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排序方式: 共有1074条查询结果,搜索用时 15 毫秒
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Haliza Abdul Aziz Noor Azeerah Abas Bonnie Tay Yen Ping Zainab Idris 《Journal of surfactants and detergents》2020,23(2):251-262
The technology for transesterification reactions between methyl esters and alcohols is well established by using classical homogeneous alkaline catalysts, which provide high conversion of methyl esters to specialty or nonindigenous esters. However, in certain products where the purity of the esters is of concern, the removal of homogeneous catalysts after the completion of the reaction is a challenge in terms of production cost and water footprint. Therefore, a study to investigate the potential of heterogeneous catalysts was conducted on reactions between methyl palmitate and triethanolamine. The degree of basicity and active surface area of calcium oxide (CaO), zinc oxide (ZnO), and magnesium oxide (MgO) were first characterized by using temperature-programmed desorption (TPD-CO2) and Brunauere–Emmett–Teller (BET), respectively. Among the metal oxides investigated, the CaO catalyst showed the best catalytic activity toward the transesterification process as it gave the highest conversion of methyl palmitate and yielded fatty esteramine compositions similar to the conventional homogeneous catalyst. The optimum transesterification condition by using the CaO catalyst utilized a lower vacuum system of approximately 200 mbar, which could minimize a considerable amount of energy consumption. Furthermore, low CaO dosage of 0.1% was able to give a conversion of 94.5% methyl ester and formed esteramine at 170 °C for 2 h. Therefore, the production of esterquats from esteramine may become more economically feasible through the methyl ester route by using the CaO catalyst, which can be recycled three times. 相似文献
3.
Adnan Köksal 《Journal of Infrared, Millimeter and Terahertz Waves》1997,18(8):1525-1537
A parametric study of linearly tapered slot antenna (LTSA) in air and a method for optimization of its pattern are presented. A method of moments code is utilized to investigate the behavior of LTSA’s as the length, height and the taper angle varies. It is shown that the antenna pattern can be improved using a top layer of dielectric material with varying permittivity. 相似文献
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本文研究了无线局域网中使信号频谱得到优化的一种简单OFDM子载波加载算法。此算法基于边缘自适应(Margin Adaptive)加载准则及其在室内无线信道上的性能。 相似文献
6.
In this work we present the discrete models for dynamic fracture of structures built of brittle materials. The models construction is based on Voronoi cell representation of the heterogeneous structure, with the beam lattice network used to model the cohesive and compressive forces between the neighboring cells. Each lattice component is a geometrically exact shear deformable beam which can describe large rigid body motion and the most salient fracture mechanisms. The latter can be represented through the corresponding form of the beam constitutive equations, which are derived either at microscale with random distribution of material properties or at a mesoscale with average deterministic values. The proposed models are also placed within the framework of dynamics, where special attention is paid to constructing the lattice network mass matrix as well as the corresponding time-stepping schemes. Numerical simulations of compression and bending tests is given to illustrate the models performance. 相似文献
7.
Adnan Morshed 《Journal of Architectural Education》2002,55(4):201-210
The early twentieth-century invention of the airplane brought on a cultural euphoria that influenced the works and writings of urbanists, architects, artists, and science-fiction writers during the 1920s and 1930s. Le Corbusier's urban design for Rio de Janeiro—which he sketched, so he claimed, from an airplane—offers a visual basis to study how the aesthetic experience of flight was translated spatially, visually, and politically into his design of the future city. The polemics informing Le Corbusier's aerial "discovery" of South American geography revealed that there was a new empowerment in the act of looking from above, and that the spatial characteristics of his subsequent design interventions evoked that empowerment. 相似文献
8.
Adnan Ibrahimbegovi Franois Frey 《International journal for numerical methods in engineering》1994,37(21):3659-3683
A consistent formulation of the geometrically linear shell theory with drilling rotations is obtained by the consistent linearization of the geometrically non-linear shell theory considered in Parts I and II of this work. It was also shown that the same formulation can be recovered by linearizing the governing variational principle for the three-dimensional geometrically non-linear continuum with independent rotation field. In the finite element implementation of the presented shell theory, relying on the modified method of incompatible modes, we were able to construct a four-node shell element which delivers a very high-level performance. In order to simplify finite element implementation, a shallow reference configuration is assumed over each shell finite element. This approach does not impair the element performance for the present four-node element. The results obtained herein match those obtained with the state-of-the-art implementations based on the classical shell theory, over the complete set of standard benchmark problems. 相似文献
9.
Forecasting based on sectoral energy consumption of GHGs in Turkey and mitigation policies 总被引:1,自引:0,他引:1
Recently, global warming and its effects have become one of the most important themes in the world. Under the Kyoto Protocol, the EU has agreed to an 8% reduction in its greenhouse gas (GHG) emissions by 2008–2012. The GHG emissions (total GHG, CO2, CO, SO2, NO2, E (emissions of non-methane volatile organic compounds)) covered by the Protocol are weighted by their global warming potentials (GWPs) and aggregated to give total emissions in CO2 equivalents. The main subject in this study is to obtain equations by the artificial neural network (ANN) approach to predict the GHGs of Turkey using sectoral energy consumption. The equations obtained are used to determine the future level of the GHG and to take measures to control the share of sectors in total emission. According to ANN results, the maximum mean absolute percentage error (MAPE) was found as 0.147151, 0.066716, 0.181901, 0.105146, 0.124684, and 0.158157 for GHG, SO2, NO2, CO, E, and CO2, respectively, for the training data with Levenberg–Marquardt (LM) algorithm by 8 neurons. R2 values are obtained very close to 1. Also, this study proposes mitigation policies for GHGs. 相似文献
10.
Muhammad Khurram Tufail Niaz Ahmad Le Yang Lei Zhou Muhammad Adnan Naseer Renjie Chen Wen Yang 《中国化学工程学报》2021,39(11):16-36
The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm-1, and deformability, the sulfide-based Li7P3S11 solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li7P3S11 could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li7P3S11-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries. 相似文献