Influence of silicon on the growth of barrier-type anodic films on titanium

Amorphous anodic titania, stabilised by incorporation of silicon species, is shown to grow to high voltages on sputter-deposited, single-phase Ti-Si alloys during anodizing at a constant current density in ammonium pentaborate electrolyte. The films comprise two main layers, with silicon species confined to the inner layers. An amorphous-to-crystalline transition occurs at ∼60 V on the Ti-6 at.% Si alloy, while the transition is suppressed to voltages above 140 V on alloys with 12 and 26 at.% silicon. The crystalline oxide, nucleated at a depth of ∼40% of the film thickness, is associated with the presence of a precursor of crystalline oxide in the pre-existing air-formed oxide. The modified structure of the air-formed oxide due to increased incorporation of silicon species suppresses the amorphous-to-crystalline transition until the onset of dielectric breakdown. The transport numbers of cations and anions during growth of the anodic oxides are independent of the concentration of silicon species in the inner layer, despite the marked change in the field strength.     

Heat transfer enhancement in hydromagnetic dissipative flow past a moving wedge suspended by H2O-aluminum alloy nanoparticles in the presence of thermal radiation

This letter investigates the two dimensional magnetohydrodynamic Falkner Skan flow of water saturated with AA7072–H₂O and AA7075–H₂O nanoparticles over a moving wedge. Influence of viscous dissipation and thermal radiation is also under consideration. The model is reduced into nondimensional form by using defined self-similar transformations. Then, numerical study (Runge-Kutta numerical scheme) is carried out for solution purpose. The effects of pertinent flow parameters are discussed in the flow regimes by means of graphical aid. Graphical results for special cases (static wedge and when the movement of flow and wedge is in opposite direction) of the model are also elucidated graphically. It is noted that fluid velocity decreases for volumetric fraction and magnetic force favor the velocity. Significant effects of thermal radiation and nanoparticles volume fraction pointed for thermal filed and the influence of Eckert number is almost inconsequential. For more radiative fluid heat transfer coefficient decreases and nanoparticles volumetric fraction favor the local rate of heat transfer. In the presence of AA7075 nanoparticles, rate of heat transfer is quite rapid as compared to that of AA7072 nanoparticles. To validate the present computations, some present results are compared with already existing results in the literature and found better agreement between them. Finally, major points of the study ingrained in the last section of the letter.     

Anaerobic digestion for global warming control and energy generation—An overview

Anaerobic digestion often generates ‘biogas’ – an approximately 3:1 mixture of methane and carbon dioxide – which has been known to be a ‘clean’ fuel since the late 19th century. But a great resurgence of interest in biogas capture – hence methane capture – has occurred in recent years due to the rapidly growing spectre of global warming. Anthropogenic causes which directly or indirectly release methane into the atmosphere, are responsible for as much as a third of the overall additional global warming that is occurring at present. Hence the dual advantage of methane capture – generating energy while controlling global warming – have come to the fore.This paper presents an overview of the natural and the anthropogenic sources that contribute methane to the atmosphere. In this context it underscores the urgency with which the world must develop and enforce methods and practices to enhance methane capture.     

Correction to: Pool Fires in Chemical Process Industries: Occurrence,Mechanism, Management

Journal of Failure Analysis and Prevention - In the original version of this article, Vipin’s name was incorrect. It is correct as reflected here. The original article has also been corrected.     

Variation in patient dose due to differences in calibration and dosimetry protocols

For precise and accurate patient dose delivery,the dosimetry system must be calibrated properly according to the recommendations of standard dosimetry protocols such as TG-51 and TRS-398. However, the dosimetry protocol followed by a calibration laboratory is usually different from the protocols that are followed by different clinics, which may result in variations in the patient dose.Our prime objective in this study was to investigate the effect of the two protocols on dosimetry measurements.Dose measurements were performed for a Co-60 teletherapy unit and a high-energy Varian linear accelerator with 6 and 15 MV photon and 6, 9, 12, and 15 MeV electron beams, following the recommendations and procedures of the AAPM TG-51 and IAEA TRS-398 dosimetry protocols. The dosimetry systems used for this study were calibrated in a Co-60 radiation beam at the Secondary Standard Dosimetry Laboratory(SSDL) PINSTECH,Pakistan, following the IAEA TRS-398 protocol. The ratio of the measured absorbed doses to water in clinical setting,D_w(TG-51/TRS-398), was 0.999 and 0.997 for 6 and15 MV photon beams,whereas these ratios were 1.013,1.009, 1.003, and 1.000 for 6, 9, 12, and 15 MeV electron beams, respectively. This difference in the absorbed dosesto-water D_w ratio may be attributed mainly due to beam quality(K_Q) and ion recombination correction factor.     

