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Multimedia Tools and Applications - A secret sharing scheme partitions a secret into a set of shares and distributes them among the eligible participants, with each participant receiving one share...  相似文献   
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Synthesis of nanocrystalline pristine and Mn-doped calcium copper titanate quadruple perovskites, CaCu3?xMnxTi4?xMnxO12 (x = 0, 0.5, and 1.0) by modified citrate solution combustion method has been reported. Powder X-ray diffraction patterns attest the phase purity of the perovskite materials. Average particle sizes of all the materials obtained from the Scherrer's formula are in the range of 55–70 nm. The specific surface areas for all the perovskites obtained from BET isotherms are found to be low as expected for the condensed oxide systems and fall in the range of 13–17 m2 g?1. Transmission electron microscopy studies show a reduction in particle size of CaCu3Ti4O12 with increase in Mn doping. Ca and Ti are present in +2 and +4 oxidation states in all the materials as demonstrated by X-ray photoelectron spectroscopy analyses. Cu2+ gets reduced in CaCu3Ti4O12 with higher Mn content. Mn is observed to be present only in +3 oxidation state. All the materials have been examined to be active in CO oxidation as well as H2 production from methanol steam reforming. CaCu3Ti4O12 with ~14 at.% Mn is found to show best catalytic activities among these materials. A comprehensive analysis of the catalytic activities of these perovskites toward CO oxidation and H2 production from MSR reveal the cooperative activity of copper-manganese in the doped perovskites and it is more effective at lower manganese content.  相似文献   
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In the catalytic reaction of an iron(III) porphyrin with t-BuOOH, CumOOH, H2O2 and C6F5IO, cyclohexene was used as a probe substrate. The selective hydroxylation of cyclohexene by hydroperoxides proceeds through radical path and this has been utilized for successful dioxygen activation/autooxidation. For other oxidants epoxide was the major product and the reactions proceed through non-radical path.  相似文献   
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Mössbauer spectra of the products obtained by carbothermal reduction and distribution of silica in the presence of iron in the temperatures range 1200o to 1540o were studied. The preponderance of β- Si3N4 over the α form at a higher reaction temperature were assumed to be related to the formation of an Fe-Si-N liquid. The liquid did not alter its composition with the variation of reduction-temprature, Iron had no effect on the reaction mechanism below 1300oC.  相似文献   
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Microsystem Technologies - Single-Walled Carbon Nanotubes (SWCNTs) are widely used as potential carriers in drug delivery systems. The objective of this work was to observe the effects of pristine,...  相似文献   
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Polyurethane is used for making mould in soft tooling (ST) process for producing wax/plastic components. These wax components are later used as pattern in investment casting process. Due to low thermal conductivity of polyurethane, cooling time in ST process is long. To reduce the cooling time, thermal conductive fillers are incorporated into polyurethane to make composite mould material. However, addition of fillers affects various properties of the ST process, such as stiffness of the mould box, rendering flow-ability of melt mould material, etc. In the present work, multi-objective optimization of various conflicting objectives (namely maximization of equivalent thermal conductivity, minimization of effective modulus of elasticity, and minimization of equivalent viscosity) of composite material are conducted using evolutionary algorithms (EAs) in order to design particle-reinforced polyurethane composites by finding the optimal values of design parameters. The design parameters include volume fraction of filler content, size and shape factor of filler particle, etc. The Pareto-optimal front is targeted by solving the corresponding multi-objective problem using the NSGA-II procedure. Then, suitable multi-criterion decision-making techniques are employed to select one or a small set of the optimal solution(s) of design parameter(s) based on the higher level information of the ST process for industrial applications. Finally, the experimental study with a typical real industrial application demonstrates that the obtained optimal design parameters significantly reduce the cooling time in soft tooling process keeping other processing advantages.  相似文献   
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