Estimation of relative evapotranspiration from NOAA PAL to derive growth characteristics in India

Clear‐sky dekadal relative evapotranspiration (RET) was derived using the surface energy‐balance approach applied to 10‐day composite NOAA PAL (8 km×8 km) datasets over the Indian landmass. This was further used to differentiate between growth characteristics for an irrigated intensive agriculture over a northern India state (e.g. Punjab) and a rainfed ill‐posed agriculture over a central India state (e.g. Madhya Pradesh) using time‐series data sets for five growing years (June–April): 1996–1997, 1997–1998, 1998–1999, 1999–2000, and 2000–2001. The triangular scatter between RET and normalized difference vegetation index (NDVI) showed that the minimum RET increases linearly with NDVI producing a ‘basal line’ that represents relative canopy transpiration only. A clear distinction in scatter was found between the two contrasting agro‐ecosystems showing a higher RET or root zone wetness in irrigated than rainfed systems. In rainfed rice‐growing regions, an inverse correlation (0.6–0.75) was found between RET and the Keetch–Byram meteorological drought index (KBDI), and a substantial reduction in RET was also found in a sub‐normal (2000) compared with a normal (1999) monsoon season. RET estimates were found to be most sensitive to atmospheric transmissivity followed by other land‐surface radiation budget inputs, such as NDVI, LST, and albedo. Error propagation due to three surface parameters is the opposite of that for transmissivity. The maximum possible error in clear‐sky NOAA PAL RET was estimated to be 12–15%. This test study would be helpful in deriving RET using optical and thermal data from a suite of current and future Indian geostationary satellite sensors for monitoring growing conditions.     

Spectral selectivity and accelerated life testing of Al-PbS solar selective surfaces

High absorptance and low thermal emittance selective surfaces have been formed by evaporating lead sulphide onto Al evaporated Al substrates. The dependence of selectivity, α/?, on thickness has been studied. The maximum selectivity was obtained for PbS thickness of 400 Å. The emissivity is found to increase with temperature. The coatings are stable up to a temperature of 240°C in air. Long term ultraviolet irradiation causes the photo-oxidation of PbS to PbSO₄ which results in the increase of emittance and a decrease in absorptance. When cycled between 0°C and 200°C, the coatings do not show any signs of degradation.     

Minimizing decomposition of vaporized hydrogen peroxide for biological decontamination of galvanized steel ducting

The behavior of vaporous hydrogen peroxide (VHP) was examined in clean, room-scale galvanized steel (GS) and polyvinylchloride-coated steel air ducts, to understand how it might be used to decontaminate larger ventilation systems. VHP injected into the GS duct decreased in concentration along the length of the duct, whereas VHP concentrations in the polyvinylchloride coated duct remained essentially constant, suggesting that VHP decomposed at the GS surface. However, decomposition was reduced at lower temperatures (approximately 22 degrees C) and higher flow rates (approximately 80 actual cubic meter per hour). A computational fluid dynamics model incorporating reactive transport was used to estimate surface VHP concentrations where bioaerosol contamination is likelyto reside, and also showed that VHP decomposition was enhanced at bends within the duct, compared to straight sections. Use of G. stearothermophilus indicators, in conjunction with model estimates, indicated that a concentration-contact time of approximately 100 mg/L H2O2(g) x min was required to achieve a 6 log reduction of indicator spores in clean GS duct, at 30 degrees C. When VHP is selected for building decontamination, this work suggests the most efficacious strategy may be to decontaminate GS ducting separately from the rest of the building, as opposed to a single decontamination event in which the ventilation system is used to distribute VHP throughout the entire building.     

Comparing zonal and CFD model predictions of isothermal indoor airflows to experimental data

It is inappropriate to use the assumption of instantaneously well-mixed zones to model airflows and pollutant transport in large indoor spaces. We investigate two approaches for describing the details of airflows in large indoor spaces, for accuracy and suitability for integration with multi-zone infiltration models. One approach, called the zonal method, was developed over the last 15 years to provide an improvement over the well-mixed assumption. The second approach is the use of a computational fluid dynamics simulation using a coarse grid model of the large indoor space. We compare velocity predictions from different formulations of zonal methods and coarse-grid k-epsilon computational fluid dynamics (CFD) models, to measurements, in a 2D mechanically ventilated isothermal room. Our results suggest that, when airflow details are required, coarse-grid CFD is a better-suited method to predict airflows in large indoor spaces coupled with complex multi-zone buildings, than are the zonal methods. Based on the comparison of pressure predictions from different models, we offer guidance regarding the coupling of a model of detailed airflow in large spaces to algebraic multi-zone infiltration models.     

The effect of σ-phase precipitation at 800°C on the mechanical properties of a high alloyed duplex stainless steel

High alloyed duplex stainless steels, referred to as super duplex, are being used increasingly for applications in corrosive environments. The higher Cr and Mo contents of these materials can lead to susceptibility to σ-phase precipitation, even during short time exposures to high temperatures. The 800°C aging of a high alloyed duplex stainless steel was investigated. Optical microscopy with image analysis, X-ray diffraction, and SEM were used to determine the σ-phase and to estimate the amount. Mechanical properties such as tensile strength, impact strength and hardness were investigated. It was found that the impact strength is most sensitive to aging at 800°C. The σ-phase transformation is discussed and the microstructural aspects are described.     

