Effect of temperature on structural, optical and photoluminescence properties of antimony (Sb) doped polycrystalline CuInS2 thin films prepared by spray pyrolysis

Copper indium disulphide (CuInS₂) is an absorber material for solar cell and photovoltaic applications. By suitably doping CuInS₂ thin films with dopants such as Zn, Cd, Na, Bi, Sn, N, P and As its structural, optical, photoluminescence properties and electrical conductivities could be controlled and modified. In this work, Sb (0.01 mole (M)) doped CuInS₂ thin films are grown in the temperature range 300-400 °C on heated glass substrates. It is observed that the film growth temperature, the ion ratio (Cu/In = 1.25) and Sb-doping affects the structural, optical and photoluminescence properties of sprayed CuInS₂ films.The XRD patterns confirm that the Sb-doping suppresses the growth of CuInS₂ polycrystalline thin films along (1 1 2) preferred plane and in other characteristic planes. The EDAX results confirm the presence of Cu, In, S and Sb. About 60% of light transmission occurs in the wavelength range 350-1100 nm. The absorption coefficient (α) is found to be in the order of 10⁵ cm⁻¹. The band gap energy increases as the temperature increases from 300-400 °C (1.35-1.40 eV). SEM photographs depict that large sized crystals of Sb-doped CuInS₂ (1 μm) are formed on the surface of the films. Well defined sharp blue and green band emissions are exhibited by Sb-doped CuInS₂ thin films. Defects-related photoluminescence emissions are discussed. These Sb-doped CuInS₂ thin films are prepared by the cost effective method of spray pyrolysis from the aqueous solutions of CuCl₂, InCl₃, SC(NH₂)₂ and SbCl₃ on heated glass substrates.     

Oxytocin-Selective Nanogel Antibody Mimics

Oxytocin imprinted polymer nanoparticles were synthesized by glass bead supported solid phase synthesis, with NMR and molecular dynamics studies used to investigate monomer–template interactions. The nanoparticles were characterized by dynamic light scattering, scanning- and transmission electron microscopy and X-ray photoelectron spectroscopy. Investigation of nanoparticle-template recognition using quartz crystal microbalance-based studies revealed sub-nanomolar affinity, k_d ≈ 0.3 ± 0.02 nM (standard error of the mean), comparable to that of commercial polyclonal antibodies, k_d ≈ 0.02–0.2 nM.     

A decade''s experience in chemistry maintenance of once through steam generator of fast breeder test reactor

The steam generator of fast breeder test reactor (FBTR) at Kalpakkam (India) is a once through Steam Generator (OTSG) which requires the feed water at high purity level. Therefore, for maintaining feed water chemistry, all volatile treatment (AVT) is adopted along with a full-flow deep bed Condensate Polishing Unit (CPU) in the steam water system. Operational difficulties such as premature termination of operation cycle of the CPU, enhanced impurity pickup resulting in increased load for CPU, early silica breakthrough, etc. were observed on occasions. This paper describes the modifications carried out in the steam water circuit to overcome these problems. A decade's experience in operating the CPU and maintaining the feed water quality is also discussed.     

Structural,magnetic and dielectric properties of nanocrystalline cobalt ferrite by wet hydroxyl chemical route

Nanopowders of CoFe₂O₄ are synthesized via wet chemical co-precipitation processing at pH 8. The synthesized nanoferrite powders are annealed at various temperatures (350 °C, 700 °C and 1050 °C) and are characterized. X-ray diffraction (XRD) patterns indicate the crystalline nature of CoFe₂O₄ nanopowders. Transmission electron microscope (TEM) investigations show, anisotropic shapes like cubic, hexagonal and spherical morphology of nanoparticles with average particle size 38–85 nm. Dielectric constant decreases as the frequency increases. Low value of dielectric loss at higher frequencies suggests the material is suitable for high frequency applications. AC conductivity increases with frequency. The saturation magnetization (M_s), remanant magnetism (M_R) and coercivity (H_C) increases with applied field.