Utilising the Hoek triaxial cell for multiaxial testing of hollow rock cylinders

Specimens in the form of hollow cylinders are versatile tools which can be used in many applications ranging from simulating stress conditions around underground openings to studying the behaviour of geomaterials under a wide variety of stress paths. Nevertheless, they remain little utilised in experimental studies due to the lack of suitable testing facilities and the difficulties involved in developing such facilities. This work presents a simple and practical solution for hollow cylinder test apparatus devised by combining a widely used and readily available conventional triaxial cell, developed by Hoek and Franklin (Trans. Inst. Min. Metall. 77 (1968) A22 (Section A)), and specially designed internal pressure loading configuration. In order to verify the performance of the new apparatus and demonstrate its versatility, various tests have been carried out on specimens of Springwell sandstone under uniaxial, biaxial, triaxial and polyaxial compression as well as indirect tension. The results obtained confirm the effect of the intermediate principal stress on rock failure and show that the apparent strength of rock is markedly influenced by the stress conditions imposed. It is aimed that the introduction of such simple apparatus would contribute to establishing common multiaxial testing systems that can provide more realistic predictions of the actual behaviour of rock and guide the formulation of more adequate numerical models.     

Energy efficient scheduling in local area networks

Wireless Networks - In Wireless Local Area Networks (WLAN), portable devices such as notebooks, tabs, and smart phones are powered by batteries with limited energy. With the great increase of using...     

Plasmonic Elastic Capsules as Colorimetric Reversible pH‐Microsensors

There is a crucial need for effective and easily dispersible colloidal microsensors able to detect local pH changes before irreversible damages caused by demineralization, corrosion, or biofilms occur. One class of such microsensors is based on molecular dyes encapsulated or dispersed either in polymer matrices or in liquid systems exhibiting different colors upon pH variations. They are efficient but often rely on sophisticated and costly syntheses, and present significant risks of leakage and photobleaching damages, which is detrimental for mainstream applications. Another approach consists of exploiting the distance‐dependent plasmonic properties of metallic nanoparticles. Still, assembling nanoparticles into dispersible colloidal pH‐sensitive sensors remains a challenge. Here, it is shown how to combine optically active plasmonic gold nanoparticles and pH‐responsive thin shells into “plasmocapsules.” Upon pH change, plasmocapsules swell or shrink. Concomitantly, the distance between the gold nanoparticles embedded in the polymeric matrix varies, resulting in an unambiguous color change. Billions of micron‐size sensors can thus be easily fabricated. They are nonintrusive, reusable, and sense local pH changes. Each plasmocapsule is an independent reversible microsensor over a large pH range. Finally, their potential use for the detection of bacterial growth is demonstrated, thus proving that plasmocapsules are a new class of sensing materials.     

Mucoadhesive dosage form of lidocaine hydrochloride: I. Mucoadhesive and physicochemical characterization

The aim of this study was to characterize a buccal mucoadhesive film using lidocaine and its hydrochloride salt (LDHCL) as a model drug. Buccal films were developed using carbopol 971P as a mucoadhesive polymer, and glycerol as a plasticizer. Scanning Electron Microscope, Differential Scanning Calorimetry, X-ray powder diffraction, and Fourier Transform Infra Red techniques were used to characterize the mucoadhesive films. Bioadhesive properties were evaluated using the Universal Instron Instrument with chicken pouch as a model tissue.

LDHCL and its base were present in carbopol 971P films in a molecular dispersion state without exerting any effect on the glass transition of these films. The mucoadhesive force between the chicken pouches and the film containing glycerol did not change by time during the tested period (1-20 min), while increased with increasing the amount of glycerol (10-40% w/w of polymer content). Furthermore, a linear increase in the mucoadhesive force was accompanied by the increase in the film thickness, while a linear decrease followed by plateau was obtained when loading the patch with LDHCL at concentration above 1 mg/cm².

Loading carbopol film with lidocaine base, in a concentration up to 6 mg/cm² decreased linearly the mucoadhesive properties, which could be attributed to salt formation between the acidic carboxylic moiety of carbopol and basic lidocaine.     