Model Estimates of the Contributions of Environmental Tobacco Smoke to Volatile Organic Compound Exposures in Office Buildings

Volatile organic compounds (VOC) in office buildings originate from multiple sources, such as outdoor air, building materials., occupants, office supplies, and office equipment. Many of the VOC found in office buildings are also present in environmental tobacco smoke (ETS), e.g., benzene, toluene, formaldehyde. Measurements made to date in office buildings have been interpreted by some to imply that the contributions of ETS to VOC exposures in office buildings are small. We have made a first order estimate of the contributions of ETS to VOC concentrations based on the VOC content of ETS and a time-dependent mass-balance model. Four different ventilation-infiltration scenarios were modelled for a typical office building. The results indicate that ETS can contribute significantly to total indoor levels of VOC in office buildings, even under moderate ventilation conditions. Ranges of concentrations for three of the four modelled scenarios substantially overlapped measured ranges of the compounds in office buildings. Average daytime concentrations of benzene from ETS, for example, for three of the four modelled scenarios, ranged from 2.7 to 6.2 μg m^?3, compared to reported measurements of 1.4 to 8.1 μg m^?3 for four office buildings. Under a “worst reasonable” case scenario, the average modelled ETS-contributed concentration of benzene was 33.9 μg m^?3 for a 40-hour work week.     

Relative Effectiveness of Sub-slab Pressurization and Depressurization Systems for Indoor Radon Mitigation: Studies with an Experimentally Verified Numerical Model

The performance of sub-slab-ventilation (SSV) systems has been parametrically studied with a numerical model that was earlier compared successfully with experiment ( Bonnefous et al., 1992 ). The model distinguishes between the sub-slab gravel and the underlying soil. It is used w examine system performance for the following system parameters: the permeability of the soil and of the sub-slab gravel, the magnitude of pressurization (or depressurization) applied by the SSV system, and the mode of SSV application (i.e. pressurization (SSP) or depressurization (SSD)). The mechanisms contributing to the successful performance of SSP and SSD systems are identified. For SSD systems, the mechanisms are (1) the inversion of the pressure gradient across the basement slab, and (2) the reduction of the radon concentration in the soil. For SSP systems, the mechanisms are (1) the elimination of convective flow of soil-gas from the soil into the sub-slab gravel by pressurization of the sub-slab region, (2) the reduction of the radon concentration in the soil, and (3) the suppression of diffusion of soil-gas from the soil into the sub-slab gravel by advective flow of air from the gravel bed into the subgravel soil. Numerical modeling demonstrates that placement of a sub-slab gravel layer substantially improves the SSV system performance. Except in the case of highly permeable soils, SSD systems are predicted to perform better than SSP systems. This prediction is consistent with reported field experience. The numerical model is used to elucidate the reasons for this difference in performance.     

Synergistic effects during CO oxidation over mixed oxides. Study of (Fe2O3+SnO2) and (Mn2O3+SnO2) systems

Based on the comparative evaluation of the catalytic activity of Fe₂O₃, Mn₂O₃ and SnO₂ and their mixed oxides (Fe₂O₃+SnO₂) and (Mn₂O₃+SnO₂), it is shown that the system (Mn₂O₃+SnO₂) shows strong synergistic effects during CO oxidation reaction. Such effects are not observed for the analogous system (Fe₂O₃+SnO₂). Based on the calcination and reduction behaviour of these two mixed oxide systems and the redox potentials of the involved cations, the possible reasons for the observance of synergistic effects for the (Mn₂O₃+SnO₂) system are discussed.     

Affordable, safe housing based on expanded polystyrene (EPS) foam and a cementitious coating

This paper describes an ongoing project to demonstrate an affordable, safe, and energy-efficient housing technology based on expanded polystyrene (EPS) panels with a cementitious coating. The concepts being described are (1) EPS panels embedded with galvanized steel trusses, steel mesh welded or clipped to the protruding points of the trusses and finished with a coating of cement plaster; (2) fiber-reinforced cement board panels and a core of EPS, glued together with high-strength adhesive, dried under high pressure, and connected with cellulose fiber cement board splines; and (3) EPS panels coated with a fiber-reinforced composite. The scope of this project is to model energy flows, analyze costs, simulate seismic forces, test against environmental conditions, and build pilot houses initially in California, Texas and Afghanistan. Results from air quality and energy flow analyses, preliminary cost modeling, structural calculations, and fire testing are reported. The performance goals address seismic safety; energy efficiency in extreme temperatures to reduce fuel use and indoor air quality hazards; affordability and simplicity of construction, as well as ease of expansion for future development; local employment opportunities and small-scale capital investments; and finally, cultural acceptance through education and adaptation to traditional architecture.

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