Toxic metals in the atmosphere in Lahore, Pakistan

Aerosol mass (PM₁₀ and PM_2.5) and detailed elemental composition were measured in monthly composites during the calendar year of 2007 at a site in Lahore, Pakistan. Elemental analysis revealed extremely high concentrations of Pb (4.4 μg m^− 3), Zn (12 μg m^− 3), Cd (0.077 μg m^− 3), and several other toxic metals. A significant fraction of the concentration of Pb (84%), Zn (98%), and Cd (90%) was contained in the fine particulate fraction (PM_2.5 and smaller); in addition, Zn and Cd were largely (≥ 60%) water soluble. The 2007 annual average PM₁₀ mass concentration was 340 μg m^− 3, which is well above the WHO guideline of 20 μg m^− 3. Dust sources were found to contribute on average (maximum) 41% (70%) of PM₁₀ mass and 14% (29%) of PM_2.5 mass on a monthly basis. Seasonally, concentrations were found to be lowest during the monsoon season (July-September). Principle component analysis identified seven factors, which combined explained 91% of the variance of the measured components of PM₁₀. These factors included three industrial sources, re-suspended soil, mobile sources, and two regional secondary aerosol sources likely from coal and/or biomass burning. The majority of the Pb was found to be associated with one industrial source, along with a number of other toxic metals including As and Cr. Cadmium, another toxic metal, was found at concentrations 16 times higher than the maximum exposure level recommended by the World Health Organization, and was concentrated in one industrial source that was also associated with Zn. These results highlight the importance of focusing control strategies not only on reducing PM mass concentration, but also on the reduction of toxic components of the PM as well, to most effectively protect human health and the environment.     

Educational reforms and internationalization of universities: evidence from major regions of the world

Internationalization of universities has become a worldwide phenomenon as global economic integration continues to make its way forcefully into the higher education. The objective of the study is to develop a model for internationalization of universities with the transformation of some promising macroeconomic variables i.e., educational reforms and economic growth in the seven largest regions of the world [namely, East Asia and Pacific (sample 25 countries); Europe and Central Asia (40 countries); Latin America and Caribbean (27 countries); Middle East and North Africa (17 countries); North America (22 countries); South Asia (7 countries) and Sub-Saharan Africa (21 countries)]. The data has been analyzed by panel fixed effect regression from the period of 1990–2011. In addition to transform inputs into output, the study employed eleven indicators of education and five indicators for growth, where the resulting vector is internationalization. The results show the dynamic linkages between educational indicators and economic factors in the selected regions of the World. In East Asia and Pacific region, tertiary and higher education expenditures per student increase the economic factors. Higher education is a powerful driver of long-term growth in Europe and Central Asia. Governments of the state should have to focus on higher education enrolment, as it does not have any significant contribution to increase GDP; gross capital formation and FDI in Latin America and Caribbean region. Higher education enrolment in MENA region significantly increases growth factors on the cost of increase gross national expenditures. Investment in general education and other generic human capital is of the utmost importance in creating an enabling environment for FDI in North America. It is imperative for South Asia to encourage the skill levels and education opportunities for females, in order to maximize the effects of FDI on the female human capital stock and therefore economic growth. Tertiary school enrolment and tertiary expenditures per student identified the importance of tertiary education in Sub-Saharan Africa. The results conclude that educational indicators improve the economic gains, which ultimately reap out the benefit of internationalization.     

A New Method for Siting Hazardous Units in Chemical Process Facilities Which Minimizes Risk at Least Cost: RIDIMPUS

A new method, RIsk and DIstance Minimization in Process Units Siting (RIDIMPUS), is presented with which hazardous units can be sited in a chemical process facility in a manner that the risk of accidents involving the hazardous units as also the cost of spacing the units is minimized. To achieve this, safety and cost factors were modeled using various governing parameters and then expressions were designed to integrate the safety and the economic concerns to form model equations, inequalities and disjunctions. The resulting nonlinear programming model is solvable by using algorithms and solvers on any common desktop computer, thereby providing an optimal and prompt solution.