Slag foaming is an important phenomenon in steelmaking processes with both beneficial as well as negative effects. The present work is part of the wider project on the modelling of slag foaming, with special reference to dynamic conditions. Since bubble formation is the first step to foam formation, the present work was carried out in an attempt to simulate the bubble formation in slag/metal reactions in steelmaking processes by water‐modelling experiments. The bubble formation due to the gas produced through chemical reaction at the interface between oleic acid and sodium bicarbonate solution was systematically monitored. The chemical reaction rate was varied by varying the concentration of sodium bicarbonate. The bubbles were observed to be generated in the heavier aqueous phase just below the water‐oil interface. The bubbles penetrated the interface and escaped through the oil phase. The rate of the reaction was estimated from the volume of the gas that passed the water/oil interface. It was observed that the bubble formation and bubble growth mechanism were influenced by the reaction rate while the bubble size seemed to be unaffected by the reaction rate. 相似文献
An amperometric biosensor for determination of biochemical oxygen demand in wastewater has been developed to overcome the time consuming monitoring procedures. The performance and stability of the immobilized membrane have been investigated at 37 °C and pH 6.8. Immobilized microbial membranes maintain their stability and activity after intermittent use for 400 cycles when stored at 4 °C in sodium phosphate buffer pH 6.8. The response time of the BOD sensor was only 90 min, being independent of the concentration, and the lower detection limit was 1 mg/l. The obtained BOD values showed correlation with that of the conventional method for BOD determination (BOD5) with a deviation of ±10%. Moreover, the sensor exhibits good repeatability (3.39–4.45%) and reproducibility (1.85–2.25%). Software was added to upgrade this sensor and to make it a promising candidate for online monitoring. 相似文献
Kinetics of in situ degradation bis-(2-chloroethyl) sulphide (sulphur mustard, HD) on polyoxometalate impregnated carbon systems such as 11-molybdo-1-vanadophosphoric acid (V1/C), phosphotungstic acid (PTA/C), sodium phosphotungstic acid (PTANa/C), phosphomolybdic acid (PMoA/C), sodium phosphomolybdic acid (PMoANa/C) and silicotungstic acid (SiTA/C) have been studied. These carbons were characterized for micropore volume and surface area by N2 Brunauer, Emmett and Teller (BET) equation. For degradation studies the solution of HD in chloroform was prepared and taken for the uniform adsorption on the carbon systems using incipient volume. Degradation kinetics was monitored by gas chromatograph equipped with flame ionization detector (GC/FID) and found to be following the pseudo first order kinetics. The values of kinetic rate constant and half-life were calculated. V1/C system showed the fastest degradation of HD. Hemimustard, thiodiglycol, 1,4-oxathiane, sulphoxide and vinyl-2-chloroethyl sulphide were found to be the degradation products with V1/C system which indicated the oxidative, hydrolytic and dehydrohalogenation reactions, responsible for HD degradation. Effect of moisture was also studied on most reactive system, i.e., V1/C. The study indicated that V1/C can be used as a promising adsorbent system for the degradation of HD. 相似文献
Nickel nanorods with diameters ranging from 5 to 10 nm, encapsulated inside the carbon nanotubes, are prepared using microwave plasma chemical vapor deposition. High-resolution transmission electron microscopy (HRTEM) studies reveal the perfect crystalline nature of the rods with d-spacing closely matching the (111) interplanar spacing of Ni. The (111) planes of the Ni nanorods are always aligned at 39.6 degrees with respect to the graphite planes of the nanotubes. The cosine component of the d-spacing along the direction of the graphite planes is found to be 1.6 A; exactly half the d-spacing between the graphite planes. The electron diffraction pattern shows clear spots corresponding to Ni structure. The field cooled and zero field cooled magnetization data reveal the reversibility of the magnetization of the Ni nanorods and show a blocking temperature of 195 K, which correspond to energy barrier of 0.4 eV/(V). 相似文献
Nanomaterials (NMs) have abundant applications in areas such as electronics, energy, environment industries, biosensors, nano devices, theranostic platforms, etc. Nanoparticles can increase the solubility and stability of drug‐loaded materials, enhance their internalisation, protect them from initial destruction in the biological system, and lengthen their circulation time. The biological interaction of proteins present in the body fluid with NMs can change the activity and natural surface properties of NMs. The size and charge of NMs, properties of the coated and uncoated NMs, nature of proteins, cellular interactions direct their internalisation pathway in the cellular system. Thus, the present review emphasises the impact of coated, uncoated NMs, size and charge, nature of proteins on nano–bio surface interactions and on internalisation with specific focus on cancer cells. The increased activity of NPs may also result in toxicity on health and environment, thus emphasis should be given to assess the toxicity of NMs in the medical field. The e‐data sharing portals of NMs have also been discussed in this review that will be helpful in providing the information about the chemical, physical, biological properties and toxicity of NMs. 相似文献
Requirements Engineering - Writing clear and unambiguous requirements that are conflict-free and complete is no easy task. Incorrect requirements lead to errors being introduced early in the design... 相似文献
Dense crowd counting and modeling at different gatherings has ignited a new flame in the visual surveillance research community. There is a high possibility of mishappenings in the form of stampede, mob fighting at these gatherings and the administration is helpless in these scenarios. There is a requirement of analyzing the crowd to prevent these dangerous situations. The proposed work is a case study of Kumbh Mela which models the crowd counting in densely populated images. In the proposed work, the orthographic projection of the crowd is captured using a camera attached to a drone, to reduce the effect of occlusion and scaling which, otherwise, may get introduce during image acquisition process. The captured data is fed to a Convolutional Neural Network for training the model to count head of persons present in the frame. The results obtained from the trained model are validated using geometry and imaging techniques. The proposed model has achieved a mean-absolute-error of 94.3 and a mean-squared-error of 104.6 which seems to outperform the existing state-of-the-art models with respect to the reported performance parameters. The proposed model can be used as a viable solution in applications related to modeling the crowd behavior.
Molecular interaction in two-dimensional(2D)van der Waals(vdW)interfaces has drawn tremendous attention for extraordinary materials characteristics.Sofar sensing characteristics of molecular interaction has been exploited extensively to reach the detection limit to a few parts-per-billion(ppb)of molecules and far less attention is given to the evolution of persistent current state due to the molecular exposure.Our study focuses on molecular memory operation of MoS2-graphene heterostructure based field effect transistor.Metastable resistance state of the device due to the external perturbation of molecules is tuned to get a nearly relaxation free current state at much lower molecular concentration of 10 ppb tofacilitate non-volatile memory features for molecular memory operation.An ultrafast switching operation in milli-second order is achieved at room temperature for the fastest recovery obtained sofar in any molecular sensor.The process is co-controlled both by molecular as well as external charge density. 相似文献