Photocatalytic Property and Electronic Structure of Lanthanide-based Oxysulfides

Lanthanide-based oxysulfides and sulfide, LnTaO_3.5S_0.5, Ln₁₀OS₁₄ (Ln = La, Pr, Nd, Sm) and La₄In₅S₁₃, were successively synthesized by sulfurization in a flowing H₂S. The sulfurization decreased the band-gap energies from >4 eV to <3eV, because of the formation of occupied S3p orbitals on the top of valence band. In accordance with the small band gap, the H₂ evolution from a 0.01 M Na₂S and 0.01 M Na₂SO₃ solution system was observed under irradiation of light up to >500 nm. The rate of H₂ evolution under light irradiation of >500 nm increased in the order of Ni/LaTaO_3.5S_0.5 < Ru/La₁₀OS₁₄ < Pt/La₄In₅S₁₃.     

Development of 170 GHz/500 kW gyrotron

A development of 170GHz/500kW level gyrotron was carried out as R&D work of ITER. The oscillation mode is TE_31,8. In a short pulse experiment, the maximum power of 750kW was achieved at 85kV/40A. The efficiency was 22%. In the depressed collector operation, 500kW/36%/50ms was obtained. The maximum efficiency of 40% was obtained at P_RF=470kW whereas the power decrease by the electron trapping was observed. Pulse extension was done up to 10s at P_RF=170kW with the depressed collector operation. The power was limited by the temperature increase of the output window.     

Effect of platinum on the critical current density of fluorine-doped YBa2Cu3Ox superconductors

The critical current density, Jc, in fluorine-doped YBa2Cu3Ox bulk superconductors has been measured at several temperatures. The measured Jc value is 108 A m-2 at 77 K and 0.5 T. A sample with a larger critical current density can be produced by the addition of a small amount of platinum during the sintering process. The added platinum has the effect of evenly distributing Y2BaCuO5 particles and voids in the matrix in comparison with the undoped sample. These distributions of Y2BaCuO5 particles and voids are reflected in an increase in the critical current density. However, these distributions are not directly related to the observed peak effect in the critical current density. If the fluorine-doped YBa2Cu3Ox superconductor consists of the matrix and a phase with a Ginzburg–Landau parameter, that is slightly different from that of the matrix, then the occurrence of the peak effect can be explained.     

Preparation and mesostructure control of highly ordered zirconia particles having crystalline walls

Mesostructured zirconia particles having monoclinic-type crystalline walls were prepared using a low-temperature crystallization technique. Crystalline zirconia particles with highly-ordered mesostructures were obtained through the sol–gel process of zirconium sulfate tetrahydrate at 333 K in the presence of molecular self-assemblies of cetyltrimethylammonium bromide (CTAB) or mixtures of CTAB and anionic molecules such as sodium dodecyl sulfate and sodium p-toluenesulfonate. Variations in the molar ratios of CTAB and the chemical species of anionic molecules led to the variations in the periods of highly-ordered zirconia having crystalline walls. Calcination of the mesostructured zirconia particles prepared using templates consisting solely of CTAB yielded crystalline mesoporous zirconia particles.     

Effect of Ultrasonication on the Microstructure and Tensile Elongation of Zirconia-Dispersed Alumina Ceramics Prepared by Colloidal Processing

To obtain dense, fine-grained ceramics, fine particles and advanced powder processing, such as colloidal processing, are needed. Al₂O₃ and ZrO₂ particles are dispersed in colloidal suspensions by electrosteric repulsion because of polyelectrolyte absorbed on their surfaces. However, additional redispersion treatment such as ultrasonication is required to obtain dispersed suspensions because fine particles tend to agglomerate. The results demonstrate that ultrasonication is effective in improving particle dispersion in suspensions and producing a homogeneous fine microstructure of sintered materials. Superplastic tensile ductility is improved by ultrasonication in preparing suspensions because of the dense and homogeneous fine microstructure.     

An Effective Cache Replacement Algorithm in Transcoding-Enabled Proxies

In this paper, we address the problem of cache replacement for transcoding proxy caching. Transcoding proxy is a proxy that has the functionality of transcoding a multimedia object into an appropriate format or resolution for each client. We first propose an effective cache replacement algorithm for transcoding proxy. In general, when a new object is to be cached, cache replacement algorithms evict some of the cached objects with the least profit to accommodate the new object. Our algorithm takes into account of the inter-relationships among different versions of the same multimedia object, and selects the versions to replace according to their aggregate profit which usually differs from simple summation of their individual profits as assumed in the existing algorithms. It also considers cache consistency, which is not considered in the existing algorithms. We then present a complexity analysis to show the efficiency of our algorithm. Finally, we give extensive simulation results to compare the performance of our algorithm with some existing algorithms. The results show that our algorithm outperforms others in terms of various performance metrics.     

Determination of standard gibbs energies of formation of Cr2N and CrN

The standard Gibbs energies of formation of Cr₂N and CrN have been measured by an equilibration technique and by using thermogravimetry and differential thermal analysis (TG-DTA) at temperatures ranging from 1232 to 1523 K. The results are expressed as follows:

日本水坝的安全管理和地震安全评价

日本是一个地震多发的国家,而特殊的地形又决定了水坝在其经济社会发展中具有重要的地位,因此水坝的安全管理和地震安全评价就成为一个至关重要的方面.     

SENSORY AND INSTRUMENTAL TEXTURE ANALYSIS OF CASSAVA (MANIHOT ESCULENTA, CRANTZ) ROOTS

Two cassava varieties, at three harvesting ages, 6, 12 and 24 months, were analyzed for sensory flavor and texture development. Maximum shear force, Texture Profile Analysis (TPA) and water absorption during cooking were determined at various sampling times. Changes during cooking were described by pseudo‐zero order models for water absorption, flavor and texture development for the fast cooking samples. The 24‐month‐old roots had higher variability and never reached optimum texture or flavor development. Significant pseudo first order models could represent hardness, cohesiveness and chewiness of the TPA, while springiness and adhesiveness varied in a non‐linear fashion. Maximum shear force was 111 N for raw samples and 8.1 N for samples that cooked in less than 25 min. Samples that required longer cook time had on the average a maximum shear force of 19 N.