Performance of glass fiber reinforced polymer bars under elevated temperatures

This paper investigates the residual tensile properties of newly developed glass fiber reinforced polymer (GFRP) bars after being subjected to elevated temperatures for different periods. A total of 120 GFRP specimens were tested in this study. Half of the samples were covered with concrete while the other half were bare bars. The specimens were subjected to three different controlled temperatures (100, 200 and 300 °C) for three different periods (1, 2, and 3 h). Test results showed that almost no losses were observed in the tensile modulus after all exposure periods and temperatures. Losses in the tensile strength, proportional to the level of temperature and exposure period, were recorded. The bars with concrete cover showed higher residual tensile strength compared to their counterparts without coating. The concrete cover was more effective at the lowest temperature level (100 °C) and at the shortest time period (1 h). Scanning Electronic Microscopy (SEM) technique was also used to investigate the effect of elevated temperature on the degradation mechanism of the GFRP bars. The results showed that increasing the temperature level affected the resin matrix surrounding the glass fibers and consequently affected the bond between the fibers and the matrix.     

Highly Conductive Poly(3,4‐ethylenedioxythiophene):Poly (styrenesulfonate) Films Using 1‐Ethyl‐3‐methylimidazolium Tetracyanoborate Ionic Liquid

Highly conductive poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) films are obtained using ionic liquids as additives. Upon adding 1‐ethyl‐3‐methylimidazolium tetracyanoborate (EMIM TCB) to the conducting polymer, the conductivity increases to 2084 S cm^?1; this is attributed to the phase separation of PSS leading to a structural change in the film. A comparative study with 1‐butyl‐3‐methyl imidazolium tetrafluoroborate (BMIM BF₄) shows that EMIM TCB gives higher conductivity and transmittance and can be regarded as one of the most promising additives for the preparation of indium tin oxide (ITO)‐free organic devices using PEDOT:PSS/EMIM TCB as electrodes.     

Seismic Behavior of As-Built, ACI-Complying, and CFRP-Repaired Exterior RC Beam-Column Joints

In this paper, the efficiency and effectiveness of carbon-fiber-reinforced polymer (CFRP) sheets for upgrading the shear strength and ductility of a seismically deficient exterior beam-column joint were studied and compared with an American Concrete Institute (ACI)-based design joint specimen. One as-built joint specimen, representing the preseismic code design and construction practice for joints and one ACI-based design joint specimen, satisfying the seismic design requirements of the current code of practice were cast. The as-built specimen was used as baseline (control) specimen. These two specimens (i.e., the as-built control and the ACI-based specimens) were subjected to cyclic lateral load histories to induce damage equivalent to damage expected from a severe earthquake. The damaged control specimen was then repaired by filling its cracks with epoxy and externally bonding CFRP sheets to the joint, the beam, and part of the column regions. This specimen was identified as the repaired specimen. The repaired specimen was subjected to a similar cyclic lateral load history, and its response history was recorded. The response histories of the as-built control, the repaired, and the ACI-based design specimen were then compared. The test results demonstrated that externally bonded CFRP sheets can effectively improve both the shear strength and the deformation capacity of seismically deficient and damaged beam-column joints to a state comparable to the ACI-based design joint.     

Interfacial electrochemistry and electrodeposition from some ionic liquids: In situ scanning tunneling microscopy, plasma electrochemistry, selenium and macroporous materials

In this paper we report on recent results from our group, namely on the interface ionic liquid/electrode, plasma electrochemistry and electrodeposition of selenium and of macroporous structures. Ionic liquids show an interesting and liquid dependent surface chemistry: in some liquids the long range “herringbone” superstructure of Au(1 1 1) is visible, in others it is not. Glow discharge plasmas can be employed as a contact free electrode to make nanoparticles in solutions, e.g. nanoparticles of germanium. Selenium can be electrodeposited from ionic liquids under environmental conditions in an open cell and both the red and the grey phases of selenium are feasible. With the help of self organized opal structures of polystyrene spheres macroporous materials of Ag, Al and conducting polymers can be made. The prospects and limits of ionic liquids in surface electrochemistry and electrodeposition are shortly discussed.     

Prediction of strength parameters of FRP-confined concrete

This research deals with the prediction of compressive strength and crushing strain of FRP-confined concrete using neural networks and regression models. Basic information on neural networks and the types of neural networks most suitable for the analysis of experimental results are given. A set of experimental data, covering a large range of parameters, for the training and testing of neural networks is used. The prediction models based on neural network are presented. The influence of raw and the non-dimensional group of variables on compressive strength and crushing strain of FRP-confined concrete is studied through sensitivity analysis, which provided a basis for the development of a new regression based model. The neural networks based model gave high prediction accuracy and the results demonstrated that the use of neural networks in assessing the compressive strength and crushing strain of FRP-confined concrete is both practical and beneficial.