New approach to unsupported ReS2 nanorod catalyst for upgrading of heavy crude oil using methane as hydrogen source

Highly active ReS₂ nanocatalysts were prepared by CVD method and characterized by XRD, BET -BJH, Raman spectroscopy, XPS, TPR, NH₃-TPD, SEM, and HRTEM techniques. Catalytic activities were used in upgrading heavy crude oil using methane as hydrogen source. The results showed a significant increase in API and decrease in sulfur and nitrogen content of crude oil. RSM technique was used to investigate the interactive effects of temperature (200–400 °C), pressure (20–40 bar) and dosage of nanocatalyst (0.5–2 wt. %) on the performance of HDS reaction. The results represent that the maximum predicted HDS activity (74.375%) was estimated under the optimal conditions (400 °C, 20 bars, and 2 wt % of nanocatalyst). Also, the effect of reaction temperature, pressure and dosage of ReS₂ nanorods catalyst on HDN of heavy crude oil was investigated and highest efficiency in the HDN process (93%) occurred at 400 °C and 40 bar using 2 wt % ReS₂.     

Improving fairness in IEEE 802.11 networks using MAC layer opportunistic retransmission

This paper introduces DAFMAC (Decode And Forward MAC), a scalable opportunistic cooperative retransmission enhancement for the IEEE 802.11 MAC protocol which operates without the need for additional explicit control signalling. Distributed opportunistic retransmission algorithms rely on selecting a single suitable relay without direct arbitration between nodes. Simulations show that DAFMAC offers a significant improvement in fairness for both throughput and jitter, giving multiple parallel data flows a more equal opportunity to utilise the channel. DAFMAC cooperative retransmissions are shown to reduce node energy consumption for a given throughput. Further, the DAFMAC relay selection algorithm is shown to scale very well in terms of complexity and memory requirements in comparison to other cooperative retransmission schemes.     

Designing a fuzzy system for controlling the armament fire in dynamic siege

This paper presents a fuzzy system for controlling the fire command in a surface-to-surface engagement by assuming siege of friendly side by enemy forces. The system must be capable of interacting with a dynamic and uncertain battle world in a real-time manner. In siege situation, it is assumed that the enemy troops are advancing toward friendly side in different directions and the defence resources are limited and nonrenewable at a single platform. Thus, resource allocation problem in a real-time manner is an important and vital component of battle management until coming of auxiliary forces. This paper addresses the design of a fuzzy system as an efficient tool for real-time decision-making in order to optimize the defense resource allocation in engagement.     

Green synthesis of 5-arylidene-2,4-thiazolidinedione, 5-benzylidene rhodanine and dihydrothiophene derivatives catalyzed by hydrated ionic liquid tetrabutylammonium hydroxide in aqueous medium

An efficient synthesis of 5-arylidene-2,4-thiazolidinediones and 5-benzylidene rhodanines by the Knoevenagel condensation of 2,4-thiazolidinedione or rhodanine with aromatic aldehydes was studied. It proceeded smoothly in the presence of tetrabutylammonium hydroxide/H ₂O-EtOH to afford the corresponding products in high yields at 50°C. Also, a series of dihydrothiophene derivatives were synthesized via the four-component reaction of aldehyde, malonitrile, 2,4-thiazolidinedione, and piperidine in the presence of Bu₄NOH as a basic ionic liquid in aqueous medium. This new method offers several advantages, such as excellent yields, short reaction times, and simple procedure.     

Warranty servicing for discretely degrading items with non-zero repair time under renewing warranty

This paper considers a repair-replacement strategy for a special class of discretely degrading and repairable products under renewing free replacement warranty. Each product may experience N different working states with different exponential hazard functions, before the warranty contract expires. Once the item enters working state i (i = 1, 2, … , N), it can either fail or move to any of the subsequent working states with different probabilities, given that a transition has been made. In the former case, the best rectification action, replacement or minimal repair, regarding the failure status, i.e., the product degradation level at the failure time and the remaining warranty time, should be conducted to put the item into operation. It is assumed that replacement of the faulty item occurs instantly and the product warranty is renewed, but non-zero repair time has been included in the model. We derive the optimal replacement-repair policy to minimize the manufacturer’s expected warranty servicing cost per item sold. The Adomian decomposition method is used to find an analytic approximate solution for a special case with two working states. For N > 2, a simulation based optimization method has been developed to analyze the expected warranty cost. Some numerical examples in each section are given to clearly demonstrate the application of this model.     

