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Maykel Cruz-Monteagudo Cristian Robert Munteanu Fernanda Borges Eugenio Uriarte Humberto González-Díaz 《Polymer》2008,49(25):5575-5587
The Quantitative Structure-Property Relationships (QSPRs) based on Graph or Network Theory are important for predicting the properties of polymeric systems. In the three previous papers of this series (Polymer 45 (2004) 3845-3853; Polymer 46 (2005) 2791-2798; and Polymer 46 (2005) 6461-6473) we focused on the uses of molecular graph parameters called topological indices (TIs) to link the structure of polymers with their biological properties. However, there has been little effort to extend these TIs to the study of complex mixtures of artificial polymers or biopolymers such as nucleic acids and proteins. In this sense, Blood Proteome (BP) is one of the most important and complex mixtures containing protein polymers. For instance, outcomes obtained by Mass Spectrometry (MS) analysis of BP are very useful for the early detection of diseases and drug-induced toxicities. Here, we use two Spiral and Star Network representations of the MS outcomes and defined a new type of TIs. The new TIs introduced here are the spectral moments (πk) of the stochastic matrix associated to the Spiral graph and describe non-linear relationships between the different regions of the MS characteristic of BP. We used the MARCH-INSIDE approach to calculate the πk(SN) of different BP samples and S2SNet to determine several Star graph TIs. In the second step, we develop the corresponding Quantitative Proteome-Property Relationship (QPPR) models using the Linear Discriminant Analysis (LDA). QPPRs are the analogues of QSPRs in the case of complex biopolymer mixtures. Specifically, the new QPPRs derived here may be used to detect drug-induced cardiac toxicities from BP samples. Different Machine Learning classification algorithms were used to fit the QPPRs based on πk(SN), showing J48 decision tree classifier to have the best performance. These results suggest that the present approach captures important features of the complex biopolymers mixtures and opens new opportunities to the application of the idea supporting classic QSPRs in polymer sciences. 相似文献
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Staub Adrian; Rayner Keith; Pollatsek Alexander; Hy?n? Jukka; Majewski Helen 《Canadian Metallurgical Quarterly》2007,33(6):1162
Readers' eye movements were monitored as they read sentences containing noun-noun compounds that varied in frequency (e.g., elevator mechanic, mountain lion). The left constituent of the compound was either plausible or implausible as a head noun at the point at which it appeared, whereas the compound as a whole was always plausible. When the head noun analysis of the left constituent was implausible, reading times on this word were inflated, beginning with the first fixation. This finding is consistent with previous demonstrations of very rapid effects of plausibility on eye movements. Compound frequency did not modulate the plausibility effect, and all disruption was resolved by the time readers' eyes moved to the next word. These findings suggest (contra Kennison, 2005) that the parser initially analyzes a singular noun as a head instead of a modifier. In addition, the findings confirm that the very rapid effect of plausibility on eye movements is not due to strategic factors, because in the present experiment, unlike in previous demonstrations, this effect appeared in sentences that were globally plausible. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
6.
Peter Su Adrian Gerlich Motomichi Yamamoto Thomas H. North 《Journal of Materials Science》2007,42(24):9954-9965
The formation of local melted films during friction stir spot welding of as-cast AZ91D and thixomolded AZ91 material is investigated.
The average temperatures close to the tip of the rotating pin vary from 438 to 454 °C during the dwell period in friction
stir spot welding. These measured temperature values are higher than the melting temperature of α-Mg + Mg17Al12 eutectic (437 °C). It is suggested that the temperature in the stir zone during the dwell period is determined by the relative
proportions of α-Mg and (α-Mg + Mg17Al12) eutectic material, which are incorporated during friction stir spot welding. Based on the stir zone temperature measurements
and a detailed examination of material located at the root of the pin thread it is suggested that material is moved downwards
via the pin thread and into the stir zone during the dwell period in friction stir spot welding. Evidence of local melted
film formation is observed in the stir zone of AZ91 spot welds. It is suggested that melted films are retained since their
dissolution rate is much slower in the high temperature stir zone than it is when melted films is formed in the stir zone
during Al 7075-T6 friction stir spot welding. The spontaneous melting temperature, solute diffusion rate and the thermodynamic
driving force for droplet dissolution are much higher during Al 7075-T6 friction stir spot welding. 相似文献
7.
Adrian Thomas Christopher D. Gilson Tanveer Ahmed 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,64(1):73-79
Equipment was developed to measure the time for complete gelling of sodium alginate fibres in calcium chloride solution, taken as the time to achieve maximum tensile strength. The effects of fibre diameter, alginate concentration, alginate composition and calcium chloride concentration on gelling time were investigated. A diffusional model, developed to predict the gelling time, agreed with experimental results except for the effect of calcium ion concentration which was modelled empirically. 相似文献
8.
Ian G. Richardson Adrian R. Brough Rik Brydson Geoffrey W. Groves Christopher M. Dobson 《Journal of the American Ceramic Society》1993,76(9):2285-2288
Solid-state 27 Al and 29 Si magic angle spinning NMR spectroscopy has been combined with electron energy loss spectroscopy carried out in the transmission electron microscope to determine the location of Al substituting in a semicrystalline C-S-H gel present in a hydrated synthetic slag glass. The gel is found to contain mainly pentameric silicate chains in which the central silicon is substituted by aluminum. 相似文献
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PPTC元件为电子设备提供价廉可靠的端口保护 总被引:1,自引:0,他引:1
Adrian Mikolajczak 《电子产品世界》2003,(14):60-62
高分子正温度系数(PPTC)电路保护元件主要是对有破坏性的电流过载冲击进行保护,通常称之为“可恢复式保险丝”。PPTC元件被广泛应用于计算机和外部设备的电路保护,以确保在发生意外连接中断或短路的情况下,不会导致永久性且代价巨大的内部和外部电路受损。这种元件已经成为了I/O(输入/输出)保护的工业标准,广泛应用于USB、IEEE1394、CPU和VGA等方面。在USB和IEEE1394的规范说明中都特别提及这种元件。在计算机工业中,应用PPTC元件较其它类似技术,如一次性保险丝具有更多优点。最主要的是PPTC元件是可恢复式的,减少了由于保… 相似文献
10.
Adrian Maxim Ramin Poorfard Bart DeCanne 《电子设计应用》2007,(8):82-84,85,91
CMOS技术是把L波段卫星调谐器、解调器和其它功能整合至低成本、高效能单芯片的关键。本文将探讨新型低中频和传统零中频DBS调谐器架构在单芯片DBS射频前端设计中的优缺点。 相似文献