinoma (HCC) perfusion and flow with the fast exchange regime-allowed Shutter-Speed model (SSM) compared to the Tofts model (TM).

Materials and methods

In this prospective study, 25 patients with HCC underwent DCE-MRI. ROIs were placed in liver parenchyma, portal vein, aorta and HCC lesions. Signal intensities were analyzed employing dual-input TM and SSM models. ART (arterial fraction), K ^trans (contrast agent transfer rate constant from plasma to extravascular extracellular space), v _e (extravascular extracellular volume fraction), k _ep (contrast agent intravasation rate constant), and τ _i (mean intracellular water molecule lifetime) were compared between liver parenchyma and HCC, and ART, K ^trans, v _e and k _ep were compared between models using Wilcoxon tests and limits of agreement. Test–retest reproducibility was assessed in 10 patients.

Results

ART and v _e obtained with TM; ART, v _e , k _e and τ _i obtained with SSM were significantly different between liver parenchyma and HCC (p < 0.04). Parameters showed variable reproducibility (CV range 14.7–66.5 % for both models). Liver K ^trans and v _e ; HCC v _e and k _ep were significantly different when estimated with the two models (p < 0.03).

Conclusion

Our results show differences when computed between the TM and the SSM. However, these differences are smaller than parameter reproducibilities and may be of limited clinical significance.