Parallel processing of continuous queries over data streams

In this paper, we propose parallel processing of continuous queries over data streams to handle the bottleneck of single processor DSMSs. Queries are executed in parallel over the logical machines in a multiprocessing environment. Scheduling parallel execution of operators is performed via finding the shortest path in a weighted graph called Query Mega Graph (QMG), which is a logical view of K machines. By lapse of time, number of tuples waiting in queues of different operators may be very different. When a queue becomes full, re-scheduling is done by updating weight of edges of QMG. In the new computed path, machines with more workload will be used less. The proposed system is formally presented and its correctness is proved. It is also modeled in PetriNets and its performance is evaluated and compared with serial query processing as well as the Min-Latency scheduling algorithm. The presented system is shown to outperform them w.r.t. tuple latency (response time), memory usage, throughput and also tuple loss- critical parameters in any data stream management systems.     

In vitro characterization of a novel tissue engineered based hybridized nano and micro structured collagen implant and its in vivo role on tenoinduction,tenoconduction, tenogenesis and tenointegration

Surgical reconstruction of large tendon defects is technically demanding. Tissue engineering is a new option. We produced a novel tissue engineered, collagen based, bioimplant and in vitro characterizations of the implant were investigated. In addition, we investigated role of the collagen implant on the healing of a large tendon defect model in rabbits. A two cm length of the left rabbit’s Achilles tendon was transected and discarded. The injured tendons of all the rabbits were repaired by Kessler pattern to create and maintain a 2 cm tendon gap. The collagen implant was inserted in the tendon defect of the treatment group (n = 30). The defect area was left intact in the control group (n = 30). The animals were euthanized at 60 days post injury (DPI) and the macro- micro- and nano- morphologies and the biomechanical characteristics of the tendon samples were studied. Differences of P < 0.05 were considered significant. The host graft interaction was followed at various stages of tendon healing, using pilot animals. At 60 DPI, a significant increase in number, diameter and density of the collagen fibrils, number and maturity of tenoblasts and tenocytes, alignment of the collagen fibrils and maturity of the elastic fibers were seen in the treated tendons when compared to the control ones (P < 0.05). Compared to the control lesions, number of inflammatory cells, amount of peritendinous adhesions and muscle fibrosis and atrophy, were significantly lower in the treated lesions (P < 0.05). Treatment also significantly increased load to failure, tensile strength and elastic modulus of the samples as compared with the control ones. The collagen implant properly incorporated with the healing tissue and was replaced by the new tendinous structure which was superior both ultra-structurally and physically than the loose areolar connective tissue regenerated in the control lesions. The results of this study may be valuable in the clinical practice.     

Application-aware virtual paths insertion for NOCs

Network-on-chip (NoC) has rapidly become a promising alternative for complex system-on-chip architectures including recent multicore architectures. Additionally, optimizing NoC architectures with respect to different design objectives that are suitable for a particular application domain is crucial for achieving high-performance and energy-efficient customized solutions. Despite the fact that many researches have provided various solutions for different aspects of NoCs design, a comprehensive NoCs system solution has not emerged yet. This paper presents a novel methodology to provide a solution for complex on-chip communication problems to reduce power, latency and area overhead. Our proposed NoC communication architecture is based on setting up virtual source–destination paths between selected pairs of NoCs cores so that the packets belonging to distance nodes in the network can bypass intermediate routers while traveling through these virtual paths. In this scheme, the paths are constructed for an application based on its task-graph at the design time. After that, the run time scheduling mechanism is applied to improve the buffer management, virtual channel and switch allocation schemes and hence, the constructed paths are optimized dynamically. Moreover, in our design the router complexity and its overheads are reduced. Additionally, the suggested router has been implemented on Xilinx Virtex-5 FPGA family. The evaluation results captured by SPLASH-2 benchmark suite reveal that in comparison with the conventional NoC router, the proposed router takes 25% and 53% reduction in latency and energy, respectively besides 3.5% area overhead. Indeed, our experimental results demonstrate a significant reduction in the average packet latency and total power consumption with negligible area overhead.